• Title/Summary/Keyword: Solution stability

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Study on the Stability of NaBH4 Solution during Storage Process (NaBH4수용액 저장과정 중 안정성에 관한 연구)

  • Sim, Woojong;Jo, Jaeyoung;Choi, Daeki;Nam, Sukwoo;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.48 no.3
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    • pp.322-326
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    • 2010
  • Stability of sodium borohydride solution during storage was studied. In order to enhance the $NaBH_4$ stability, NaOH and KOH were added to the $NaBH_4$ solution. The effect of concentration of the borohydride and alkaline solution, temperature and materials of storage vessels on the rate of borohydride hydrolysis was investigated. The rate of hydrogen evolution decreased as the concentration of alkaline increased due to increase of $NaBH_4$ stability in the solution. The stability of $NaBH_4$ solution decreased when the borohydride concentration raised from 10 to 15 wt% and then increased when the $NaBH_4$ concentration increased above 15 wt% due to increase in the pH of the concentrated solution. The activity coefficient of hydrolysis of $NaBH_4$ solution(NaOH 3.0 wt%, $NaBH_4$ 25 wt%) was 115.1 kJ/mol and this value was 1.5~4.0 times higher than that of hydrolysis of $NaBH_4$ solution with catalyst. The borohydride solutions in glass and stainless-steel vessel were more stable than the solution in plastic(PE) vessel.

Influence of Acetic Acid Solution on Heat Stability of L-Ascorbic Acid

  • Jang, Keum-Il;Lee, Hyeon-Gyu
    • Food Science and Biotechnology
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    • v.17 no.3
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    • pp.637-641
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    • 2008
  • This study investigated the heat stability of L-ascorbic acid (AA) in acetic acid solution. To analyze the degradation of AA using high performance liquid chromatography (HPLC), AA was measured at a wavelength of 244 nm in acetic acid and 265 nm in distilled water. During the storage of AA in acetic acid or distilled water at $37^{\circ}C$, degradation of AA was slower in acetic acid than in distilled water. On examining various ratios of AA to acetic acid, the stability of AA at $100^{\circ}C$ for 30 min was the highest when the concentration of acetic acid was 10 times higher than the concentration of AA. After acetic acid was added into AA degraded by heating, the AA is stabilized by reheating. Ultimately, these results indicate that degraded AA is reduced by hydrogen ions dissociated from acetic acid, and the rate of reduction of degraded AA in acetic acid solution is improved with heat processing.

Storage Stability and Color Reproducibility of Yellow and Red Dyes Extracted from Carthamus tinctorius L.

  • Shin, Youn-Sook;Yoo, Dong-Il
    • Textile Coloration and Finishing
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    • v.24 no.3
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    • pp.165-172
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    • 2012
  • The stability of yellow and red dyes prepared from safflower (Carthamus tinctorius L.) in aqueous solution and in solid state was investigated. External factors such as light irradiation and temperature on the stability were examined during storage. Changes in absorbance of dye solutions and the color changes of fabrics dyed after long time storage were measured. Also, color reproducibility during storage was investigated by dyeing test on various fabrics. Red colorant in aqueous solution was very unstable to light, resulting that about 40% of absorbance were lost in 12hrs. The absorbance of yellow dye solutions was not decreased within 84hrs. In aqueous medium, yellow dye was much more stable than carthamin. Both dyes are relatively stable for long storage when they are stored in solid state compared to when in aqueous solution. Color changes are marginal in both dyes.

Stability of Gingkoflavonglycoside in Gingko Extract Aqueous Solution (은행잎엑스 수용액 중 Gingkoflavonglycoside의 안정성)

  • Kim, Chong-Kook;Park, Man-Ki;Lee, Eun-Jin;Hwang, Sung-Joo
    • Journal of Pharmaceutical Investigation
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    • v.19 no.4
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    • pp.213-217
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    • 1989
  • To formulate the stable preparation of Gingko extract injection and to evaluate the stability of the preparation, Gingko extract aqueous solutions having various pH values were prepared and the stability of ginskoflavonglycoside (GFG) was investlfated by high performance liquid chromatography. The stability of GFG decreased as pH increased, while the water solubility of Gingko extract decreased as pH decreased. The optimal pH of the Gingko extract aqueous solution was found to be pH 6.5. The shelf life $(T_{90%})$ of the Gingko extract aqueous solution of pH 6.5 at $20^{\circ}C$ was extrapolated to be four years.

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EXISTENCE AND GLOBAL EXPONENTIAL STABILITY OF A PERIODIC SOLUTION TO DISCRETE-TIME COHEN-GROSSBERG BAM NEURAL NETWORKS WITH DELAYS

  • Zhang, Zhengqiu;Wang, Liping
    • Journal of the Korean Mathematical Society
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    • v.48 no.4
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    • pp.727-747
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    • 2011
  • By employing coincidence degree theory and using Halanay-type inequality technique, a sufficient condition is given to guarantee the existence and global exponential stability of periodic solutions for the two-dimensional discrete-time Cohen-Grossberg BAM neural networks. Compared with the results in existing papers, in our result on the existence of periodic solution, the boundedness conditions on the activation are replaced with global Lipschitz conditions. In our result on the existence and global exponential stability of periodic solution, the assumptions in existing papers that the value of activation functions at zero is zero are removed.

STABILITY OF POSITIVE STEADY-STATE SOLUTIONS IN A DELAYED LOTKA-VOLTERRA DIFFUSION SYSTEM

  • Yan, Xiang-Ping;Zhang, Cun-Hua
    • Journal of the Korean Mathematical Society
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    • v.49 no.4
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    • pp.715-731
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    • 2012
  • This paper considers the stability of positive steady-state solutions bifurcating from the trivial solution in a delayed Lotka-Volterra two-species predator-prey diffusion system with a discrete delay and subject to the homogeneous Dirichlet boundary conditions on a general bounded open spatial domain with smooth boundary. The existence, uniqueness and asymptotic expressions of small positive steady-sate solutions bifurcating from the trivial solution are given by using the implicit function theorem. By regarding the time delay as the bifurcation parameter and analyzing in detail the eigenvalue problems of system at the positive steady-state solutions, the asymptotic stability of bifurcating steady-state solutions is studied. It is demonstrated that the bifurcating steady-state solutions are asymptotically stable when the delay is less than a certain critical value and is unstable when the delay is greater than this critical value and the system under consideration can undergo a Hopf bifurcation at the bifurcating steady-state solutions when the delay crosses through a sequence of critical values.

Aviation stability analysis with coupled system criterion of theoretical solutions

  • C.C. Hung;T. Nguyen
    • Coupled systems mechanics
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    • v.12 no.3
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    • pp.221-239
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    • 2023
  • In our research, we have proposed a solid solution for aviation analysis which can ensure the asymptotic stability of coupled nonlinear plants, according to the theoretical solutions and demonstrated method. Because this solution employed the scheme of specific novel theorem of control, the controllers are artificially combined by the parallel distribution computation to have a feasible solution given the random coupled systems with aviation stability analysis. Therefore, we empathize and manually derive the results which shows the utilized lemma and criterion are believed effective and efficient for aircraft structural analysis of composite and nonlinear scenarios. To be fair, the experiment by numerical computation and calculations were explained the perfectness of the methodology we provided in the research.

The Stability of Plating Solution and the Current Density Characteristics of the Sn-Ag Plating for the Wafer Bumping

  • Kim, Dong-Hyun;Lee, Seong-Jun
    • Journal of the Korean institute of surface engineering
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    • v.50 no.3
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    • pp.155-163
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    • 2017
  • In this study, the effects of the concentration of metal ions and the applied current density in the Sn-Ag plating solutions were examined in regards to the resulting composition and morphology of the solder bumps' surface. Furthermore the effect of any impurities present in the methanesulfonic acid used as a base acid in the Sn-Ag solder plating solution on the stability of plating solution as well as the characteristics of the Sn-Ag alloys films was also explored. As expected, the uniform bump was obtained by means of removing impurities in the plating solution. Consequently the resultant solder bump was obtained in an optimal current density of the range of $1A/dm^2$ to $15A/dm^2$, which has acceptable bump shape and surface roughness with 12inch wafer trial results.

On the improvement of the guaranteed stability margins for the discrete time LQ regulator

  • Kwon, Wook-Hyun;Kim, Sang-Woo;Choi, Han-Hong
    • 제어로봇시스템학회:학술대회논문집
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    • 1989.10a
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    • pp.913-917
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    • 1989
  • In this paper, the selection method of weighting matrices in the discrete-time LQ problem are suggested in order to improve the guaranteed stability margins, i.e. the gain and phase margins. The asymptotic properties of the solution of the algebraic Riccati equations are investigated by using the closed form solution of the difference Riccati equations. It is shown that the solution of the algebraic Riccati equations monotonically increases as the state weighting matrix Q or the control weighting matrix R increase. The increasing rate of the solution is shown to be much less than that of R for large R. It is also proven that the guaranteed stability margins increases as the ratio between Q and R decreases.

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