• 제목/요약/키워드: Soot Formation and Oxidation

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압력조건에서 공기로 희석된 프로판 확산화염의 매연 생성과 산화 특성 (Soot Formation and Oxidation in Air-Diluted Propane Diffusion Flames under Elevated Pressures)

  • 배승만;남연우;이원남
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2012년도 제44회 KOSCO SYMPOSIUM 초록집
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    • pp.267-268
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    • 2012
  • Soot formation and oxidation characteristics of air-diluted propane diffusion flames have been experimentally investigated under the elevated pressure conditions. PAH concentrations showed more pressure sensitive behavior comparing to soot volume fractions. The flame/soot temperatures in soot oxidation region were obtained using the MOLLIP technique. Under the complete soot oxidation environment, the flame/soot temperature is increased with pressure. The increased temperature could accelerate the soot oxidation process and then exothermic oxidation reaction, in turn, could further raise the flame/soot temperature, which would result in the enhancement of soot oxidation process.

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화염편모델을 이용한 층류확산화염장의 매연 생성 및 산화과정 해석 (Flamelet Modelling of Soot Formation and Oxidation in a Laminar $CH_4$-Air Diffusion Flame)

  • 김군홍;김후중;김용모;김성구
    • 한국연소학회:학술대회논문집
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    • 대한연소학회 2003년도 제27회 KOSCO SYMPOSIUM 논문집
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    • pp.3-9
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    • 2003
  • By utilizing a semi-empirical soot model, the applicability of the laminar flamelet concept for simulating the formation and oxidation of soot in the laminar diffusion flame has been studied. The source terms for two transport equations of the soot formation and oxidation are calculated in the mixture fraction/scalar dissipation rate space for laminar flamelets and stored in a library. In this study, emphasis is given to the interaction associated with radiation and soot formation. The radiative heat loss is obtained by solving the radiative transfer equation using the unstructured grid finite volume method with the WSGGM. The calculated temperatures and soot volume fractions agree relatively well with the experimental data and the previous numerical results of Kaplan et al. using the detailed chemistry.

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레이저 가열 위치에 따른 확산화염의 매연생성 및 산화 특성 변화 (The Effects of Laser Heating on the Soot Formation and Oxidation of a Diffusion Flame)

  • 이원남;남연우;이춘범;신현동
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2004년도 제28회 KOSCO SYMPOSIUM 논문집
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    • pp.112-117
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    • 2004
  • The effects of laser heating on soot formation and oxidation of propylene diffusion flames have been studied experimentally under nearly sooting conditions. The non-sooting flame can be converted to a sooting flame when the laser light heats up a flame at 7 mm height, while a sooting flame can be changed to a non-sooting flame when a flame is heated with laser light at flame height of 13 mm. The selective heating at the soot formation and/or oxidation region determines the sooting behavior of a diffusion flame. The increased soot/flame temperatures are most likely to be responsible for both the decreased and increased soot formation/oxidation.

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Numerical Modeling for Combustion and Soot Formation Processes in Turbulent Diffusion Flames

  • Kim, Hoo-Joong;Kim, Yong-Mo
    • Journal of Mechanical Science and Technology
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    • 제16권1호
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    • pp.116-124
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    • 2002
  • In order to investigate the soot formation and oxidation processes, we employed the two variable approach and its source terms representing soot nucleation, coagulation, surface growth and oxidation. For the simulation of the taxi-symmetric turbulent reacting flows, the pressure-velocity coupling is handled by the pressure based finite volume method. We also employed laminar flamelet model to calculate the thermo-chemical properties and the proper soot source terms from the information of detailed chemical kinetic model. The numerical and physical models used in this study successfully predict the essential features of the combustion processes and soot formation characteristics in the reacting flow field.

아세틸렌/공기 비예혼합 난류 제트화염의 Soot 생성에 대한 수치해석 (Numerical Analysis for the Soot Formation Processes in Acetylene-Air Nonpremixed Turbulent Jet Flame)

  • 김후중;김용모;윤명원
    • 한국자동차공학회논문집
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    • 제10권6호
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    • pp.80-89
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    • 2002
  • The flame structure and soot formation in Acetylene-Air nonpremixed jet flame are numerically analyzed. We employed two variable approach to investigate the soot formation and oxidation processes. The present soot reaction mechanism involves nucleation, surface growth, particle coagulation, and oxidation steps. The gas phase chemistry and the soot nucleation, surface growth reactions are coupled by assuming that the nucleation and soot mass growth has the certain relationship with the concentration of pyrene and acetylene. We also employed laminar flamelet model to calculate the thermo-chemical properties and the proper soot source terms from the information of detailed chemical kinetic model. The numerical and physical model used in this study successfully predict the essential features of the combustion processes and soot formation characteristics in the reaction flow field.

화염편 모델을 이용한 층류확산화염장의 매연 생성 및 산화과정 해석 (Flamelet Modelling of Soot Formation and Oxidation in a Laminar $CH_4-Air$ Diffusion Flame)

  • 김군홍;김후중;김용모
    • 한국자동차공학회논문집
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    • 제13권1호
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    • pp.68-75
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    • 2005
  • By utilizing a semi-empirical soot model, the applicability of the laminar flamelet concept fur simulating the formation and oxidation of soot in the laminar diffusion flame has been studied. The source terms for two transport equations of the soot formation and oxidation are calculated in the mixture fraction/scalar dissipation rate space for laminar flamelets and stored in a library. In this study, emphasis is given to the interaction associated with radiation and soot formation. The radiative heat loss is obtained by solving the radiative transfer equation using the unstructured grid finite volume method with the WSGGM. The calculated temperatures and soot volume fractions agree relatively well with the experimental data and the previous numerical results of Kaplan et al. using the detailed chemistry.

A Study on the Characteristics of Soot Formation and Oxidation in Free Fuel Droplet Array

  • Lee, Myung-Jun;Kim, Jong-Youl;Yeom, Jeong-Kuk;Ha, Jong-Yul;Chung, Sung-Sik
    • Journal of Mechanical Science and Technology
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    • 제16권6호
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    • pp.851-860
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    • 2002
  • In this study, it was attempted to obtain the fundamental data for the formation and oxidation of soot from a diesel engine. Combustion of spray injected into a cylinder is complex phenomenon having physical and chemical processes, and these processes affect each other. There are many factors in the mechanism of the formation and oxidization of soot and it is necessary to observe spray combustion microscopically. In order to observe with that view, free fuel droplet array was used as an experimental object and the droplet array was injected into an atmospheric combustion chamber with high temperature. Ambient temperature of the combustion chamber, interdroplet spacing, and droplet diameter were selected as parameters, which affect the formation and oxidation of soot. In this study, it was found that the parameters also affect ignition delay of droplet. The ambient temperature especially affected the ignition delay of droplet as well as the flame temperature after self-ignition. As the interdroplet spacing that means the local equivalence ratio in a combustion chamber was narrow, formation of soot was increased. As diameter of droplet was large, surface area of the droplet was also broad, and hence evaporation of the droplet was more active than that of a droplet with relative small diameter.

음영사진의 화상해석에 의한 디젤화염에 관한 연구 (A Study on the Diesel Flame by Means of Image Analysis ofn Shadow Photographs)

  • 장영준;박호준;신본무정
    • 대한기계학회논문집
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    • 제14권5호
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    • pp.1222-1233
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    • 1990
  • 본 연구에서는 급속압축장치에서 실현된 단발분무하염내의 매연을 레이저음영 사진법에 의하여 가시화하고, 화염내의 매연농도의 시간적, 공간적분포를 조사한다. 또 전보에서 측정된 비증발분무내의 당량비분포와 비교검토하여 디젤화염내의 매연 생 성기구를 고찰하고, 분위기조건에 따른 착화지연이 매연생성에 미치는 영향 및 매연생 성과 열발생율과의 관계를 밝힌다.

동축류 확산화염의 OH 라다칼 분포 및 매연 특성 (OH Radical Distribution and Sooting Characteristics in Co-Flow Diffusion Flames)

  • 이원남;송영훈;차민석
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 1997년도 제15회 KOSCO SYMPOSIUM 논문집
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    • pp.1-11
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    • 1997
  • The soot and OH radical distributions have been experimentally studied in ethylene and propane laminar diffusion flames. The integrated soot volume fraction was measured along the centerline of a flame using a laser light extinction method. Planar laser light scattering and PLIF techniques are employed for the soot and OH radical distribution measurements utilizing Nd:YAG laser and OPO, FDO system. The concentration of OH radical is rapidly decreased at the edge of sooting region, which implies the importance of OH radical species on the soot oxidation process. For ethylene flames, the addition of air in fuel moves the OH radical distribution towards the center line of a flame at the soot oxidation region, while the concentration of OH radical remains relatively high at the soot formation region. The interaction between soot particles and OH radicals becomes more active with fuel-air at the soot oxidation region. For propane flames, however, any indication of the increased interaction between soot particles and OH radicals with fuel-air was not noticed.

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EFFECTS OF SPLIT INJECTION AND OXYGEN-ENRICHED AIR ON SOOT EMISSIONS IN A DIESEL ENGINE

  • Nguyen, Khai;Sung, Nak-Won;Lee, Sang-Su
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회B
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    • pp.2965-2970
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    • 2008
  • Effects of split injection and oxygen-enriched air on soot emissions in a DI diesel engine were studied by the KIVA-3V code. When split injection is applied, the second injection of fuel into a cylinder results in two separate stoichiometric zones which increases soot oxidation. As a result, soot emissions are decreased with split injection. When oxygen-enriched air is applied together with split injection, higher concentration of oxygen helps secondary combustion which results in a higher temperature in the cylinder. The increased temperature promotes growth reaction of acetylene with soot but doesn't improve the acetylene formation during the second injection of fuel. As more acetylene is consumed in the growth reaction of acetylene, the net acetylene mass in the cylinder is decreased, which leads to a decrease of soot formation. With an increase of soot oxidation caused by split injection, the soot emissions are decreased significantly. However, to avoid excessive NOx emissions with increased oxygen concentration, the level of oxygen concentration should be lower than 22% in volume.

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