• Title/Summary/Keyword: Sorption in a rock matrix

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Travel Times of Radionuclides Released from Hypothetical Multiple Source Positions in the KURT Site (KURT 환경 자료를 이용한 가상의 다중 발생원에서의 누출 핵종의 이동 시간 평가)

  • Ko, Nak-Youl;Jeong, Jongtae;Kim, Kyung Su;Hwang, Youngtaek
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.11 no.4
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    • pp.281-291
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    • 2013
  • A hypothetical repository was assumed to be located at the KURT (KAERI Underground Research Tunnel) site, and the travel times of radionuclides released from three source positions were calculated. The groundwater flow around the KURT site was simulated and the groundwater pathways from the hypothetical source positions to the shallow groundwater were identified. Of the pathways, three pathways were selected because they had highly water-conductive features. The transport travel times of the radionuclides were calculated by a TDRW (Time-Domain Random Walk) method. Diffusion and sorption mechanisms in a host rock matrix as well as advection-dispersion mechanisms under the KURT field condition were considered. To reflect the radioactive decay, four decay chains with the radionuclides included in the high-level radioactive wastes were selected. From the simulation results, the half-life and distribution coefficient in the rock matrix, as well as multiple pathways, had an influence on the mass flux of the radionuclides. For enhancing the reliability of safety assessment, this reveals that identifying the history of the radionuclides contained in the high-level wastes and investigating the sorption processes between the radionuclides and the rock matrix in the field condition are preferentially necessary.

A Control Volume Scheme for Three-Dimensional Transport: Buffer and Matrix Effects on a Decay Chain Transport in the Repository

  • Lee, Y.M.;Y.S. Hwang;Kim, S.G.;C.H. Kang
    • Nuclear Engineering and Technology
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    • v.34 no.3
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    • pp.218-231
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    • 2002
  • Using a three-dimensional numerical code, B3R developed for nuclide transport of an arbitrary length of decay chain in the buffer between the canister and adjacent rock in a high- level radioactive waste repository by adopting a finite difference method utilizing the control- volume scheme, some illustrative calculations have been done. A linear sorption isotherm, nuclide transport due to diffusion in the buffer and the rock matrix, and advection and dispersion along thin rigid parallel fractures existing in a saturated porous rock matrix as well as diffusion through the fracture wall into the matrix is assumed. In such kind of repository, buffer and rock matrix are known to be important physico-chemical harriers in nuclide retardation. To show effects of buffer and rock matrix on nuclide transport in HLW repository and also to demonstrate usefulness of B3R, several cases of breakthrough curves as well as three- dimensional plots of concentration isopleths associated with these two barriers are introduced for a typical case of decay chain of $^{234}$ Ulongrightarrow$^{230}$ Thlongrightarrow$^{226}$ Ra, which is the most important chain as far as the human environment is concerned.

A Theoretical Study on the Colloid-facilitated Radionuclide Transport with Decay Chain in the Fractured Rock (균열암반에서 방사성 붕괴사슬과 콜로이드를 동반한 방사성 핵종의 이동에 관한 이론적 연구)

  • 박진백;황용수;강철형
    • Tunnel and Underground Space
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    • v.13 no.1
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    • pp.20-32
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    • 2003
  • To understand the behavior of migration of contaminants in a fractured porous medium is a key to assure the overall safety of a potential radwaste repository. The feasible retention mechanism of contaminant transport in a tinctured medium are sorption of contaminants on solid surface and matrix diffusion of contaminants from a fracture into an adjacent porous medium. The acceleration mechanisms are the migration of contaminants in the form of pseudo-colloids and the limit of a volume f3r matrix diffusion. In this paper, the effects of these two acceleration mechanisms are studied mathematically, then semi-analytically computed by the application of the Talbot theorem and verified. Results indicate that the acceleration processes cannot be neglected in the modeling of contaminant transport in a fractured porous medium.

Migration of THO & Np in a Fractured Granite Core at Deep Underground Laboratory

  • PARK Chung-Kyun;CHO Won-Zin;HAHN Pil-Soo;KIENZLER B.
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.255-263
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    • 2005
  • Migration experiments of THO and 237Np have performed through a sampled granite core in Chemlab2 probe at the Aspo hard Rock laboratory. The elution curves of THO were analysed to determine hydraulic properties such as the extent of dispersion effect according to flow rates. The retardation phenomena of the solutes were observed and described with elution curves and migration plumes. After migration test, the rock core was opened, and the remaining radioactivities on the rock fracture surfaces were measured. The transport process was simulated with a two-dimensional channel model. The mass transport process was described with three types of basic processes ; advection, sorption and matrix diffusion. By the combination of these processes, effects of each process on transport were described in terms of elution curves and migration plumes. By comparing the simulation results to the experimental one, it was possible to analyse the retardation effect quantitatively.

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Influence of EDZ on the Safety of a Potential HLW Repository

  • Hwang Yong-Soo;Kang Chul-Hyung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.4
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    • pp.253-262
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    • 2004
  • Construction of tunnels in a deep crystalline host rock for a potential High-Level Radioactive Waste(HLW) repository inevitably generates an excavation disturbed zone (EDZ). There have been a series of debates on whether a permeability in an EDZ increases or not and what would be the maximum depth of an EDZ. Recent studies show mixed opinions on permeability. However, there has been an international consensus on the thickness of an EDZ; 30 cm for TBM and 1 meter for controlled blast. One of the impacts of an EDZ is on determining the distance between adjacent deposition holes. The void gap by the excavation hinders relaxation of temperature profiles so that the current Korean reference designing distance between holes should be stretched out more to keep the maximum temperature in a buffer region below 100 degrees Celsius. The other impact of an EDZ is on the long-term post closure radiological safety. To estimate the impact, the reference scenario, the well scenario, is chosen. Released nuclides diffuse through a bentonite buffer region experiencing strong sorption and reach a fracture surrounded by a porous medium. Inside a fractured porous region, radionuclides migrate by advection and dispersion with matrix diffusion into a porous medium. Finally, they reach a well assumed to be a source of potable water for local residents. The annual individual dose is assessed on this well scenario to find out the significance of an EDZ. A profound sensitivity study was performed, but all results show that the impact is negligible. Even though the role of an EDZ turns out to be limited on overall safety assessment, still it is worthwhile to study the chemical role of an EDZ, such as a potential source for natural colloids, potential sealing of an open fracture by fine clay particles generated by the process of an EDZ, and alteration of a sorption mechanism by an EDZ in the future.

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Study on Radionuclide Migration Modelling for a Single Fracture in Geologic Medium : Characteristics of Hydrodynamic Dispersion Diffusion Model and Channeling Dispersion Diffusion Model (단일균열 핵종이동모델에 관한 연구 -수리분산확산모델과 국부통로확산모델의 특성-)

  • Keum, D.K.;Cho, W.J.;Hahn, P.S.;Park, H.H.
    • Nuclear Engineering and Technology
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    • v.26 no.3
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    • pp.401-410
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    • 1994
  • Validation study of two radionuclide migration models for single fracture developed in geologic medium the hydrodynamic dispersion diffusion model(HDDM) and the channeling dispersion diffusion model(CDDM), was studied by migration experiment of tracers through an artificial granite fracture on the labolatory scale. The tracers used were Uranine and Sodium lignosulfonate know as nonsorbing material. The flow rate ranged 0.4 to 1.5 cc/min. Related parameters for the models were estimated by optimization technique. Theoretical breakthrough curves with experimental data were compared. In the experiment, it was deduced that the surface sorption for both tracers did not play an important role while the diffusion of Uranine into the rock matrix turned out to be an important mass transfer mechanism. The parameter characterizing the rock matrix diffusion of each model agreed well The simulated result showed that the amount of flow rate could not tell the CDDM from the HDDM quantitatively. On the other hand, the variation of fracture length gave influence on the two models in a different degree. The dispersivity of breakthrough curve of the CDDM was more amplified than that of the CDDM when the fracture length was increased. A good agreement between the models and experimental data gave a confirmation that both models were very useful in predicting the migration system through a single fracture.

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