• Title/Summary/Keyword: Solution-process

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A study on the Manufacture of the CuO Powder from Copper Chloride Solution by Spray Pyrolysis Process (분무열분해법에 의한 구리염화물 용액으로부터 CuO 분말 제조에 관한 연구)

  • Yu, Jae-Geun;Park, Hui-Beom
    • Korean Journal of Materials Research
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    • v.12 no.1
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    • pp.58-67
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    • 2002
  • In this study copper chloride(CuCl$_2$) solution was used as raw material to produce the fine copper oxide powder which has less than 1 $\mu\textrm{m}$ average particle size and has uniform particle size distribution by spray pyrolysis process. In the present study, the effects of reaction temperature, the injection speed of solution and air, the nozzle tip size and the concentration of raw material solution on the properties of produced powder were studied. The structure of the powder became much more compact with increasing the reaction temperature regardless of copper concentration of the raw material solution. The particle size of the powder increased accordingly with increasing the reaction temperature in case of 30 g/$\ell$ copper concentration of the solution. The particle size of the powder increased accordingly, and the surface structure of the powder became more porous with increasing the copper concentration of the raw material solution. When copper concentration in raw material solution was more than 100 g/$\ell$, all produced powder was CuCl regardless of reaction temperatures. When copper concentration in solution was below 30 g/$\ell$ and reaction temperature was higher than 90$0^{\circ}C$, CuO was the main phase. The surface of the powder tended to become porous with increasing the injection speed of solution. Particle size was increased and the surface of the powder showed severely disrupted state with increasing the nozzle tip size. The particle size was decreased and the particle size distribution was more uniform with increasing the air pressure through the nozzle.

Effect of Thesium Chinese Turczaninow Aqua-acupuncture Solution and Astragail Radix Aqua-acupuncture Solution on Promotion/ progression of Carcinogenesis (하고초와 황기 약침액이 발암 진행과정에 미치는 영향)

  • 손윤희;박신화;류준선;조경희;임종국;남경수
    • Journal of Life Science
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    • v.11 no.4
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    • pp.335-339
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    • 2001
  • Cancer chemoprevention refers to the use of natural or synthetic substances to prevent initiational and promotional events that occur during the process of carcinogenesis. Thesium Chinese Turczaninow aqua-acupuncture solution (TCTAS) and Astragli Radix aqua-acupuncture solution (ARAS) were tested as the cancer chemopreventive agents using biochemical markers of carcinogenesis. The effects on the inhibition of phorbol 12- myristate 13-acetate(TPA)-induced free radical formation in HL-60 cells and the inhibition of polyamine metabolism were measured. There is significant inhibition of TAP-induced free radical formation in human leukemic cells with cells with ARAS. Proliferation of Acanthamoeba castellanii was inhibited by TCTAS and ARAS. TCTAS and ARAS positive in these assays may inhibit the carcinogenesis process and is considered promising cancer-preventing agents.

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Manufacture and Properties of Gypsum-Wood (Gypsum-Wood의 제조와 성질)

  • Lee, Jong-Shin;Kim, Soung-Joon
    • Journal of the Korea Furniture Society
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    • v.19 no.1
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    • pp.83-90
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    • 2008
  • Gypsum-wood composites were made by introducing inorganic substances into wood using calcium chloride, first treating solution, and sodium sulfate, secondary treating solution, by double diffusion process under atmospheric pressure at room temperature. The process conducted as follows: water saturated specimens were soaked in calcium chloride solutions at several concentration. Then the specimens were soaked further in saturated sodium sulfate solution, and they were leached in flowing tap water for 24h. To attain sufficient weight percent gain (WPG) values, the suitable concentration of calcium chloride and soaking time in saturated sodium sulfate solution were 20% and 48h, respectively. Inorganic substances were produced mainly in the lumina of tracheides. It was made sure that these substances were dihydrate gypsum($CaSO_4$ $2H_2O$) by X -ray microanalysis (SEM-EDX). The composites had good fire resistance due to low heat transfer rate of gypsum formed in wood. However, the composites had little decay resistances, because they showed high weight losses by test fungi attacks.

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Characteristic of Photodegradation of MTBE Using TiO2/UV Process (TiO2/UV공정을 이용한 수중 MTBE의 광분해 특성)

  • Ryu, Seong Pil;Kim, Seong Su;O, Yun Geun
    • Journal of Environmental Science International
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    • v.13 no.3
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    • pp.289-295
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    • 2004
  • The objective of this study is to delineate removal efficiency of the MTBE in solution by $TiO_2$ photocatalytic degradation as a function of the following different experimental conditions: Initial concentration of MTBE, air flow rate in solution, $H_2O_2$ dosage and pH of the solution. Photodegradation rate was increased with decreasing initial concentration of MTBE. The removal efficiency was 82% after 180 min in the case of MTBE concentration of 100 mg/L but 100% after 180 min in the case of 20 mg/L. Removal efficiency was increased with increasing pH, $H_2O_2$ dosage and air flow rate in solution.

Separation and Extraction of Hot Particulate from contaminated Perfluorocarbon solution

  • Kim Gye-Nam;Narayan Mathuresh;Wou Hui-Jun;Jung Chong-Hun;Oh Won-Zin
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.70-71
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    • 2005
  • It was an idea to develop a system to remove the contaminated hot particulate to make clean nuclear research facilities to the clear visibility for researcher. In order to clean micron and sub micron size particulates from used PFC solution as a decontamination tool. Since PFC solution is very expensive so it was a high recommendation to develop the some filtration equipment to purify PFC for next decontamination process, in additionally, reduce the secondary waste. However, we developed an easy and economic filter system to purify the PFC solution. The major advantage of the process operates in closed loop under near ambient conditions, thus minimizing the potential for fugitive TRU emissions and reduces the secondary waste. This has very significant safety and cost impacts. Here we proposed the two types PFC filter systems.

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Characterization of Hydrazine Solution Processed Multi-layered CuInSe2 Thin Films (하이드라진 용액법으로 형성된 CuInSe2 다층 박막 분석)

  • Chung, Choong-Heui
    • Journal of Surface Science and Engineering
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    • v.48 no.4
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    • pp.169-173
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    • 2015
  • $CuInSe_2$ thin films which have been widely used for thin solar cells as a light absorber were prepared by hydrazine solution processing, and their microstructural properties were investigated. Hydrazine $CuInSe_2$ precursor solutions were prepared by dissolving $Cu_2S$, S, $In_2Se_3$ and Se powder in hydrazine solvent. Multilayer $CuInSe_2$ chalcopyrite phase thin films were prepared by repeating spin-coating process using the precursor solution. Unfortunately, the presence of the interfaces between each $CuInSe_2$ layer formed by multi-layer coating impeded grain growth across the interface. Here, by doing simple interface engineering to solve the limited grain growth issue, the large grained (${\sim}1{\mu}m$) $CuInSe_2$ thin films were obtained.

Effects of Non-absorbable Gases in the Absorption of Water Vapor by Aqueous LiBr Solution Film on Horizontal Tube Banks

  • Kwon, Ky-Seok;Kim, Byong-Joo
    • International Journal of Air-Conditioning and Refrigeration
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    • v.9 no.2
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    • pp.19-27
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    • 2001
  • In the present study, the effects of film Reynolds number (60∼200) and volumetric content of non-absorbable gases (0∼10%) in water vapor on the absorption process of aqueous LiBr solution were investigated experimentally. The formation of solution film on the horizontal tubes of six rows was observed to be complete for Re>100. Transition film Reynolds number was found to exist above which the Nusselt number and Schmidt number diminishes with solution flow rate. As the concentration of non-absorbable gases increased, mass transfer rate decreased more seriously than heat transfer rate did. the degradation effects of non-absorbable gases seemed to be significant especially when small amount of non-absorbable gases was introduced to the pure water vapor.

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Comparative study on structural and luminescence properties of solution processed ZnO thin films

  • Park, Byung-Yoon;Choi, Sung-Ho;Hong, Chang-Seop;Ryu, Beyong-Hwan;Jung, Ha-Kyun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1433-1436
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    • 2009
  • Film morphology, crystallinity, and luminescence property of solution processed ZnO films have been studied. Fluorine addition and annealing ambient significantly change the defect-related emission band as well as the structural property. Using the overall emission behaviors, we can predict an optimized process condition for solution-based ZnO thin film.

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Enhanced Crystallization of Amorphous Si Using viscous Ni Solution and Microwave Annealing

  • Ahn, Jin-Hyung;Eom, Ji-Hye;Ahn, Byung-Tae
    • Journal of Information Display
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    • v.2 no.2
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    • pp.7-12
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    • 2001
  • A viscous Ni solution was coated over amorphous Si thin film for evenly spread of Ni metal source. The Ni s. prepared by dissolving $NiCl_2$ into IN HCI and mixing with propylene glycol. $NiCl_2$ and Ni were deposited on the amorphous film after oven dry and they enabled to obtain a uniform crystallization. The crystallization using the viscous Ni solution was a Ni-silicide mediated process, the same process used with Ni metal layer. The crystallization temperature was lowered to $480^{\circ}C$ by the synergy effect of silicide-mediated crystallization and microwave-induced crystallization. Lateral crystallization was also enhanced such that the velocity of lateral crystallization by microwave annealing became faster than by furnace annealing.

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Undrained solution for cavity expansion in strength degradation and tresca soils

  • Li, Chao;Zou, Jin-feng;Sheng, Yu-ming
    • Geomechanics and Engineering
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    • v.21 no.6
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    • pp.527-536
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    • 2020
  • An elastic-plastic solution for cavity expansion problem considering strength degradation, undrained condition and initial anisotropic in-situ stress is established based on the Tresca yield criterion and cavity expansion theory. Assumptions of large-strain for plastic region and small-strain for elastic region are adopted, respectively. The initial in-situ stress state of natural soil mass may be anisotropic caused by consolidation history, and the strength degradation of soil mass is caused by structural damage of soil mass in the process of loading analysis (cavity expansion process). Finally, the published solutions are conducted to verify the suitability of this elastic-plastic solution, and the parametric studies are investigated in order to the significance of this study for in-situ soil test.