• 제목/요약/키워드: Spectral calibration

검색결과 255건 처리시간 0.025초

POTENTIAL OF NIRS FOR SUPPORTING BREEDING AND CULTIVATION OF MEDICINAL AND SPICE PLANTS

  • Schulz, Hartwig;Steuer, Boris;Kruger, Hans
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.1162-1162
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    • 2001
  • Whereas NIR spectroscopy has been applied in agriculture for more than 20 years, few studies refer to those plant substances occurring only in smaller amounts. Nevertheless there is a growing interest today to support efficiently activities in the production of high-quality medicinal and spice plants by this fast and non-invasive method. Therefore, it was the aim of this study to develop new NIR methods for the reliable prediction of secondary metabolites found as valuable substances in various plant species. First, sophisticated NIR methods were established to perform fast quality analyses of intact fennel, caraway and dill fruits deriving from single-plants [1]. Later on, a characterization of several leaf drugs and the corresponding fresh material has been successfully performed. In this context robust calibrations have been developed for dried peppermint, rosemary and sage leaves for the determination of their individual essential oil content and composition [2]. A specially adopted NIR method has been developed also for the analysis of carnosic acid in the leaves of numerous rosemary and sage gene bank accessions. Carnosic acid is an antioxidative substance for which several health promoting properties including cancer preservation are assumed. Also some other calibrations have been developed for non-volatile substances such as aspalathin (in unfermented rooibos leaves), catechins (in green tea) and echinacoside (in different Echinacea species) [3]. Some NIR analyses have also been successfully performed on fresh material, too. In spite of the fact that these measurements showed less accuracy in comparison to dried samples, the calibration equations are precise enough to register the individual plant ontogenesis and genetic background. Based on the information received, the farmers and breeders are able to determine the right harvest time (when the valuable components have reached their optimum profile) and to select high-quality genotypes during breeding experiments, respectively. First promising attempts have also been made to introduce mobile diode array spectrometers to collect the spectral data directly on the field or in the individual natural habitats. Since the development of reliable NIRS methods in this special field of application is very time-consuming and needs continuous maintenance of the calibration equations over a longer period, it is convenient to supply the corresponding calibration data to interested user via NIRS network. The present status of all activities, preformed in this context during the last three years, will be presented in detail.

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DETERMINATION OF SUGARS AND ORGANIC ACIDS IN ORAGE JUICES USING NEAR INFRARED DIFFUSE REFLECTANCE SPECTROSCOPY

  • Tewari, Jagdish;Mehrotra, Ranajana;Gupta, Alka;Varma, S.P.
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.1522-1522
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    • 2001
  • Beverages based on fruit juices are among the most popular commercially available drinks. There is an ever-increasing demand for these juices in the market. Orange juice is one of the most common as well as most favorite flavor. The fruit processing industries have a tremendous responsibility of quality control. For quality evaluation estimation of various components of the juice is necessary. Sucrose, glucose, fructose, citric acid and malic acid are the prime components of orange juice. Little information is available on analysis of orange juice. However, conventional and general wet chemistry procedures are currently being used which are no longer desired by the industry owing to the time involved, labor input and harmful chemicals required for each analysis. Need to replace these techniques with new, highly specific and automated sophisticated techniques viz. HPLC and spectroscopy has been realized since long time. Potential of Near Infrared Spectroscopy in quantitative analysis of different components of food samples has also been well established. A rapid, non-destructive and accurate technique based on Near Infrared Spectroscopy for determination of sugars and organic acids in orange juice will be highly useful. The current study is an investigation into the potential of Near Infrared Diffuse Reflectance Spectroscopy for rapid quantitative analysis of sucrose, glucose, fructose citric acid and malic acid in orange juice. All the Near Infrared measurements were peformed on a dispersive NIR spectrophotometer (ELICO 153) in diffuse reflectance mode. The spectral region from 1100 to 2500nm has been explored. The calibration has been performed on synthetic samples that are mixtures of sucrose, glucose, fructose, citric acid and malic acid in different concentration ranges typically encountered real orange juice. These synthetic samples are therefore considered to be representatives of natural juices. All the Near Infrared spectra of synthetic samples were subjected to mathematical analysis using Partial Least Square (PLS) algorithm. After the validation, calibration was applied to commercially available real samples and freshly squeezed natural juice samples. The actual concentrations were compared with those predicted from calibration curve. A good correlation is obtained between actual and predicted values as indicated by correlation coefficient ($R^2$) value, which is close to unity, showing the feasibility of the technique.

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선형 강도 교정을 이용한 라만 스펙트럼 인식 (The identification of Raman spectra by using linear intensity calibration)

  • 박준규;백성준;박아론
    • 한국산학기술학회논문지
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    • 제19권3호
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    • pp.32-39
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    • 2018
  • 라만 스펙트럼은 측정 장비 및 환경 조건에 따라 동일한 물질이라도 스펙트럼의 강도 차이를 보인다. 이는 라만 분광의 패턴 인식적인 접근에 제약을 주기 때문에 장비간의 호환성 및 라만 데이터베이스의 재사용을 위해 반드시 해결해야 하는 문제다. 이를 위해 이전의 주요 연구들에서는 측정 장비 간에 전달 함수를 가정하고 이를 구한 후 직접적인 스펙트럼의 교정을 수행하였다. 하지만 이 방식은 강도 왜곡을 발생시키는 다른 조건들에 대해서는 대처 할 수 없는 방법이다. 따라서 본 논문에서는 다양한 측정 조건에 보다 유연하게 대응 할 수 있는 선형 강도 교정을 이용한 분류 방법을 제안하였다. 제안한 방법의 성능 평가를 위해 실험에서는 14033종의 화학 물질에서 측정된 라만 라이브러리를 실험물질에 대한 판별 지표로 사용하였으며, 3개의 라만 분광기로부터 측정된 10종의 화학 물질 라만 스펙트럼을 실험 데이터로 사용하였다. 실험결과에 따르면 제안한 방법을 사용하였을 때 강도 왜곡된 스펙트럼에 대해 100%의 판별 성능을 보였으며, 판별된 스펙트럼에 대해서도 이전보다 높은 상관점수를 보여 사용자가 화학 물질을 판별하는 데 유용한 도구로 사용될 수 있음을 확인하였다.

LRFD 보정을 위한 동적해석에 의한 도로교의 동적하중허용계수 (Dynamic Load Allowance of Highway Bridges by Numerical Dynamic Analysis for LRFD Calibration)

  • 정태주;신동구;박영석
    • 대한토목학회논문집
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    • 제28권3A호
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    • pp.305-313
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    • 2008
  • 본 연구에서는 교량의 노면조도 및 교량과 차량 사이의 상호작용을 고려한 수치해석방법을 사용하여 구한 도로교의 동적하중허용계수(DLA)를 LRFD 형식으로 신뢰도이론의 2차 모멘트법을 적용하여 보정하였다. 대상교량은 건설교통부에서 제정한 "도로교 상부구조 표준도"에 수록되어 있는 단순 PSC빔교와 단순 강판형교, 그리고 LRFD로 설계된 개구제형 단면을 갖는 강박스형교를 사용하고, "보통의 도로"에 대하여 생성시킨 10개의 노면조도를 사용하였다. 차량은 5축 트랙터-트레일러인 표준트럭(DB-24)을 3차원 차량모델로 모델링하고, 교량은 주형을 보요소로, 콘크리트 바닥판은 쉘요소로 이상화시켰으며 주형과 콘크리트 바닥판 사이는 Rigid Link를 사용하여 3차원으로 모델링하였다. 3가지 형식에 대한 10개의 교량에 각각 10개의 노면조도를 사용하여 해석적 방법으로 구한 100개의 해석결과와 OHBDC에서 사용한 보정 식을 사용하여 PSC빔교, 강판형교, 강박스형교 및 전체 대상교량에 대한 LRFD 형식의 DLA를 통계적으로 추정하였다.

초분광 항공원격탐사 테스트베드 구축 및 시험자료 획득 (Construction and Data Analysis of Test-bed by Hyperspectral Airborne Remote Sensing)

  • 장안진;김용일;최석근;한동엽;최재완;김용민;한유경;박홍련;왕표;임희창
    • 대한원격탐사학회지
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    • 제29권2호
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    • pp.161-172
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    • 2013
  • 분광 영상의 효과적인 테스트베드 구축은 초분광 영상의 다양한 활용을 위하여 선행되어야한다. 본 연구에서는 다양한 연구 분야에 적용할 수 있는 테스트베드의 구축 방법 및 효용성에 대한 기초 연구를 수행하였다. 이를 위하여, 기존의 국내 외 테스트베드 생성 방법을 분석하고, 이를 바탕으로 하여 항공기 기반 초분광 센서의 촬영을 위한 테스트베드를 설계하였다. 구축된 테스트베드를 촬영한 영상에서 기준자료를 생성시키기 위하여, 본 연구에서는 대리보정에 의한 전처리 기법을 적용하고, 이에 대한 효용성을 분석하였다. 실험결과, 대리보정은 타프를 이용하는 것이 가장 이상적이지만, 상황에 따라서 분광반사율이 일정하거나, 변화폭이 상대적으로 적은 물질을 이용하는 것이 가능하다는 것을 확인하였다. 본 연구에서 촬영한 테스트베드 자료는 국내 외의 초분광 영상 처리 연구에 참조자료로 사용될 수 있을 것으로 사료된다.

Transferring Calibrations Between on Farm Whole Grain NIR Analysers

  • Clancy, Phillip J.
    • 한국근적외분광분석학회:학술대회논문집
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    • 한국근적외분광분석학회 2001년도 NIR-2001
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    • pp.1210-1210
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    • 2001
  • On farm analysis of protein, moisture and oil in cereals and oil seeds is quickly being adopted by Australian farmers. The benefits of being able to measure protein and oil in grains and oil seeds are several : $\square$ Optimize crop payments $\square$ Monitor effects of fertilization $\square$ Blend on farm to meet market requirements $\square$ Off farm marketing - sell crop with load by load analysis However farmers are not NIR spectroscopists and the process of calibrating instruments has to the duty of the supplier. With the potential number of On Farm analyser being in the thousands, then the task of calibrating each instrument would be impossible, let alone the problems encountered with updating calibrations from season to season. As such, NIR technology Australia has developed a mechanism for \ulcorner\ulcorner\ulcorner their range of Cropscan 2000G NIR analysers so that a single calibration can be transferred from the master instrument to every slave instrument. Whole grain analysis has been developed over the last 10 years using Near Infrared Transmission through a sample of grain with a pathlength varying from 5-30mm. A continuous spectrum from 800-1100nm is the optimal wavelength coverage fro these applications and a grating based spectrophotometer has proven to provide the best means of producing this spectrum. The most important aspect of standardizing NIB instruments is to duplicate the spectral information. The task is to align spectrum from the slave instruments to the master instrument in terms of wavelength positioning and then to adjust the spectral response at each wavelength in order that the slave instruments mimic the master instrument. The Cropscan 2000G and 2000B Whole Grain Analyser use flat field spectrographs to produce a spectrum from 720-1100nm and a silicon photodiode array detector to collect the spectrum at approximately 10nm intervals. The concave holographic gratings used in the flat field spectrographs are produced by a process of photo lithography. As such each grating is an exact replica of the original. To align wavelengths in these instruments, NIR wheat sample scanned on the master and the slave instruments provides three check points in the spectrum to make a more exact alignment. Once the wavelengths are matched then many samples of wheat, approximately 10, exhibiting absorbances from 2 to 4.5 Abu, are scanned on the master and then on each slave. Using a simple linear regression technique, a slope and bias adjustment is made for each pixel of the detector. This process corrects the spectral response at each wavelength so that the slave instruments produce the same spectra as the master instrument. It is important to use as broad a range of absorbances in the samples so that a good slope and bias estimate can be calculated. These Slope and Bias (S'||'&'||'B) factors are then downloaded into the slave instruments. Calibrations developed on the master instrument can then be downloaded onto the slave instruments and perform similarly to the master instrument. The data shown in this paper illustrates the process of calculating these S'||'&'||'B factors and the transfer of calibrations for wheat, barley and sorghum between several instruments.

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Digital Recording Device를 ol용한 회전중인 블레이드 표면의 압력섭동 측정 (Measurement of Surface Pressure Fluctuations on a Rotating Blade Using a Digital Recording Device)

  • 윤정식;강웅;성형진
    • 대한기계학회논문집B
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    • 제29권10호
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    • pp.1119-1129
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    • 2005
  • A new measurement system of wall pressure fluctuations on a rotating machinery, composed of digital recording device, was developed and evaluated. The small-sized digital recording device was attached on the rotating machinery and then was detached for data reduction. In order to obtain the system transfer function of the digital recording system, a dynamic calibration was performed utilizing the signal from a 1/8 inch B&K microphone as input. The time history of the unsteady pressure was then reconstructed from the output of the sensor by using this transfer function. The reconstructed pressure signals showed good agreement with the reference signal in both temporal and spectral sense. This sensor was then used to measure the wall pressure fluctuations on a rotating blade. An array of microphones were installed on the blade in the circumferential and radial directions. Various statistical moments were obtained from the measurement data set. Comparison of these quantities with the existing studies demonstrated satisfactory agreement. These tests give credence to the relevance and reliability of this device for applications in more complicated turbulent rotating machineries.

게이지 블록 간섭계의 선진화 및 완전 자동화 (Advancing the Gauge Block Interferometer and Automating the Gauge Block Calibration)

  • 강주식;김재완;서호성;이원규;김종안
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2005년도 춘계학술대회 논문집
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    • pp.547-550
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    • 2005
  • Gauge blocks are the most widely used material measure in length field in industry. The gauge block interferometer, which is the gauge block measuring system, comprises Twyman-Green type interferometer optics and light sources having precisely known wavelengths. This paper describes the work done for advancing the measurement system and automating the measurement process. The advancing of the system was done mainly by exchanging the spectral lamp with the frequency stabilized lasers, and the automation of measurement was achieved by modifying the hardware and developing the automatic measuring software. As the results of this work, the contrast of interferometric fringes of gauge blocks longer than 100 mm s enhanced about 20 times, and the measurement time has reduced down to 50% by automation.

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EO-1 Hyperion 초분광 영상의 밴드 접합 기법을 이용한 Landsat 8 (LDCM) OLI 센서의 방사 특성 검증 (Validation of the Radiometric Characteristics of Landsat 8 (LDCM) OLI Sensor using Band Aggregation Technique of EO-1 Hyperion Hyperspectral Imagery)

  • 지준화
    • 대한원격탐사학회지
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    • 제29권4호
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    • pp.399-406
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    • 2013
  • 위성 영상 자료에 대한 품질의 향상과 안정화는 다양한 목적을 가진 사용자들을 만족시킬 수 있다. 특히 절대 방사 검/보정은 영상의 광항적 품질을 유지하기 위한 척도가 된다. 본 연구에서는 초분광 영상 밴드 접합 기법과 분광 반응도를 이용하여 다중 분광 센서의 가상화를 통해 절대 방사 보정 계수의 적합성을 판단하였다. 적합성 분석을 위해 약 30분 차이로 촬영된 EO-1 Hyperion과 Landsat-8 OLI 센서의 영상을 이용하였고, 서로 다른 특성을 지닌 토지 피복으로 구성된 3개 지역을 선정하여 복사 에너지 값을 비교 하였다. 그 결과, 시공간에 따른 차이, 센서 수준의 차이를 제외하고 모든 밴드에서 0.99 이상의 적합성을 보여 주었다.

Study on Reflectance and NDVI of Aerial Images using a Fixed-Wing UAV "Ebee"

  • Lee, Kyung-Do;Lee, Ye-Eun;Park, Chan-Won;Hong, Suk-Young;Na, Sang-Il
    • 한국토양비료학회지
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    • 제49권6호
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    • pp.731-742
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    • 2016
  • Recent technological advance in UAV (Unmanned Aerial Vehicle) technology offers new opportunities for assessing crop situation using UAV imagery. The objective of this study was to assess if reflectance and NDVI derived from consumer-grade cameras mounted on UAVs are useful for crop condition monitoring. This study was conducted using a fixed-wing UAV(Ebee) with Cannon S110 camera from March 2015 to March 2016 in the experiment field of National Institute of Agricultural Sciences. Results were compared with ground-based recordings obtained from consumer-grade cameras and ground multi-spectral sensors. The relationship between raw digital numbers (DNs) of UAV images and measured calibration tarp reflectance was quadratic. Surface (lawn grass, stairs, and soybean cultivation area) reflectance obtained from UAV images was not similar to reflectance measured by ground-based sensors. But NDVI based on UAV imagery was similar to NDVI calculated by ground-based sensors.