• Title/Summary/Keyword: Specific charge

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The Synthesis and Charge/discharge Properties of $LiNiO_2$ according to heat treatment condition (열처리 조건에 따른 $LiNiO_2$의 합성과 충방전 특성)

  • Lee, H.N.;Chun, D.G.;Choi, H.K.;Kim, K.S.;Gu, H.B.
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1603-1605
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    • 1997
  • $LiNiO_2$ is prepared by heating LiOH $H_2O$ and $Ni(OH)_2$ (mole ratio 1:1). In this study, we investigated X-ray diffraction, and charge/discharge property heat treatment condition and conductive agent sort and volume of $LiNiO_2$ prepared at various temperature and time. All $LiNiO_2$ prepared at this study showed hexagonal structure. In charge/discharge capacities, heated at $O_2$ than air and $750^{\circ}C$ than $700^{\circ}C$, specific capacity is higher. Therefore, when preliminary heat at $650^{\circ}C$ $O_2$ and heat at $750^{\circ}C$ carried out, charge/discharge property is best.

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Charge/discharge capacity and cycle salability of LiMn$_2$O$_4$cathode by sorts and volume of conductive agent (도전재 종류와 양에 따른 LiMn$_2$O$_4$정극의 충방전 용량 및 Cycle 안정성)

  • 정인성;박계춘;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.275-278
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    • 1997
  • We investigated effectness of sort and volume of conductive agent to charge/discharge capacity of LiMn$_2$O$_4$. LiMn$_2$O$_4$is prepared by reacting stoichiometric mixture of LiOH . $H_2O$ and MnO$_2$(mole ratio 1 : 2) and heating at 80$0^{\circ}C$ for 24h, 36h, 48h, 60h and 72h. All LiMn$_2$O$_4$cathode active materials show spinel structure. Cathode active materials calcined at 80$0^{\circ}C$ for 36h, charge/discharge characteristics and cycle stability have remarkable advantages. Used that super-s-black and 20wt% as conductive agent in LiMn$_2$O$_4$, it is excellent than property of cathode used Acetylene black or mixture of Super-s-black and acetylene black at charge/discharge capacity and cycle stability. Also, specific efficiency of cathode is excellent as over 98% and that of first cycle is excellent as 92%.

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On the vibration influence to the running power plant facilities when the foundation excavated of the cautious blasting works. (S화력발전소 3, 4호기 증설에 따르는 정밀발파작업으로 인한 인접가동발전기및 구조물에 미치는 파동영향조사)

  • Huh Ginn
    • Explosives and Blasting
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    • v.8 no.1
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    • pp.3-16
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    • 1990
  • The cautious blasting works had been used with emulsion explosion electric M/S delay caps. Drill depth was from 3m to 6m with Crawler Drill $\varphi{70mm}$ on the calcalious sand stone(sort-moderate-semi hard Rock). The total numbers of feet blast were 88. Scale distance were induces 15.52-60.32. It was applied to propagation Law in blasting vibration as follows. Propagtion Law in Blasting Vibration $V=K(\frac{D}{W^b})^n$ where V : Peak partical velocity(cm/sec) D : Distance between explosion and recording sites (m) W : Maximum Charge per delay-period of eighit milliseconds or more(Kg) K : Ground transmission constant, empirically determind on th Rocks, Explosive and drilling pattern ets. b : Charge exponents n : Reduced exponents Where the quantity $D/W^b$ is known as the Scale distance. Above equation is worked by the U.S Bureau of Mines to determine peak particle velocity. The propagation Law can be catagrorized in three graups. Cabic root Scaling charge per delay Square root Scaling of charge per delay Site-specific Scaling of charge per delay Charge and reduction exponents carried out by multiple regressional analysis. It's divided into under loom and over loom distance because the frequency is verified by the distance from blast site. Empirical equation of cautious blasting vibration is as follows. Over 30m----under l00m----- $V=41(D/3\sqrt{W})^{-1.41}$ -----A Over l00m-----$V= 121(D/3\sqrt{W})^{-1.66}$-----B K value on the above equation has to be more specified for furthur understang about the effect of explosives, Rock strength. And Drilling pattern on the vibration levels, it is necessary to carry out more tests.

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On the vibration influence to the running power plant facilities when the foundation excavated of the cautious blasting works (삼천포화력발전소 3, 4호기 증설에 따르는 정밀발파작업으로 인한 인접가동발전기 및 구조물에 미치는 진동영향조사)

  • Huh, Ginn
    • Journal of the Korean Professional Engineers Association
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    • v.24 no.6
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    • pp.97-105
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    • 1991
  • The cautious blasting works had been used with emulsion explosion electric M/S delay caps. Drill depth was from 3m to 6m with Crawler Drill ø70mm on the calcalious sand stone (soft-moderate-semi hard Rock). The total numbers of fire blast were 88 round. Scale distance were induces 15.52-60.32. It was applied to propagation Law in blasting vibration as follows. Propagation Law in Blasting Vibration (Equation omitted) where V : Peak partical velocity(cm/sec) D : Distance between explosion and recording sites(m) W : Maximum Charge per delay-period of eighit milliseconds o. more(kg) K : Ground transmission constant, empirically determind on the Rocks, Explosive and drilling pattern ets. b : Charge exponents n : Reduced exponents Where the quantity D / W$^n$ is known as the Scale distance. Above equation is worked by the U.S Bureau of Mines to determine peak particle velocity. The propagation Law can be catagrorized in three graups. Cubic root Scaling charge per delay Square root Scaling of charge per delay Site-specific Scaling of charge per delay Charge and reduction exponents carried out by multiple regressional analysis. It's divided into under loom and over 100m distance because the frequency is verified by the distance from blast site. Empirical equation of cautious blasting vibration is as follows. Over 30 ‥‥‥under 100m ‥‥‥V=41(D/$^3$√W)$\^$-1.41/ ‥‥‥A Over 100 ‥‥‥‥under 100m ‥‥‥V=121(D/$^3$√W)$\^$-1.56/ ‥‥‥B K value on the above equation has to be more specified for furthur understang about the effect of explosives, Rock strength. And Drilling pattern on the vibration levels, it is necessary to carry out more tests.

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On the vibration influence to the running power plant facilities when the foundation excavated of the cautious blasting works. (S 화력발전소 3, 4호기 증설에 따르는 정밀발파작업으로 인한 인접가동발전기 및 구조물에 미치는 진동영향조사)

  • Huh Ginn
    • Explosives and Blasting
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    • v.9 no.4
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    • pp.3-12
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    • 1991
  • The cautious blasting works had been used with emulsion explosion electric M /S delay caps. Drill depth was from 3m to 6m with Crawler Drill 70mm on the calcalious sand stone (soft-moderate-semi hard Rock) . The total numbers of feet blast were 88. Scale distance were induces 15.52-60.32. It was applied to Propagation Law in blasting vibration as follows .Propagtion Law in Blasting Vibration V=k(D/W/sup b/)/sup n/ where V : Peak partical velocity(cm/sec) D : Distance between explosion and recording sites(m) W ; Maximum Charge per delay -period of eight milliseconds or more(Kg) K : Ground transmission constant, empirically determind on the Rocks, Explosive and drilling pattern ets. b : Charge exponents n : Reduced exponents Where the quantity D/W/sup b/ is known as the Scale distance. Above equation is worked by the U.S Bureau of Mines to determine peak particle velocity. The propagation Law can be catagrorized in three groups. Cabic root Scaling charge per delay Square root Scaling of charge per delay Site-specific Scaling of charge delay Charge and reduction exponents carried out by multiple regressional analysis. It's divided into under loom and over loom distance because the frequency is varified by the distance from blast site. Empirical equation of cautious blasting vibration is as follows. Over 30m--under 100m----V=41(D/ W)/sup -1.41/-----A Over l00m---------V=121(D/ W)/sup -1.56/-----B K value on the above equation has to be more specified for furthur understand about the effect of explosives. Rock strength, And Drilling pattern on the vibration levels, it is necessary to carry out more tests.

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Interfacial Features of Colloidal Particles in Aqueous Environment and Change in Its Stability According to Influential Conditions (수중 콜로이드성 고형물의 계면화학적 특성 및 영향 인자 조건에 따른 안정성의 변화)

  • Shin, Sung-Hye;Kim, Dong-Su
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.12
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    • pp.2227-2238
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    • 2000
  • The interfacial features of suspension system made of $CaCO_3$ particles have been investigated for the purpose of designing its effective treatment process. For the examination of variation of electrokinetic potential as a function of pH. the value of potential was observed to shift in the negative direction, which was thought to be due to the adsorption of hydroxide ion on the particle surface. Adsorption of surfactant on suspended particles resulted in the change of surface charge and shift in electrokinetic potential, which was dependent upon the sign of head charge and concentration of surfactant. Addition of inorganic salts affected stability of suspension greatly and sedimentation rate of suspension was influenced by the electric valence and amount of ions produced by dissolution of inorganic coagulants. DLVO theory made it possible to construct a energy profile diagram and a close correlation was found between experimental result and theoretically derived consequences. Non-specific adsorption of indifferent electrolyte resulted in the compression of electrical double layer and specific adsorption induced the shift of IEP and PZC in the opposite direction.

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The Electrochemical Characteristics of Mesopore Active Carbon Fiber for EDLC Electrode (EDLC 전극용 메조기공 활성탄소 섬유의 전기화학적 특성)

  • Kang, Chae-Yoen;Shin, Yun-Sung;Lee, Jong-Dae
    • Korean Chemical Engineering Research
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    • v.49 no.1
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    • pp.10-14
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    • 2011
  • The electrode material performances of electric double layer capacitor(EDLC) were investigated using mesopous active carbon fiber(ACF), which was prepared by the iron exchange method. The mesoporous ACF had pore characteristics of specific surface area around 1249, 664 $m^2$/g, mesoporous fraction around 70.6-81.3% and meanpore size around 2.78-4.14 nm. The results showed that as HNO3 treatment time decreased, the specific surface area increased and mesoporous fraction decreased. To investigate electrochemical performance of EDLC, unit cell was manufactured using mesoporus ACF, conducting material and binder; organic elctrolyte was used on this experiment. The specific capacitance of ACF treated with HNO3 for 2 hours turned out to be 0.47 $F/cm^2$and the results of the cyclic charge-discharge tests were stable. Thus, the electrochemical performance of EDLC was mainly dependent on specific surface area of ACF electrode and the diffusion resistance of charge decreased as the mesopore increased.

The Circular Center Cut with Large Empty Hole & Pre-Splitting in Tunnel Blasting (터널에서 대구경 무장약공과 선균열을 이용한 심빼기 공법에 관한 연구)

  • 김재홍;임한욱
    • Tunnel and Underground Space
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    • v.11 no.3
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    • pp.248-256
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    • 2001
  • The cylindrical cut is most frequently used in tunnel blast regardless of their dimensions. In this study the new parallel cut is proposed to raise advance per round, which is considered to be an elevation of the traditional cylinder cuts. The general geometric pattern of a new cut with parallel blast holes is proposed. The detailed burden and spacing between the central blasthole and those of the four section are also given. The blast results between new cut and traditional cylinder cut are given. The main results of this study are as follows. 1) The average advances per rounds in new cuts can reach 99.5% of drilling length. That of traditional cylinder cuts are known approximately 90∼95% 2) Specific charge weight of new cut compare to that of cylinder cut is approximately reduced 5% from 1.363 to 1.297 kg/㎥ 3) Specific drilling rate is also reduced 8% from 2.393 to 2.130 m/㎥ 4) Vibrations, fly rock, and fragmentation produced by the new blast are to be proved superior to those of the traditional cylinder cuts.

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Improvement on Dyeability of Hanji with Natural Dyes Using a (3-chloro-2-hydroxypropyl) Trimethyl Ammonium Chloride (양이온화 처리 한지의 천연염색성)

  • Yoo, Seung-Il;Oh, Ui-Myeong;Min, Yu-Ri;Choi, Tae-Ho
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.3
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    • pp.88-97
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    • 2011
  • We carried out cationization of Dak pulp (paper mulberry bast fiber pulp) which is raw material of Hanji (Traditional Korean Paper) using a (3-chloro-2-hydroxypropyl) trimethyl ammonium chloride to improve dyeability during a dyeing of Hanji with Gardenia (Gardenia jasminoides) and smoke tree (Cotinus coggygria). Fiber specific charge densities were determined using polyelectrolyte titration method and K/S values of dyed Hanji was calculated by Kubelka-Munk equation. As the result, fiber specific charge density increased with degree of cationization. Colors of Hanji dyed with Gardenia did not vary significantly with degree of cationization, but cationized Hanji dyed with smoke tree showed a large increase of a* value and reddish yellow color. After-mordanting did not decrease K/S value of dyes with cationized Hanji. K/S values of dyed Hanji decreased with increasing dyeing temperature. For smoke tree, the cationization impair lightfastness of dyed Hanji without mordant. After-mordanting with copper acetate or iron chloride improved lightfastness of dyed Hanji.

A Study on Surface Charge Characteristics on Various Plastic Materials for Ttiboelectrostatic Separation of Plastic Wastes (폐플라스틱 정전분리를 위한 하전특성에 관한 연구)

  • 김도균;조희찬;전호석
    • Resources Recycling
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    • v.11 no.3
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    • pp.37-45
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    • 2002
  • Triboelectrostatic Separation procese is a technology that different particles charged after contact and rubbing different materials are separated in an electric field. At this time, charged polarity of different materials depends on their own work function. Therefore this study discovers work functions of various plastics and determines charging characteristics for the specific optimum operation condition. The experiment is conducted with two sample sets composed of various different plastics. Each sample is charged by contact and rubbing different materials. Surface charge of charged particles is measured by Faraday Cage. The specific work function of an each plastic is driven by measured charging amount and charged particles are separated in a certain electric field ($\pm$20 kV). At last, the relationship between charging amount and separation efficiency is induced by the separation experiment.