• Title/Summary/Keyword: Source Site

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Analysis of Organic Molecular Markers in Atmospheric Fine Particulate Matter: Understanding the Impact of "Unknown" Point Sources on Chemical Mass Balance Models

  • Bae, Min-Suk;Schauer, James J.
    • Journal of Korean Society for Atmospheric Environment
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    • v.25 no.3
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    • pp.219-236
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    • 2009
  • Particle-phase organic tracers (molecular markers) have been shown to be an effective method to assess and quantify the impact of sources of carbonaceous aerosols. These molecular markers have been used in chemical mass balance (CMB) models to apportion primary sources of organic aerosols in regions where the major organic aerosol source categories have been identified. As in the case of all CMB models, all important sources of the tracer compounds must be included in a Molecular Marker CMB (MM-CMB) model or the MMCMB model can be subject to biases. To this end, the application of the MM-CMB models to locations where reasonably accurate emissions inventory of organic aerosols are not available, should be performed with extreme caution. Of great concern is the potential presence of industrial point sources that emit carbonaceous aerosols and have not been well characterized or inventoried. The current study demonstrates that emissions from industrial point sources in the St. Louis, Missouri area can greatly bias molecular marker CMB models if their emissions are not correctly addressed. At a sampling site in the greater St. Louis Area, carbonaceous aerosols from industrial point sources were found to be important source of carbonaceous aerosols during specific time periods in addition to common urban sources (i.e. mobile sources, wood burning, and road dust). Since source profiles for these industrial sources have not been properly characterized, method to identify time periods when point sources are impacting a sampling site, needs to avoid obtaining biases source apportionment results. The use of real time air pollution measurements, along with molecular marker measurements, as a screening tool to identify when point sources are impacting a receptor site is presented.

Source Identification of Heavy Metal Contamination at an Industrial Complex Established Using Construction Wastes (건설폐기물을 성토재로 사용한 산업단지에서의 중금속 오염 원인 규명)

  • JOO, Gwonho;KIM, Kibeum;NAM, Kyoungphile;JUNG, Jae-Woong;Moon, Seheum;CHOI, Yongju
    • Journal of Soil and Groundwater Environment
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    • v.23 no.1
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    • pp.54-62
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    • 2018
  • This paper is aimed at source tracking of soil heavy metal contamination at a site established by reusing construction wastes. The soil heavy metal concentration at the study site peaked at a depth range of 5-10 m. Column studies were conducted to investigate the possibility of the contamination scenario of infiltration of stormwater carrying heavy metals of ground origin followed by selective heavy metal accumulation at the 5-10 m depth range. Almost all amount of lead, zinc, cadmium, and nickel introduced to the columns each packed with 0-5 m or 5-10 m field soil were accumulated in the column. The very poor heavy metal mobility in spite of the weak association of the heavy metals with the soil (characterized by a sequential extraction procedure) can be attributed to the high pH (10-11) of the construction wastes. From the results, the heavy metal contamination of the subsurface soil by an external heavy metal source was determined to be very unlikely at the study site. The column study applied in the current study is expected to be a useful methodology to present direct evidence of the contaminant source tracking at soil contamination sites.

A Study on the New Method by EMPLUX for Soil-Remediation(1) (토양오염 복원을 위한 EMPLUX를 사용한 새로운 방법에 대한 연구)

  • Kim, Jung-Sung
    • Journal of Environmental Science International
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    • v.16 no.12
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    • pp.1325-1335
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    • 2007
  • The utility of soil-gas surveys is directly proportional to their accuracy in reflecting and representing changes in the subsurface concentrations of source compounds. Passive soil-gas vapor-phase is merely a fractional trace of the source, so, as a matter of convenience, the units used in reporting detection values from EMFLUX surveys are smaller than those employed for source-compound concentrations. According to the Leaking Underground Storage Tank(LUST) Program Annual Report, approximately 16 U.S. million dollars were spent for environmental site investigations at over 1,600 Underground Storage Tank(UST) sites and approximately over 1,000 acres of land was characterized and remediated in the State of Illinois in the year of 2003 alone. The main purpose of this study is to propose an idea to significantly reduce the site investigation cost by utilizing a passive soil-gas survey and conventional intrusive drilling method and to fully define the three dimensional characteristics of subsurface contamination from two industrial drycleaning facilities.

Radionuclide-Specific Exposure Pathway Analysis of Kori Unit 1 Containment Building Surface

  • Byon, Jihyang;Park, Sangjune;Ahn, Seokyoung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.3
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    • pp.347-354
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    • 2020
  • Site characterization for decommissioning Kori Unit 1 is ongoing in South Korea after 40 years of successful operation. Kori Unit 1's containment building is assumed to be mostly radioactively contaminated, and therefore radiation exposure management and detailed contamination investigation are required for decommissioning and dismantling it safely. In this study, site-specific Derived Concentration Guideline Levels (DCGLs) were derived using the residual radioactivity risk evaluation tool, RESRAD-BUILD code. A conceptual model of containment building for Kori Unit 1 was set up and limited occupational worker building inspection scenario was applied. Depending on the source location, the maximum contribution source and exposure pathway of each radionuclide were analyzed. The contribution of radionuclides to dose and exposure pathways, by source location, is expected to serve as basic data in the assessment criteria of survey areas and classification of impact areas during further decommissioning and decontamination of sites.

The Dynamic Basement Amplification Characteristics of a Dam Site using a Reference Site Method (기준관측소 방법을 이용한 댐체 기반암의 동적 지반증폭특성)

  • Wee, Soung-Hoon;Kim, Jun-Kyoung;Yoo, Seong-Hwa
    • Journal of the Korean earth science society
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    • v.38 no.2
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    • pp.161-171
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    • 2017
  • Observed ground motions are composed of three factors such as, seismic source, attenuation, and site amplification effect. Among them, the site amplification characteristics should be considered significantly when estimating seismic source and attenuation characteristics with more confidence. The site effect is also necessary when estimating not only seismic hazard in seismic design engineering but also rock mechanical properties. This study uses the method of H/V spectral ratio of observed ground motion between target site and reference site called a reference site method. In addition to using the vertical Fourier spectrum of the reference site, we try out the horizontal Fourier spectrum as a new method in this study. We analyze H/V spectral ratio of six ground motions respectively, observed at four sites close to Yedang Reservoir. We then compare site amplification effects at each site using 3 kinds of seismic energies including S waves, Coda waves energy, and background noise. The results suggest that each site showed similar site amplification patterns in S waves and Coda waves energy. However, the site amplification of background noise shows much different characteristics from those of S waves and Coda wave energy, which suggests that the background noises at each site have their own developing mechanism. Each station shows its own characteristics of specific resonance frequency and site amplification properties in low, high and specific resonance frequency ranges. Comparison of the method used in this study to the others that used different methods can provide us with more information about the dynamic amplification of a site characteristics and site classification.

The Association between having a Usual Source of Care and Adherence to Medicines in Patients with Chronic Diseases (만성질환자의 상용치료원 이용과 복약순응도 간의 관계)

  • Jung, Youn;Byeon, Jinok
    • Korean Journal of Clinical Pharmacy
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    • v.26 no.2
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    • pp.128-136
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    • 2016
  • Objective: This study was to explore the association between having a usual source of care and adherence to medicines in patient with chronic diseases. Methods: The 2012 Korea Health Panel was used as a data source. We analyzed 4,418 respondents that were diagnosed with chronic diseases and utilized health care services. Non-adherence to medication, a dependent variable, was defined as "not taking the medicines that were prescribed for treating chronic disease" or "not following the direction for medication". Whether having a usual source of care or not was used as a key independent variable, which was defined as having a regular site or a regular doctor for medical test, treatment, and consultation. Sex, age, education level, marital status, income, the type of health insurance, the number of chronic disease and CCI (Charlson Comorbidity Index) were included as covariates in the analysis. We conducted a multivariate logistic regression. Results: Totally, 30 percent of respondents reported to experience non-adherence to medication. Having a usual source of care was significantly associated with lower non-adherence to medication regardless its type, which is a regular doctor (OR=0.61, 95% CI=0.53-0.70) or a regular site (OR=0.67, 95% CI=0.58-0.78). Furthermore, having a usual source of care was associated with both of medication persistence (OR=0.66, 95% CI=0.54-0.81) and compliance (OR=0.65, 95% CI=0.56-0.76). Conclusion: Our results showed the possibility that usual source of care is able to conduct a positive role in improving adherence to medication with better management of chronic disease.

Influence of Surface Heterogeneity on Turbulent Transfer in the Surface Layer (지표면의 비균질성이 지표층의 난류수송에 미치는 영향)

  • Hong, Seon-Ok;Lee, Young-Hee;Lim, Yoon-Jin
    • Atmosphere
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    • v.24 no.3
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    • pp.317-329
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    • 2014
  • Eddy covariance data have been analyzed to investigate the influence of surface heterogeneity on turbulent transfer over farmland and industrial sites near Nakdong river, Korea, where both large and small scale heterogeneities co-exist. For this purpose, basic turbulent statistics, quadrant analysis and multi-resolution decomposition have been analyzed during the daytime. Basic turbulent statistics were compared with typical turbulent statistics in the surface layer. Such comparisons were in close agreement for momentum and heat at both sites but not for water vapor at industrial site. The correlation coefficient between water vapor and vertical velocity ($r_{wq}$) is relatively low and skewness of water vapor ($sk_q$) is very low at industrial site, possibly due to limited water source. For heat at both sites and water vapor at farmland, the quadrant analysis show similar behavior to that over homogeneous site but for water vapor at industrial site, the presence of river and limited water source at industrial site seems to influence on water vapor transfer by coherent eddy motion by increasing sweep contribution and decreasing ejection contribution. Multi-resolution decomposition analysis shows that large scale heterogeneity leads to low $r_{Tq}$ at large averaging time regardless of season at both sites and there are seasonal changes of $r_{Tq}$ in mid-averaging times at industrial site, possibly due to seasonal change of trees and grasses near the site.

Application of In Situ Measurement for Site Remediation and Final Status Survey of Decommissioning KRR Site

  • Hong, Sang Bum;Nam, Jong Soo;Choi, Yong Suk;Seo, Bum Kyoung;Moon, Jei Kwon
    • Journal of Radiation Protection and Research
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    • v.41 no.2
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    • pp.173-178
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    • 2016
  • Background: In situ gamma spectrometry has been used to measure environmental radiation, assumptions are usually made about the depth distribution of the radionuclides of interest in the soil. The main limitation of in situ gamma spectrometry lies in determining the depth distribution of radionuclides. The objective of this study is to develop a method for subsurface characterization by in situ measurement. Materials and Methods: The peak to valley method based on the ratio of counting rate between the photoelectric peak and Compton region was applied to identify the depth distribution. The peak to valley method could be applied to establish the relation between the spectrally derived coefficients (Q) with relaxation mass per unit area (${\beta}$) for various depth distribution in soil. The in situ measurement results were verified by MCNP simulation and calculated correlation equation. In order to compare the depth distributions and contamination levels in decommissioning KRR site, in situ measurement and sampling results were compared. Results and Discussion: The in situ measurement results and MCNP simulation results show a good correlation for laboratory measurement. The simulation relationship between Q and source burial for the source layers have exponential relationship for a variety depth distributions. We applied the peak to valley method to contaminated decommissioning KRR site to determine a depth distribution and initial activity without sampling. The observed results has a good correlation, relative error between in situ measurement with sampling result is around 7% for depth distribution and 4% for initial activity. Conclusion: In this study, the vertical activity distribution and initial activity of $^{137}Cs$ could be identifying directly through in situ measurement. Therefore, the peak to valley method demonstrated good potential for assessment of the residual radioactivity for site remediation in decommissioning and contaminated site.

A Study on Runoff Properties of Non-point Pollutant in Nakdong watershed by using SWAT model (SWAT 모형을 이용한 낙동강 하구언의 비점오염물질 유출특성 규명)

  • Lee, Eun-Jeong;Choi, Kyoung-Sik;Kim, Tae-Keun
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.6
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    • pp.815-823
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    • 2012
  • Non-point source pollutants in down stream of Nakdong river were simulated by SWAT. GIS was utilized to make input data of SWAT such as landuse pattern and soil. Meteorological data of 2007 and 2009 were applied for the calibration and validation of runoff in SWAT. It was difficult to calibrate and validate the runoff and nutrient results since a study area was influenced by the tidal effects. Jindong site was selected to escape from the bias of runoff simulation in the coastal area. $R^2$ values of calibration and validation were 0.8 and 0.79. However, $R^2$ values of water qualities were very low level in comparison to runoff. These resulted from the concentration scale of water qualities such as BOD, T-N and T-P. Additionally, tidal influence could effected on the measurements of nutrients. The simulated annual averages and patterns of BOD, T-N and T-P in SWAT were similar to the measurement data. 80 ~ 96 % of nonpoint source pollutants at Nakbon M site were released from April to August of 2009. The ratio of T-N and T-P from nonpoint source were above 50 % during the rainy season.