• Title/Summary/Keyword: Specific of $^{14}C$

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The Preparation of Non-aqueous Supercapacitors with LiMn2O4/C Composite Positive Electrodes (LiMn2O4/C 복합 양극을 이용한 비수계 슈퍼커패시터의 제조)

  • Kim, Kyoungho;Yoo, Jeeyoung;Kim, Minsoo;Yeu, Taewhan
    • Korean Chemical Engineering Research
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    • v.45 no.2
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    • pp.178-182
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    • 2007
  • Non-aqueous supercapacitors by using activated C and $LiMn_2O_4$ as an active material in a positive electrode were prepared and characterized. From the cyclic voltammetry and AC impedance analysis, the capacitive effect by electric double layer of activated carbon and the faradic effect by intercalation/deintercalation of $Li^+$ ion were observed. Increasing the ratio of $LiMn_2O_4$, specific capacitances and energy densities of supercapacitor were increased. At the ratio of 0.86:0.14 ($LiMn_2O_4:C$), the maximum specific capacitance of 17.51 Wh/L and energy density of 23.83 F/cc were obtained, which were more than twice of those for a conventional electric double layer capacitor. Even after 1,000 charge/discharge cycle, the supercapacitor by using the electrode containing 14% of activated carbon and 86% of $LiMn_2O_4$ showed 60% better specific capacitance and energy density than that by using the electrode containing 100% activated carbon.

The Determination of $^{14}C$ in Stack Effluent Gases by Carbonate Suspension Counting Method (탄산염 부유측정법을 이용한 연도 가스중의 방사성 탄소 측정)

  • Chun, Sang-Ki;Woo, Hyung-Joo;Cho, Soo-Young;Kim, Nak-Bae;Lee, Jong-Dae
    • Analytical Science and Technology
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    • v.12 no.4
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    • pp.279-283
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    • 1999
  • The purpose of this study was to optimize carbonate suspension counting method for the measurements of high level activity of $^{14}C$ in a reactor stack effluent gases. Although it is less sensitive method, the carbonate suspension counting method has been found to be a suitable technique for the $^{14}C$ monitoring of samples with small amount but with high specific activity and to be relatively simple and fast.

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c-KIT Positive Schistosomal Urinary Bladder Carcinomas are Frequent but Lack KIT Gene Mutations

  • Shams, Tahany M.;Metawea, Mokhtar;Salim, Elsayed I.
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.1
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    • pp.15-20
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    • 2013
  • Urinary bladder squamous cell carcinoma (SCC), one of the most common neoplasms in Egypt, is attributed to chronic urinary infection with Schistosoma haematobium (Schistosomiasis). The proto-oncogene c-KIT, encoding a tyrosine kinase receptor and implicated in the development of a number of human malignancies, has not been studied so far in schistosomal urinary bladder SCCs. We therefore determined immunohistochemical (IHC) expression of c-KIT in paraffin sections from 120 radical cystectomies of SCCs originally obtained from the Pathology Department of Suez Canal University (Ismailia, Egypt). Each slide was evaluated for staining intensity where the staining extent of >10% of cells was considered positive. c-KIT overexpression was detected in 78.3% (94/120) of the patients, the staining extents in the tumor cells were 11-50% and >50% in 40 (42.6%) and 54 (57.4%) respectively. The positive cases had 14.9%, 63.8%, 21.3% as weak, moderate and strong intensity respectively. Patients with positive bilharzial ova had significantly higher c-KIT expression than patients without (95.2% vs. 38.9%, P=0.000). Mutation analysis of exons 9-13 was negative in thirty KIT positive cases. The high rate of positivity in SBSCC was one of the striking findings; However, CD117 may be a potential target for site specific immunotherapy to improve the outcome of this tumor.

Effects of Inhibitors on the Activity of cAMP Phosphodiesterase in the Mouse Oocytes (생쥐난자내 cAMP Phosphodiesterase의 활성에 미치는 억제제의 영향에 관한 연구)

  • 정민환;조완규
    • The Korean Journal of Zoology
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    • v.29 no.2
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    • pp.79-85
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    • 1986
  • The purpose of the present experiment is to make certain the exsistence of cAMP phosphodiesterase (PDE) in mouse oocytes and confirm its possible role on meiotic resumption. The results showed two types of cAMP in the oocytes with different Michaelis constants (Km) with specific maximum (Vmax); The Km and Vmax of one of two types of PDE were estimated at $0.14 \\pm 0.01 \\muM$ and $0.42 \\pm 0.07$ fmol cAMP hydrolyzed/oocyte/minute, and the other at $14.5 \\pm 2.0 \\muM$ and $2.2 \\pm 0.5$ fmol cAMP hydrolyzed/oocyte/minute. cAMP hydrolysis by PDE was reversibly inhibited in vitro by presence of theophylline or isobutyl-methyl-xanthine (IBMX), which is well known as an inhibitor of oocyte maturation. Consequently, it can be assumed that maturation of oocyte is affected by the high level of intracellular cAMP, and its level is well maintained by presence of PDE inhibitor, such as theophylline and IBMX.

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IgA response in mice infected with Neodiplostomum seoulensis (서울주걱흡충 감염 마우스의 IgA 반응)

  • Sun HUH;Soo-Ung LEE;Moo-Ho WON;Young-Gil JEONG;Young-Hyun KWON;Chang sig CHOI
    • Parasites, Hosts and Diseases
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    • v.33 no.1
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    • pp.55-60
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    • 1995
  • To observe the production of IgA in Balb/c mice with neodiplostomiasis, 20 mice were infected with each 200 metacercariae of Neoniplostomum seoulenis. Sera and the duodenums were obtained 3, 7, 14, 28 days post-infection (PI) from five mice each group Neodipeostomum specific IgA in serum by the enzyme-linked immunosorbent assay increased from 7 days PI and persisted till 28 days PI. Immunohistochemistry for lgA was done with sections of the duodenum. The IgA-positive reaction was generally seen in the lamina propria and submucosa. Some of epithelial cells were positive at 7 and 14 days PI. The present finding showed that Neodiplostomun specific IgA antibody increased in serum and that there was local reaction of IgA in the mucosa and submucosa of the duodenum but not directly related with worm expulsion.

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Prediction of Specific Cutting Pressure in Face Milling Considering Tool Rake Angles (정면밀리에서 공구경사각을 고려한 비절삭저항 예측)

  • Ryu, S.H.;Chu, C.N.
    • Journal of the Korean Society for Precision Engineering
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    • v.14 no.2
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    • pp.169-177
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    • 1997
  • In this study, investigated are the effects of tool rake angles and the change of cutting conditions on the specific cutting pressure in face milling. The cutting force in face milling is predicted from the double cutting edge model in3-dimensional cutting. Conventional specific cutting pressure model is modified by considering the variation of tool rake angles. Effectiveness of the modified cutting force model is verified by the experiments using special face milling cutters with different cutter pockets and various rake angles. From the comparison of the presented model and the specific cutting pressure, it is shown that the axial force can be predicted by the tangential force, radial force and geometric conditions. Also, the rela- tionship between specific cutting pressure and cutting conditions including feedrate, cutting velocity and depth of cut is studied.

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Biokinetics of Carbohydrate and Lipid Metabolism in Normal Laying Hen -Part III. Determination of Radiochemcal Purity of $^{14}C(U)$-Glucose Solution by Liquid Scintillation System Using Glucose Pentaacetate (정상산란계(正常産卵鷄)에 있어서 탄수화물(炭水化物)과 지질(脂質) 대사(代謝)의 생동역학(生動力學) - 제3보(第三報), 오초산화(五醋酸化)포도당의 합성(合成) 및 액체(液體)신치레숀카운터에 의(依)한 균일표식(均一標識) $^{14}C$-포토당의 방사화학적(放射化學的) 순도(純度) 측정(測定))

  • Chiang, Y.H.;Riis, P.M.
    • Applied Biological Chemistry
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    • v.22 no.3
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    • pp.145-149
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    • 1979
  • The radiochemical purity of $^{14}C(U)-glucose$ solution to be injected to normal laying hen was investigated for studying biokinetics of carbohydrate and lipid metabolism. The liquid scintillation counter was employed for determining the activity of carbon-14. The barium hydroxide and zinc sulfate were adopted to precipitate the protein in the solution. The glucose content in the solution was observed as 0.912 mg per ml, applying Hultman's method. The specific activity of $^{14}C(U)-glucose$ solution was known as 31.3 nCi/mg glucose. The glucose pentaacetate was synthesized to isolate the pure glucose from the solution. The specific activity of pure glucose was measured as 28.5 nCi/mg glucose. Therefore, it was known that the radiochemical purity of the solution was 82.7%.

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Quenching Curves for VOCs in the Analysis of Groundwater $^{14}C$ using Liquid Scintillation Counter (액체섬광계수기를 이용한 지하수의 $^{14}C$ 측정에서 휘발성유기화합물(VOC)에 대한 소광곡선)

  • Lee, Kil-Yong;Cho, Soo-Young;Yoon, Yoon-Yeol;Ko, Kyung-Seok;Kim, Yong-Je
    • Journal of Soil and Groundwater Environment
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    • v.12 no.6
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    • pp.53-59
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    • 2007
  • Optimal quenching curves have been studied for the accurate analysis of $^{14}C$ in groundwater polluted by reducing efficiency of volatile organic compounds (VOCs) in liquid scintillation counter (LSC). The quenching parameters (SQP(E)) were measured for ten VOCs such as benzene, toluene, ethylbenzene, o-(m-,p-)xylene, trichloroethylene (TCE), tetrachloroethylene(PCE), carbon tetrachloride and chloroform. The quenching curves were plotted using $^{14}C$ standard solution and chloroform as a quenching agent. Optimal plotting conditions were determined for standard solution, LSC measuring time and the concentration of chloroform. The quenching effects of chlorinated organic compounds such as TCE, PCE, carbon tetrachloride and chloroform were greater than those of BTEX (benzene, toluene, ethylbenzene and xylene). Optimum measuring time was 100 minutes far 7,000 dpm/mL standard solution. A few mL of chloroform should be added for good quenching curves. These quenching curves have good correlation coefficients (> 0.99) and the curves could be applied to accurate analysis of $^{14}C$ in groundwater and tap water.

Latent Heat Storage Characteristics of Some Paraffins(CnH2n+2) for Thermal Environment Control of Greenhouse (그린하우스 열환경 조절을 위한 파라핀계 화합물(CnH2n+2)의 잠열 축열 특성)

  • 송현갑;유영선
    • Journal of Biosystems Engineering
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    • v.21 no.1
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    • pp.84-93
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    • 1996
  • Several paraffins(CnH2n +2) can be used as the thermal energy storage medium because of their large amount of latent heat and their flexibility of phase change temperature. But they have not been used in the thermal energy storage system because their long term stability have not been verified. Paraffins(CnH2n+2) which the values of n are 23, 24, 26 and 28 were selected for this experimental research. And this research was peformed to apply them to the practical systems. The results were summarized as follows. (1) The increase of phase change cycles had no effect on their phase change temperatures. (2) According as the values of n increased from 23 to 28, the specific heats of paraffins(CnH2n+2) increased, and were in the range of 0.47 0.75 ㎉/$kg^circ C$. (3) Thermal conductivities of them were in the range of 0.14 0.17 W/$m^circ C$. and specific gravities of them were in the range of 765800 kg/m3. (4) The density of paraffins was in the range of 765 800 kg/$m^circ C$ , and the density of solid phase was larger than that of liquid phase. (5) When the number of phase change cycles was 1, 500 cycles, the latent heat of paraffins was 90% of the initial value.

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