• Title/Summary/Keyword: Specific heat capacity

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A study on the relationship between the thermal properties of rock and the enviroment in underground spaces (암반 열물성과 지하공간 환경분석 연구)

  • Lee, Chang-Woo
    • Tunnel and Underground Space
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    • v.6 no.4
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    • pp.335-341
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    • 1996
  • This fundamental study analyzes the relationship between rock thermal properties and psychrometric properties in underground space and has a ultimate goal to develope technologies for predicting major environmental variables. The study is divided into 2 subjects (1) developement of a basic model for predicting temperature and humidity, (2) analysis of the validity of the model through application to a local underground storage space for military supplies. The basic model is built for the network of tunnel-shaped underground spaces. The model takes into account rock thermal properties and changes in moisture content in the air due to condensation/evaporation on the rock surface. Using lumped-parameter analytical method, heat flux from or to the surrounding rock is calculated and then the psychrometric properties(air quantity, pressure, temperature, humidity) are estimated through network simulation. The model can be utilized regardless of the tunnel type. The study site is a local storage space built in rock, mainly granite gneiss and quartz-porphyry. It is a U-shaped tunnel, 593.5m long and 6x6.5m wide. Relative humidity inside has to be strictly controlled under 55% to avoid erosion of a certain types of supplies stored in 6 chambers with the capacity of 300~1.000 ton. The thermal conductivity varies between 2.734 and 2.779W/m$^{\circ}C$ and the thermal diffusivity is in the range of 1.119 and $1.152{\times}10^{-6}\;m^2/s$ the specific heat between 910 and $920\;J/kg^{\circ}C$. Relative errors of the predicted values of dry/wet temperature and relative humidity are 0.8~3.0%, 0~7.5% and 0~7.0%, respectively. Apparent errors associated with the rock surface temperature seems to be partly due to the intrinsic limitations in the infrared thermometer used in this study.

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Influence of fuel injection pattern on combustion and emissions characteristics of diesel engine by using emulsified fuel applied with EGR system (에멀젼연료와 EGR의 동시적용 디젤엔진에 있어서 연료 분사 패턴이 연소와 배기가스에 미치는 영향)

  • Yoo, Dong-Hoon
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.9
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    • pp.1064-1069
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    • 2014
  • The use of emulsified fuel and EGR (Exhaust gas recirculation) system are effective methods to reduce NOx emission from diesel engines. In general, it is considered that EGR method influences diesel engine combustion in three different ways: thermal, chemical and dilution effect. Among others, the thermal effect is related to the increase of specific heat capacity due to the presence of $CO_2$ and $H_2O$ in inlet air. Meanwhile, emulsified fuel method of utilizing latent heat of vaporization and miro-explosion has been recognized as an effective technique for reducing diesel engine emissions. In this paper, an author studied on combustion and emission characteristics by using emulsified fuel (EF, Light oil : 80% + Water : 20%) and EGR (30% EGR ratio) system. And the effect of fuel injection pattern control was investigated.

Electron Transfer to Hydroxylase through Component Interactions in Soluble Methane Monooxygenase

  • Lee, Chaemin;Hwang, Yunha;Kang, Hyun Goo;Lee, Seung Jae
    • Journal of Microbiology and Biotechnology
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    • v.32 no.3
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    • pp.287-293
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    • 2022
  • The hydroxylation of methane (CH4) is crucial to the field of environmental microbiology, owing to the heat capacity of methane, which is much higher than that of carbon dioxide (CO2). Soluble methane monooxygenase (sMMO), a member of the bacterial multicomponent monooxygenase (BMM) superfamily, is essential for the hydroxylation of specific substrates, including hydroxylase (MMOH), regulatory component (MMOB), and reductase (MMOR). The diiron active site positioned in the MMOH α-subunit is reduced through the interaction of MMOR in the catalytic cycle. The electron transfer pathway, however, is not yet fully understood due to the absence of complex structures with reductases. A type II methanotroph, Methylosinus sporium 5, successfully expressed sMMO and hydroxylase, which were purified for the study of the mechanisms. Studies on the MMOH-MMOB interaction have demonstrated that Tyr76 and Trp78 induce hydrophobic interactions through π-π stacking. Structural analysis and sequencing of the ferredoxin domain in MMOR (MMOR-Fd) suggested that Tyr93 and Tyr95 could be key residues for electron transfer. Mutational studies of these residues have shown that the concentrations of flavin adenine dinucleotide (FAD) and iron ions are changed. The measurements of dissociation constants (Kds) between hydroxylase and mutated reductases confirmed that the binding affinities were not significantly changed, although the specific enzyme activities were significantly reduced by MMOR-Y93A. This result shows that Tyr93 could be a crucial residue for the electron transfer route at the interface between hydroxylase and reductase.

Adsorption and Regeneration Characteristics of Ammonia on NiCl2 Impregnated Adsorbents (NiCl2 첨착된 흡착제 상에서 암모니아의 흡착 및 재생 특성)

  • Lim, Jeong-Hyeon;Song, Kang;Park, Chu-Sik;Kim, Young-Ho
    • Applied Chemistry for Engineering
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    • v.33 no.2
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    • pp.202-209
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    • 2022
  • Effects of the support and amount of NiCl2 on ammonia adsorption capacity were investigated to improve the ammonia adsorption performance. NiCl2 was impregnated onto the surface of various supports under ultrasonic irradiation. The physicochemical properties and ammonia adsorption performance of NiCl2-impregnated adsorbents were investigated. Among the various supports, it was found that the adsorption capacity of ammonia was the best when NiCl2 was impregnated on activated carbon (AC) with the highest specific surface area. As a result of changing the amount of NiCl2 impregnated on AC, the NiCl2(2.0)/AC adsorbent impregnated with 2 mmol·g-1 of NiCl2 showed the highest ammonia adsorption capacity of 5.977 mmol·g-1. In addition, the adsorption capacity was found to be maintained at an almost constant level in five repeated cycle tests under the condition that low-temperature heat could be utilized. This indicates that the adsorbent has excellent regeneration ability.

Basic Study on 250KW-class IoT Electric Heater for Ship Fuel Heating (선박연료 가열용 250KW급 판형 IoT 전기히터의 기초연구)

  • Jang, Sung-Cheol
    • Journal of Internet of Things and Convergence
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    • v.7 no.3
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    • pp.63-68
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    • 2021
  • Domestic electric heater manufacturers are focusing on technology development to improve the efficiency of existing products. The electric heater for ship fuel is large in size and has high difficulty in miniaturization/high efficiency, so there are not many companies that try to develop technology yet. The existing electric heater has a structure of low heating efficiency because the contact time with the heat exchange tube of the heating medium is very short because the flow path of the ship engine fuel is monotonous. Since it is manufactured in a tubular shape, the volume is very large regardless of the heating efficiency. As a result, the tubular electric heater device applied by overseas advanced companies has difficulty in maintaining and repairing because it is necessary to decompose all tubular heaters when a specific part of the inside is damaged and if the heat exchange tube is damaged, all the heat exchange tubes must be decomposed. In this study, a basic study on plate type electric heaters capable of heating 10 tons of ship engine fuel per hour and setting a maximum temperature of up to 150℃ was conducted through a 250kW capacity plate type electric heater.

Environmental Tax in the Energy Sector and Its Income Distribution Effect (에너지부문 환경세 도입의 소득분배 파급효과)

  • Kang, Man-Ok;Lim, Byung-In
    • Journal of Environmental Policy
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    • v.7 no.2
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    • pp.1-32
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    • 2008
  • This study examined the income distribution effect of the environmental taxes in the energy sector by applying the Urban Family Survey and the Household Income and Expenditure Survey to the Kakwani index. The results analyzed are as follows: first, taxes of the non-transportation energy sector show progressive tax schemes, while those of transportation energy show regressive ones. Second, we calculated the scenario-specific progressivity index on basis of the existing energy price structure. Contrary to the previous works claimed to be regressive, the progressivity in scenario I got higher than before, except for the congestion taxes. Also, the index by the total sum of taxes in scenario II showed just a little bit higher progressive tax system. In scenario III, both the value added tax and the total sum of taxes have a little regressive structure, but the indexes in the environmental taxes, heat capacity taxes, and those which the environmental tax and the congestion tax and heat capacity taxes are summed up, are in general progressive. Third, subsidizing the tax revenues raised from the environmental taxes to the poor classes by a simulation approach shows more progressive as expected, implying the more subsidy the higher the progressivity index. As a result, it is said that the implementation of the environmental taxes has no negative impact on the income distribution, and the subsidy of the tax revenue raised from it to the poor can make the income inequality improve.

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A Numerical Study for Effective Operation of MSW Incinerator for Waste of High Heating Value by the Addition of Moisture Air (함습공기를 이용한 고발열량 도시폐기물 소각로의 효율적 운전을 위한 수치 해석적 연구)

  • Shin, Mi-Soo;Shin, Na-Ra;Jang, Dong-Soon
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.2
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    • pp.115-123
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    • 2013
  • Stoker type incinerator is one of the most popular one used as municipal solid waste (MSW) incineration because, in general, it is quite suitable for large capacity and need no preprocessing facility. Nowadays, however, since the combustible portion of incoming MSW increases together with the decrease of the moisture content due to prohibition of directly burying food waste in landfill, the heating value of waste is remarkably increasing in comparison with the early stage of incinerator installation. Consequently, the increased heating value in incinerator operation causes a number of serious problems such as reduction of waste amount to be burned due to the boiler heat capacity together with the significant NO generation in high temperature environment. Therefore, in this study, a series of numerical simulation have been made as parameters of waste amount and the fraction of moisture in air stream in order to investigate optimal operating condition for the resolution of the problems associated with the high heating value of waste mentioned above. In specific, a detailed turbulent reaction flow field calculation with NO model was made for the full scale incinerator of D city. To this end, the injection method of moisturized air as oxidizer was intensively reviewed by the addition of moisture water amount from 10% and 20%. The calculation result, in general, showed that the reduction of maximum flame temperature appears consistently due to the combined effects of the increased specific heat of combustion air and vaporization heat by the addition of water moisture. As a consequence, the generation of NOx concentration was substantially reduced. Further, for the case of 20% moisture amount stream, the afterburner region is quite appropriate in temperature range for the operation of SNCR. This suggests the SNCR facility can be considered for reoperation. which is not in service at all due to the increased heating value of MSW.

Vulnerability Assessment for Public Health to Climate change Using Spatio-temporal Information Based on GIS (GIS기반 시공간정보를 이용한 건강부문의 기후변화 취약성 평가)

  • Yoo, Seong-Jin;Lee, Woo-Kyun;Oh, Su-Hyun;Byun, Jung-Yeon
    • Spatial Information Research
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    • v.20 no.2
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    • pp.13-24
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    • 2012
  • To prevent the damage to human health by climate change, vulnerability assessment should be conducted for establishment of adaptation strategies. In this study, vulnerability assessment was conducted to provide information about vulnerable area for making adaptation policy. vulnerability assessment for human health was divided into three categories; extreme heat, ozone, and epidemic disease. To assess vulnerability, suitable indicators were selected by three criteria; sensitivity, adaptive capacity, and exposure, spatial data of indicators were prepared and processed using GIS technique. As a result, high vulnerability to extreme heat was shown in the low land regions of southern part. And vulnerability to harmful ozone was high in the surrounding area of Dae-gu basin and metropolitan area with a number of automobiles. Vulnerability of malaria and tsutsugamushi disease have a region-specific property. They were high in the vicinity of the Dimilitarized zone and south-western plain, respectively. In general, vulnerability of human health was increased in the future time. Vulnerable area was extended from south to central regions and from plain to low mountainous regions. For assessing vulnerability with high accuracy, it is necessary to prepare more related indicators and consider weight of indicators and use climate prediction data based on the newly released scenario when assessing vulnerability.

Hot Fire Tests of the KSR-III Sub.(I) Engines (KSR-III 축소형(I) 엔진의 연소 시험)

  • Kim, Y.H.;Kim, Y.W.;Moon, I.Y.;Ko, Y.S.;Lee, S.Y.;Ryu, C.S.;Seol, W.S.
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.30 no.8
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    • pp.120-125
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    • 2002
  • In the preceding tests using the KSR-III Sub.(I) engines, it was observed that the heat resistant capability of the engines was not enough for the mission. So Sub.(I) Mod. engines were designed and tested. The Sub.(I) Mod. engines have three major design parameters - the arrangement of main injectors, the impinging angle of main injectors and thermal barrier coating. More than twenty experiments were carried on to evaluate engine performance and heat resistance capability with respect to design parameters. In this study, the test results are introduced. Analysing the result of Sub.(I) engine tests, it is found that decreasing the impinging angle, adopting the H-type arrangement(rather than radial type arrangement) and adopting the thermal barrier coating can increase heat resistance capacity substantially. Also, engine performance evaluation is conducted using specific impulse and characteristic velocity parameter. The results show that the performance variation is small(about 5%) and the performance is better in the case of radial arrangement. It is suspected that these phenomena are caused by the change of flame structure atomization mixing characteristic of sprays and the distortion of recirculation zone. Also from the low frequency instability point of view, it is observed that reducing the impinging angle and adopting the H type arrangement can increase the instability characteristics.

Experimental Study on Dilution Effect of Exhaust Gas in SNG Combustion on a Model Gas Turbine (가스터빈에서 SNG 연료 조성에 대한 희석제의 배기배출물 저감효과에 대한 실험적 연구)

  • Joo, Seongpil;Yoon, Jisu;Kim, Jeongjin;Kim, Seongheon;Yoon, Youngbin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.44 no.7
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    • pp.603-610
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    • 2016
  • This paper describes experimental results about emission and NOx reduction of dilution effect (Nitrogen and carbon dioxide) about various fuel compositions of synthetic natural gas (SNG). Combustion experiment was performed to investigate the combustion characteristics for SNG with various hydrogen ratio in SNG, heat input and equivalence ratio in a partially premixed model gas turbine combustor. NOx emission was similar to each hydrogen ratio and flame characteristics was investigated from OH chemiluminescence images. There was a singularity of CO emission in stoichiometric condition and it can be identified using OH chemiluminescence intensity. In addition, dilution effect was studied in using nitrogen and carbon dioxide as diluent to reduce the NOx emission. Carbon dioxide diluent was more effective to NOx reduction than nitrogen diluent because of its high diluent specific heat and its heat capacity.