• 한국응용과학기술학회지
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• 제27권3호
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• pp.310-317
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• 2010

The electrochemical properties of electric double layer capacitor(EDLC) was studied by controlling pore size distribution and specific surface area of the activated carbon fiber(ACF). The mesoporous ACF, which was prepared by the iron exchange method, showed the tendency of increasing average pore size and decreasing total surface area. The mesoporous ACF (surface area = 2225 $m^2$/g, pore size=1.93 nm) showed increased mesopore(pore size=1~3nm) volume from 0.055 cc/g to 0.408 cc/g compared to its raw ACF. The charging capacity of the EDLC which uses the prepared mesoporous ACF also increased from 0.39 F/$cm^2$ to 0.55 F/$cm^2$. From these results, it can be known that the electrochemical properties of EDLC are mainly dependent on the specific surface area, but above the surface area 2200 $m^2$/g, it is the mesopore volume that affects the performance of the capacitor considerably. Because the increased mesopore volume results in a decreased ion mobility resistance, the charge capacitance is enhanced.

• Korean Chemical Engineering Research
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• 제43권3호
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• pp.425-431
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• 2005

비표면적이 큰 혼합 활성탄과 전도도가 높은 전도성고분자 폴리피롤을 이용하여 낮은 임피던스와 높은 에너지밀도를 가지는 새로운 형태의 슈퍼커패시터를 제조하였다. 전극 활성물질로 활성탄 BP-20과 MSP-20을 사용하였고, 전기 전도도를 높이기 위하여 활성탄에 전도성 개량제 카본블랙(Super P)과 2-naphthalenesulfonic acid(2-NSA)로 도핑된 전도성 고분자 폴리피롤을 첨가하였다. 용액상태의 유기 결합제 poly(vinylidenefluoride-co-hexafluoropropylene) [P(VdF-co-HFP)/NMP]에 전극 소재들을 혼합시켜 전극을 제조하였다. 실험 결과 최적의 전극 배합비는 78(MSP-20: BP-20=1 : 1) : 17 (Super P : Ppy=10:7) : 5 [P(VdF-co-HFP)] wt％이었다. 폴리피롤이 7 wt％ 첨가된 단위셀의 비정전용량은 28.02 F/g, DC-ESR은 $1.34{\Omega}$, AC-ESR은 $0.36{\Omega}$, 에너지밀도는 19.87 Wh/kg, 동력밀도는 9.77 kW/kg이었다. 500회 충 방전 실험 후 초기 정전용량의 80％를 유지하여 사이클 특성이 우수하였다. 폴리피롤을 첨가함으로써 낮은 내부 저항, 슈도용량(pseudo capacitance)의 발현, 낮은 전하전이저항 및 빠른 반응속도에 의하여 급속한 충 방전이 가능하였다. 그리고 활성탄의 흡탈착에 의한 비패러데이 용량과 폴리피롤의 산화 환원에 의한 슈도용량의 복합현상 때문에 비정전용량이 높게 나타났다.

• Environmental Engineering Research
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• 제22권3호
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• pp.294-301
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• 2017

This paper is based on experiments conducted on a stationary, four stroke, naturally aspirated air cooled, single cylinder compression ignition engine coupled with an electrical swinging field dynamometer. Instead of 100% diesel, 20% Jatropha oil methyl ester with 80% diesel blend was injected directly in engine beside 25% pre-mixed charge of diesel in mixing chamber and with 20% exhaust gas recirculation. The performance and emission characteristics are compared with conventional 100% diesel injection in main chamber. The blend with diesel premixed charge with and without exhaust gas recirculation yields in reduction of oxides of nitrogen and particulate matter. Adverse effects are reduction of brake thermal efficiency, increase of unburnt hydrocarbons (UBHC), carbon monoxide (CO) and specific energy consumption. UBHC and CO emissions are higher with Diesel Premixed Combustion Ignition (DPMCI) mode compared to compression ignition direct injection (CIDI) mode. Percentage increases in UBHC and CO emissions are 27% and 23.86%, respectively compared to CIDI mode. Oxides of nitrogen ($NO_x$) and soot emissions are lower and the percentage decrease with DPMCI mode are 32% and 33.73%, respectively compared to CIDI mode.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.254-254
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• 2006

The sensitivity of plasmid DNA (pDNA) to S1 nuclease, an enzyme to cleave a single-strand DNA, was dramatically modulated through a supramolecular assembly (polyion complex micelle) with a synthetic block copolymer, poly(ethylene glycol)-b-poly(L-lysine) (PEG-PLL). The pDNA condensed in stoichiometric charge ratio was cleaved into 7 fragments each being 10/12, 9/12, 8/12, 6/12, 4/12, 3/12, and 2/12 of the original DNA length, on the other hand, the pDNA condensed in higher charge ratios (>4), were digested into non-specific manner. Condensation of the pDNA was investigated from two viewpoints that how does the rigid DNA molecules fold and condense and how does the condensation influence their biological activity.

• Bulletin of the Korean Chemical Society
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• 제34권3호
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• pp.851-855
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• 2013

This paper describes an environmentally friendly process for the recovery of $LiFePO_4$ cathode materials from scrap electrodes by a simple thermal treatment method. The active materials were easily separated from the aluminum substrate foil and polymeric binders were also decomposed at different temperatures ($400^{\circ}C$, $500^{\circ}C$, $600^{\circ}C$) for 30 min under nitrogen gas flow. The samples were characterized by X-ray diffraction (XRD), scanning electronic microscopy (SEM), Raman spectroscopy, Thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). The electrochemical properties of the recycled $LiFePO_4$ cathode were evaluated by galvanostatic charge and discharge modes. The specific charge/discharge capacities of the recycled $LiFePO_4$ cathode were similar to those of the original $LiFePO_4$ cathode. The $LiFePO_4$ cathode material recovered at $500^{\circ}C$ exhibits a somewhat higher capacity than those of other recovered materials at high current rates. The recycled $LiFePO_4$ cathode also showed a good cycling performance.

• Journal of Photoscience
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• 제3권3호
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• pp.153-158
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• 1996

The effects of $\alpha$- and $\beta$-cyclodextrins (CD) on the twisted intramolecular charge transfer (TICT) behavior of p-N,N'-dimethylaminobenzoic acid (DMABA) in buffered aqueous solution have been investigated by examining formation and decay behaviors of the TICT-typical dual fluorescence. The ratio of the TICT emission to the normal emission (I$_a$/I$_b$) increases linearly $\alpha$-CD concentration increases, while in the presence of $\beta$-CD it shows nonlinear dependences on the CD concentration. The analysis of the CD-dependent changes of the I$_a$/I$_b$ and absorption spectra demonstrates formation of 1:1 inclusion complexes between DMABA and CDs. The decay time of the normal emission (ca. 700 ps) is little affected by the formation of $\alpha$-CD inclusion complex, whereas it increases upto ca. 1.6 ns upon formation of $\beta$-CD inclusion complex. The TICT emission for the $\beta$-CD inclusion complex exhibits two decay components while it shows a single component for the $\alpha$-CD inclusion complex, indicating formation of one or two types of inclusion complex in the presence of $\alpha$-CD or $\beta$-CD, respectively. These results are attributed to the CD cavity size dependence on patterns of complexation between CDs and DMABA. The CD size dependences of the TICT fluorescence properties with the orientation of the guest molecule demonstrate that the specific hydrogen bonding between the carboxylic acid group and water plays an important role in the excited-state TICT.

• 대한전자공학회논문지
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• 제25권10호
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• pp.1209-1215
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• 1988

도핑된 실리콘半導體와 有機容媒($C_6H_6$, $CH_3OH$, $C_2H_5OH$) 界面의 空間電荷效果와 도핑되지 않은 多結晶 硏化갈리움半島體와 電解質(NaCl, KCl, KI 溶液) 界面의 제타電位 反轉現象을 小電氣泳動測定에 依하여 定性的인 解析을 하였다. 有機容媒內의 空間電荷效果는 무시 할 수 있으며 제타 電位 反轉現象은 도핑되지 않은 多結晶 硏化 갈리움과 電解質 界面의 表面位置, 特性的 吸着, 電氣陰性度, 特性的으로 吸着된 이온의 크기에 따라 決定됨을 알았다. 콜로이드半導體의 解析面은 表面에서 結定된 거리에 位置하면 Helmholtz外面(OHP)에 거의 一致한다.

• 화약ㆍ발파
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• 제34권2호
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• pp.18-30
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• 2016

도심지 암반터파기 작업시 암반을 파쇄 하는 데 있어서 가장 경제적이고 효율적인 방법으로 폭약을 사용한 발파방법이 주로 사용되고 있는데, 이와 같은 발파방법은 발파에 따른 암반의 파쇄 시 진동 소음의 발생 및 비산 등 발파공해의 발생요인으로 인해 보안물건 주변에서 많은 제약을 받고 있는 실정이며, 폭약을 기폭 시켜 주는 뇌관의 종류 및 방법에 따라 일회 발파공수의 제한, 일회 굴착 깊이 제한 등으로 일일 생산량 감소에 따른 공사기간 증대에도 많은 영향을 미치게 된다. 따라서 본 시공사례는 국내에서 가용할 수 있는 뇌관을 선정하여 응용발파방법이 가능하도록 층상장약방법에 의한 발파패턴을 설계하여 도심지 특수구간에 대한 적용가능성을 평가하였다.

• Journal of Mechanical Science and Technology
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• 제18권1호
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• pp.30-36
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• 2004

In this paper, operation algorithms for a parallel HEV equipped with a relatively small motor are investigated. For the HEV, the power assist and the equivalent fuel algorithms are proposed. In the power assist algorithm, an electric motor is used to assist the engine which provides the primary power source. Tn the equivalent fuel algorithm, the electric energy stored in the battery is considered to be an equivalent fuel, and an equivalent brake specific fuel consumption for the electric energy is proposed. From the equivalent fuel algorithm, distribution of the engine power and the motor power is determined to minimize the fuel consumption for a given battery state of charge (SOC) and a required vehicle power. It is found from the simulation results that the fuel economy and the final battery SOC depend on the motor discharge energy and it is the best way to charge the battery only by the regenerative braking, not by the engine to improve the overall fuel efficiency of the HEV with the relatively small motor.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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• pp.541-544
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• 2001

Orthorhombic $LiMnO_2$ was synthesized by solid-state reaction using $LiOH{\cdot}H_{2}O$ and $Mn_{2}O_{3}$ as starting material. Its electrochemical properties as cathode in lithium batteries were examined. X-ray diiffraction revealed that the $LiMnO_2$ compound showed a well-defined orthorhombic phase of a space group with Pmnm. The capacity of $LiMnO_2$ agreed well with its specific surface area and grinding treatment was effective in improving cycling performance. For lithium polymer battery applications. the $LiMnO_2$ cell was characterized electrochemically by charge-discharge experiments. And the relationship between the characteristics of powder and electrochemical properties was studied in this research. A maximum discharge capacity of $160-170mAhg^{-1}$ for $LiMnO_2/Li$ cell was achieved.