• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.4 no.1
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• pp.11-16
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• 1997

Sorption studies involving the sorption of n-propanol by an Amorphous Nylon(Nylon 6I/6T) were carried out as a function of sorbate vapor activity at $23^{\circ}C$. Vapor activity levels from 0.035 to 0.91 were investigated to evaluate the concentration dependency of sorption mechanism. Sorption behavior of propanol by Nylon 6I/6T showed distinctive two mode sorption phenomena as a function of Vapor activity. At Vapor activity levels below a=0.11, equilibrium sorption was achieved within a short period of time(less than 20hrs), which can be interpreted as following a Fickian diffusion model. A Langmuir-Flory-Muggins Dual Mode Sorption model can also be applied at these concentration levels. However, for Vapor activities above a=0.11, the sorption process appeared to be non-Fickian and resulted in a lack of equilibrium being attained.

• Journal of the Korean Geotechnical Society
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• v.24 no.6
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• pp.17-25
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• 2008

Permeable reactive barriers (PRBs) technology can be applied to contaminated groundwater remediation. It is necessary to select adequate reactive material according to contaminant characterization. In groundwater. In this research, the reaction between reactive material and heavy metal contaminants was estimated through batch test. Reactive material was slag, which has been produced in Gwangyang power plant, and heavy metal contaminants were cadmium, lead and copper. Batch test consisted of two testes: 1) sorption equilibrium test and 2) sorption kinetic test. Sorption equilibrium test was performed for estimating slag sorption capacity against contaminants. And sorption kinetic test was performed for slag sorption rate with contaminants species, contaminants initial concentration and sulfate. Sorption capacity and sorption rate were affected by contaminant species. Sorption rate increased with increasing initial concentration in lead and copper but decreased with increasing initial concentration in cadmium. Sorption rate increased in existing sulfate. In low concentration, film diffusion was domain mechanism, and in high concentration, particle diffusion was domain mechanism.

• Korean Journal of Food Science and Technology
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• v.28 no.6
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• pp.1146-1150
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• 1996

The purpose of this research was to provide fundamental data required for the process design of conveying, storage and processing of food powders. Potato starch, corn starch, wheat protein, soybean protein, and model food powders prepared by mixing potato starch and wheat protein were selected and their sorption characteristics such as equilibrium moisture content, monolayer moisture content, and sorption enthalpy were determined. Equilibrium moisture content and monolayer moisture content of high starch powders were higher than those of high protein powders, and the equilibrium moisture content decreased with temperature. The determination coefficients of the regression equations to predict the equilibrium moisture content of food powders were from 0.997 to 0.999. Sorption enthalpy experiments indicated that powder of high moisture content showed lower sorption than that of low· moisture content, and the high protein powder showed lower sorption than high starch powder.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.09a
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• pp.302-305
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• 2002

Scoria is a bomb-sized, generally vesicular pyroclast that is red or black in color and light in weight. In this study, scoria from Cheju was examined for the use as a sorbent. It is composed of plagioclase, olivine, hornblende, pyroxene, and glass, with an average composition of 49.84% SiO$_2$, 14.07% A1$_2$O$_3$, End 9.14% Fe$_2$O$_3$. Studies on kinetic isotherm sorption of Zn(II) onto scoria under various parameters such as initial zinc concentration, particle size, and adsorbent/adsorbate ratio were carried out using an agitated batch. The results suggest that the smaller scoria size and the larger adsorbent/adsorbate ratio produce the higher degree of Zn(II) removal. More effective removal also appears at lower initial Zn concentration. The sorption behavior of Zn(II) onto scoria seems to be mainly controlled by cation exchange. Studies on equilibrium isotherm sorption of other heavy metals (Pb, Cu, Cd) onto scoria were also conducted and compared with those onto powdered activated carbon (PAC) and non-organic matter scoria (NOS), The results suggest that the Cheju scoria has the slightly higher sorption capability than PAC and NOS, and the order of the effective sorption onto scoria and PAC is Pb > Cu > Zn > Cd. The monometal sorption onto scoria is more stronger than the competitive sorption.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.380-383
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• 2004

Heavy metal release from wastewater is a serious environmental problem, and therefore, various wastewater treatment techniques have been developed. Among the techniques, sorption technique is most attractive. Considerable researches have been recently focused on finding out inexpensive sorbents, especially from various natural materials. In order to evaluate the applicability of the scoria taken from the Jeju Island, Korea to remove heavy metals (Pb, Cu, Zn, Cd) from aqueous solutions, equilibrium sorption experiments were conducted in this study. In equilibrium tests, powdered activated carbon (PAC), one of the most commonly used sorbents, was also tested to compare the effectiveness of the Jeju scoria with that of PAC. The Jeju scoria had larger adsorption capacity and affinity for metal ions (Pb(II), Cu(II), Zn(II), Cd(II)) than PAC. The sorption parameters of the two sorbents were evaluated by using both the Langmuir and Freundlich isotherms, and the sorption data were better fitted to the Freundlich isotherm. In addition, the sorption behavior of metal ions (Pb(II), Cu(II), Zn(II), Cd(II)) onto the scoria displayed a typical characteristic of the cation sorption. The removal of metal ions decreased at a lower pH condition due to competition with hydrogen ions for the sorption sites of Jeju scoria, while the removal increased at a high pH condition due to hydroxide precipitation.

• Journal of the Korea Furniture Society
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• v.19 no.1
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• pp.75-82
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• 2008

A series of the studies on the applied physical properties of main domestic species have been conducted last three years. Equilibrium moisture content(EMC) of Pinus koraiensis, Larix kaemferi, Pinus koraiensis were investigated. The experiments for sorption property were conducted with 20- and 80-mesh wood powder and resulted in their EMC's at various sorption conditions. Amount of moisture sorption and sorption speed of Larix kaemferi were shown the most large values and very fast among three Korean main coniferous wood.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.10
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• pp.1043-1051
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• 2005

In this stduy, adsorption and transport characteristics of Fe in the soil were investigated using convection-dispersion local equilibrium sorption model and two-site non-equilibrium sorption model. In batch experiments with different Fe concentration, characteristics of Fe adsorption was investigated using Freundlich and linear isotherm. Column experiments with different flow rate, organic matter content md Fe concentration were also carried out. We measured Fe concentrations in injection-liquid and in effluent, and then applied them to CXTFIT program. As a result of column experiments, some parameters(D, R, ${\beta}$, ${\omega}$) used in two-site non-equilibrium adsorption model were obtained. Characteristics of Fe transport were analyzed using the parameters(D, R, ${\beta}$, ${\omega}$) obtained from the CXTFIT program, Consequently, characteristics of Fe transport in the soil were predicted through two-site non-equilibrium adsorption model.

• Journal of the Korean Society of Tobacco Science
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• v.26 no.1
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• pp.43-49
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• 2004

This study was carried out to investigate moisture sorption and desorption characteristics followed by tobacco type. Experiments were performed at various temperature(5, 15, 25, 40 $^{\circ}C$) and relative humidity range (11～84 %) controlled by saturated salt solution. Regression equation was obtained to predict equilibrium moisture according to various relative humidity, temperature and tobacco types. The obtained regression equation showed high $R^2$(above 0.95) and predicted accurate equilibrium moisture. Equilibrium moisture contents declines in the following order when a relative humidity is 50 % or above: expanded stem, flue-cured, expanded tobacco, reconstituted tobacco, USA flue-cured, orient, burley. To maintain 13 % moisture of each tobacco type in the range of 5～40 $^{\circ}C$ it is recommendable to control relative humidity 49～56 % for expanded stem, 50～57 % for flue-cured, 54～61 % for USA flue-cured, 56～60 % for reconstituted tobacco, 57～62 % for expanded tobacco, 58～64 % for orient and 58～65 % for burley, respectively. It means that the relative humidity of each tobacco type should be differently controlled to maintain the same moisture under the same temperature. In the range of 5～25 $^{\circ}C$, the lower temperature showed the higher equilibrium moisture content.

• Nuclear Engineering and Technology
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• v.32 no.4
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• pp.342-349
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• 2000

A soil whose texture is silt loam was collected for the study from an area around a nuclear facility in Korea. The equilibrium sorption coefficient between Co$^{2+}$in water and the soil was 1.51/kg, on the other hand, that between Co$^{2+}$ in EDTA and the soil was 0.21/kg. The values calculated by the developed nonequilibrium sorption code corresponded to the experimental values better than those calculated by the existing equilibrium sorption code. When an EDTA solution was used as a solvent to decontaminate Co$^{2+}$ in the soil column, the relative Co$^{2+}$ concentrations of the effluent were higher at 2~10 pore volumes than those of the case using water. The soil in the column was decontaminated by 95.5% of the total amount of Co$^{2+}$ after being flushed with EDTA solution of 20 pore volumes.e volumes.

• Journal of Ginseng Research
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• v.5 no.1
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• pp.1-7
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• 1981

A study was designed to study the sorption characteristics of powder-type products of red ginseng such as red ginseng tea, red ginseng powder and spray 4ried powder of red ginseng extract The sorption rates and equilibrium moisture contents on these products were calculated at ova. a range of relative himidities and two different temperatures ($25^{\circ}C$ and 38$^{\circ}C$). Significant differences between these three products were found in water activities, sorption rates and the relationship between the ratio of %H2O/RH and moisture content The red ginseng tea required the most excessive drying to reach aw=0.4, followed by red ginseng power and spray dried powder of red ginseng extract Attempt was made to obtain equations which can predict sorption rate and moisture content of red ginseng products at given relative humidity and temperature after certain period of storage.