• Journal of the Mineralogical Society of Korea
• /
• v.11 no.2
• /
• pp.106-116
• /
• 1998

The adsorption of Cs-137 and Sr-90 onto kaolinite in prescence of major groundwater cations (Ca2+, K+, Na+) with different concentrations was simulated by using triple-layer surface complexation model (TL-SCM). The site density (8.73 sites/nm2) of kaolinite used for TL-SCM was calculated from it's CEC and specific surface area. TL-SCM modeling results indicate that concentrations dependence on 137Cs and 90Sr adsorption onto kaolinite as a function of pH is best modeled as an outer-sphere surface reaction. This suggests that Cs+ and Sr2+ are adsorbed at the $\beta$-layer in kaolinite-water interface where the electrolytes, Nacl, KCl and CaCl2, bind. However, TL-SCM results on Sr adsorption show a discrepancy between batch data and fitting data in alkaline condition. This may be due to precipitation of SrCO3 and complexation such as SrOH+. Intrinsic reaction constants of ions obtained from model fit are as follows: Kintcs=10-2.10, KintSr=10-2.30, KintK=10-2.80, KintCa=10-3.10 and KintNa=10-3.32. The results are in the agreement with competition order among groundwater ions (K+>Ca2+>Na+) and sorption reference of nuclides (Cs-137>Sr-90) at kaolinite-water interface showed in batch test.

• Environmental Engineering Research
• /
• v.10 no.6
• /
• pp.294-305
• /
• 2005

The effectiveness of fly ash-, quicklime-, and quicklime-fly ash-based stabilization/solidification(S/S) in chromium(Cr) contaminated soils was investigated using modified semi-dynamic leaching tests. Artificial soil samples composed of kaolinite or montmorillonite contaminated with chromium nitrate(4000 mg $Cr^{3+}\;kg^{-1}$ of solid) were prepared and then subjected to S/S treatment using quicklime, fly ash, or quick lime-fly ash. The effectiveness of the treatment was evaluated by assessing the cumulative fraction of leached $Cr^{3+}$ as well as, by computing the effective diffusivity ($D_e$) and the leachability index (LX) of the treated samples. The reduction in $Cr^{3+}$ release for the untreated samples was more pronounced in the presence of montmorillonite, which was attributed to sorption. Treatment with quicklime, fly ash, or quick lime-fly ash was significantly effective in reducing $Cr^{3+}$ release most probably due to the formation of pozzolanic reaction products and $Cr(OH)_3$ precipitation. The most effective treatment was observed in montmorillonite-sand soil samples treated with quicklime-fly ash (99.8% removal). The mean $D_e$ decreased significantly and the mean LX was greater than 9 for all treated samples, indicating that the treated soils were acceptable for "controlled utilization". The mechanism controlling $Cr^{3+}$ leaching from all treated samples during the first 5 days appeared to be diffusion.

• Journal of Korean Society of Environmental Engineers
• /
• v.33 no.6
• /
• pp.426-431
• /
• 2011

The objective of this study was to investigate the virus removal from artificial groundwater using Mg-Fe layered double hydroxide (LDH). Batch experiments were conducted under various experimental conditions to examine bacteriophage T7 removal with Mg-Fe LDH. Results showed that the removal of T7 by Mg-Fe LDH was a fast process, reaching equilibrium within 2~3 hrs. Mg-Fe LDH had the virus removal capacity of $1.57{\times}10^8pfu/g$ with a removal percent of 96%. Results also showed that the effect of solution pH on T7 removal was minimal between pH 6.2 and 9.1. The influence of anions ($SO_4^{2-}$, $CO_3^{2-}$, $HPO_4^{2-}$) on T7 removal was significant due to their competition with bacteriophage at the sorption sites on LDH, while the effect of $NO_3^-$ was negligible. This study demonstrated that Mg-Fe LDH could be applied as adsorbents for virus removal in water treatment.

• Journal of the Mineralogical Society of Korea
• /
• v.27 no.4
• /
• pp.271-281
• /
• 2014

The physicochemical properties of clay minerals have been investigated at the atomistic to nano scale. The microscopic studies are often challenging to perform by using experimental approaches alone. In particular, hydroxyl groups of octahedral sheets in 2:1 clay minerals have been hypothesized to impact the sorption process of metal cations; however, X-ray based techniques alone, a common tool for mineral structure examination, cannot properly test the hypothesis. The current study has examined whether computational mineralogy techniques can be applied to examine the hydroxyl structures of clay minerals. Based on quantum-mechanics and molecular-mechanics computational methods, geometry optimizations were carried out for representative dioctahedral and trioctahedral phyllosilicate minerals. Both methods well reproduced the experimental lattice parameters; however, for structural distortion occurring in the tetrahedral or octahedral sheets, molecular mechanics showed significant deviations from experimental data. The orientation angle of the hydroxyl with respect to (001) basal plane is determined by the balance of repulsion between the hydroxyl proton and Si cations of tetrahedral sites; the quantum-mechanics method predicted $25-26^{\circ}$ for the angle, whereas the angle predicted by the molecular-mechanics method was much higher by $10^{\circ}$ (i.e., $35^{\circ}$). These results demonstrate that computational mineralogy techniques are a reliable tool for clay mineral studies and can be used to further elucidate the roles of hydroxyls in metal sorption process.

• Journal of Korean Society of Environmental Engineers
• /
• v.39 no.1
• /
• pp.26-33
• /
• 2017

The objective of this study was to evaluate the characteristic of adsorption by using a meso-porous adsorbent (MPA), and investigate the removal efficiency of geosmin which taste and odor causing compounds in drinking water supplies through batch test. The results for the adsorption isotherm was analyzed by using the Langmuir equation and Freundlich equation, generally being applied. And the study showed that the both Langmuir and Freundlich equation explains the results better. Both of pseudo-first-order model and pseudo-second-order model were respectively applied for evaluation of kinetic sorption property of geosmin onto MPA. The adsorption experiment results using MPA showed that maximum adsorption capacity of MPA was lower 7 times than that of GAC, and adsorption rate of MPA was faster 11 times than that of GAC, on the basis of pseudo-first-order model. Therefore, it was determined that MPA was effectively able to remove geosmin in drinking water supplies in short EBCT condition, but regeneration cycle in MAP process was shorter than that in conventional process.

• Journal of the Korean Geotechnical Society
• /
• v.37 no.7
• /
• pp.35-42
• /
• 2021

An experimental study was carried out on kaolinite-sand mixtures with various proportions of kaolinite content. To investigate physical behaviour of mixtures, index properties and compaction test results were analysed in various aspects. Moreover, to clearly see the interaction between kaolinite and sand particles, the observational analysis through microscopic image analysis device was conducted. The test results showed that an increase in the amount of kaolinite could create a strong bonding structure which resulted in higher specific surface available for activities of kaolinite particles. Also, an increase in the amount of the kaolinite resulted in an increase in the percentage of water sorption. Then it could accelerate the occupation rate of water which tended to take up the space that would have been occupied by solid particles, and accordingly, resulted in the decreased maximum dry unit weight and increased initial void ratio. Based on the microscopic image analysis, the samples were individually classified into three types of mixture such as sand dominant, intermediate fine content, and fine dominant. In addition, the fine and coarse grains seem to interact well in the mixtures with the fine content ranging from 25 to 40%.

• Journal of the Mineralogical Society of Korea
• /
• v.16 no.4
• /
• pp.283-293
• /
• 2003

Domestic water treatment plants operate the rapid and slow filtering system using the filtering sands. Most of them are composed of beach sands, which have less sorption capacity of heavy metals as well as organic contaminants. Therefore, the development of fortified functional filtering materials with high removal capacity of organic and inorganic contaminants is needed to prevent the unexpected load of contaminated source water. This study aims to test the hydrochemical change and the removing capacity of heavy metals such as Cd, Cu, and Pb on the Jumunjin sand, feldspathic sand(weathering product of Jecheon granite), feldspathic mixing sand I(feldspathic sand mixed with 10 wt% zeolite), and feldspathic mixing sand II (feldspathic sand mixed with 20 wt% zeolite). Feldspathic mixing sand I and II showed the eruption of higher amounts of cations and anions compared with the Jumunjin sand and feldspathic sand. They also showed higher eruption of Si, Ca, $SO_4$ ions than that of Al, $NO_3$, Fe, K, Mg, and P. Feldspathic mixing sand II caused higher eruption of some cations of Na, Ca, Al than feldspathic mixing sud I, which is the result controlled by the dissolution of zeolite. Jumunjin sand and feldspathic sand showed very weak sorption of Cd, Cu and Pb. In contrast to this, feldspathic mixing sand I and II showed the high sorption and removal capacity of the increasing order of Cd, Cu and Pb. Feldspathic mixing sand II including 20% zeolite showed a fortified removal capacity of some heavy metals. Therefore, feldspathic mixing sand mixed with some contents of zeolite could be used as the fortified filtering materials for the water filtering and purification in the domestic water treatment plants.

• Journal of the Korean Society of Groundwater Environment
• /
• v.6 no.2
• /
• pp.95-100
• /
• 1999

Hydrocarbon compounds in vadose zone soils caused by adsorption onto the surfaces of solid particles are generally considered to show retardation effect. In this study, we investigated the retardation effect on the transport of Benzene in a sandy soil by conducting batch and column tests. The batch test was conducted by equilibrating dry soil mass with Benzene solutions of various initial concentrations. and by analyzing the concentrations of Benzene in initial and equilibrated solutions using HPLC. The column test consisted of monitoring the concentrations of effluent versus time known as a breakthrough curve (BTC). We used KCl and Benzene solutions with the concentration of 10 g/L and 0.88 g/L as a tracer, and injected them into the inlet boundary of the soil sample as a square pulse type respectively, and monitored the effluent concentrations at the exit boundary under a steady state condition using an EC-meter and HPLC. From the batch test, we obtained a distribution coefficient assuming that a linear adsorption isotherm exists and calculated the retardation factor based on the bulk density and porosity of the column sample. We also predicted the column BTC curve using the retardation factor obtained from the distribution coefficient and compared with the measured BTC of Benzene. The results of the column test showed that i) the peak concentration of Benzene was much smaller than that of KCl and ⅱ) the travel times of peak concentrations for the two tracers were more or less identical. These results indicate that adsorption of Benzene onto the sand panicles occurred during the pulse propagation but the retardation of Benzene caused by adsorption was not present in the studied soil. Comparison of the predicted with the measured BTC of Benzene resulted in a poor agreement due to the absence of the retardation phenomenon. The only way to describe the absolute decrease of Benzene concentration in the column leaching experiment was to introduce a decay or sink coefficient in the convection-dispersion equation (CDE) model to account for an irreversible sorption of Benzene in the aqueous phase.

• Journal of the Korean Geotechnical Society
• /
• v.27 no.10
• /
• pp.5-12
• /
• 2011

This study was focused on the reactivity of furnace slag against cadmium to design the vertical drain method with reactive column for improving contaminated sea shore sediment. The kinetic sorption test was performed by changing the initial concentration and pH. Using pseudo-second-order model, the reactivity of furnace slag was quantitatively analyzed. Equilibrium removal amount ($q_e$) of furnace slag increased and rate constant ($k_2$) decreased with the increase of initial cadmium concentration. With the increase of pH, the equilibrium removal amount ($q_e$) and rate constant ($k_2$) increased in the same initial concentration. Required retention time was related to the inverse of the product of the equilibrium removal amount ($q_e$) multiplied by rate constant ($k_2$). The required retention time could be used to design the length of reactive column.

• Asian Journal of Atmospheric Environment
• /
• v.10 no.2
• /
• pp.99-113
• /
• 2016

In order to improve the portability of basic absorbents monoethanolamine (MEA) and glycine (Gly), both were supported on microporous activated carbon (AC). Chemical modification by alkali-metal ion exchange (of Li, Na, K) was carried out on Gly-based absorbents. All supported absorbents were subjected to $CO_2$ absorption capacity (pure $CO_2$) and selectivity (indoor level) tests. Textural and chemical characterizations were carried out on test sorbents. All impregnation brought about significant reduction of specific surface area and microporosity of the adsorbent Depreciation in the textural properties was found to result to reduction in pure $CO_2$ sorption. Contrarily, low-level $CO_2$ removal capacity was enhanced as the absorbent dosage increases, resulting in supported 5 molar MEA in methanol solution. Adsorption capacities were improved from 0.016 and 0.8 in raw ACs to 1.065 mmol/g for MEA's. Surface chemistry via X-ray photoelectron spectroscopy (XPS) of the supported sorbents showed the presence of amine, pyrrole and quaternary-N. In reducing sequence of potency, pyridine, amine and pyrrolic-N were noticed to contribute significantly to $CO_2$ selective adsorption. Furthermore, the adsorption isotherm study confirms the presence of various SNGs heterogeneously distributed on AC. The adsorption mechanism of the present AC adsorbents favored Freundlich and Langmuir isotherm at lower and higher $CO_2$ concentrations respectively.