• Title/Summary/Keyword: Solution growth method

Search Result 641, Processing Time 0.03 seconds

A Study on the Growth of KTP$(KTiOPO_4)$ Single Crystal (KTP$(KTiOPO_4)$ 단결정의 육성에 관한 연구)

  • 차용원;최원웅;장지연;오근호;김판채
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.3 no.1
    • /
    • pp.12-17
    • /
    • 1993
  • Growth runs of KTP single crystals were carried out by the hydrothermal method. KTP powders used for the crystal growth were prepared as a single phase by the solid state reaction of a stoichiometric mixture of $KH_2PO_4 and TiO_2$ at TEX>$800^{\circ}C$ and subsequently by the hydrothermal treatment at $250^{\circ}C$ 4m KF solution. The most effective solvents for the crystal growth of KTP were KF and K $K_2HPO_4$ solutions. Solubilities of KTP in these solutions were positive over the range $350~450^{\circ}C$.Seed crystals of good quality could be obtained by the horizontal temperature gradient method at temperatures over the range 380~430^{\circ}C$ in these solutions. The hydrothermal conditions for the high growth rates of seed crystals are as follows: growth method; vertical temperature gradient method, solvent; 4m KF or $K_2HPO_4$ solution, temperature region; $400~450^{\circ}C$, pressure region; $1000~1500kg/cm^2$, where solubility of KTP was large enough to proceed the growth. Under such conditions, seed crystals of KTP are grown at a rate of approximately 0.06-0.08mm/day in the direction of the c-axis. Morphologies of grown crystals tended to be bounded by (100), (011) and (201) faces.

  • PDF

A study on the growth and properties of KTP single crystals ($KTP(KTiOPO_4)$단결정 육성 및 물성 연구)

  • Lee, M.J.;Cha, Y.W.;Jang, J.Y.;Orr, K.K.;Kim, P.C.
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.4 no.1
    • /
    • pp.100-104
    • /
    • 1994
  • KTP seed crystals were grown by the hydrothermal method and the properties of grown crystals were investigated by means of infrared spectrophotometer. The hydrothermal conditions for high growth rates of seed crystals are as follows: temperature ranges, between , $430 and 450^{\circ}C $ ; hydrothermal solvent, 4m KF solution ; temperatures difference, $30<{\triangle}T<65^{\circ}C$ ; filling %, 65% ; growth method, vertical temperature gradient method. Under these conditions, morphologies of the grown KTP single crystals tended to be bounded by (100), (011) and (201) faces and hydroxyl groups were observed in the grown crystals.

  • PDF

A Novel on Optimal Growth Management System of Corp using Recirculation of Nutrient Solution based on IoT and Location Tracking Technology (IoT 및 위치 추적 기술 기반의 양액 순환 방식을 활용한 작물의 최적 생장 관리 시스템에 관한 연구)

  • Jung, Se Hoon;Park, Sung Kyun;Sim, Chun Bo
    • Journal of Korea Multimedia Society
    • /
    • v.19 no.11
    • /
    • pp.1891-1899
    • /
    • 2016
  • Recently food problem and crop disaster have been increased continuously because of the meteorological changes. These cause rising cost for crops continuously and irregularly. Some researchers have studied straight structure of device for hydroponics and plant factory previously to solve a fundamental part of these problems. However, there are several problems such as limited crop cultivation space, providing irregular nutrients for crops, and lack of monitoring interfaces. For them, we propose an optimal growth and development crops management system using light source tracking and recirculation of nutrient solution method to supply nutrient continuously based on IoT. In order to evaluate the performance of our system, we compared and analyzed in terms of two viewpoints, the tracking analysis for natural light source measurement and the growth of crops through artificial light, LED, respectively. We confirmed that the higher the duty ratio of LED, the larger the crop's size, particularly. As well as, for about 1 month, we compared with the existing natural light growing environment and that of our system. It was confirmed that the size of the crops grown through our system is about three times larger than that of natural light natural crops.

Adsorption properties and metal growth aspects on the surface of activated carbon monolith electrochemically deposited with Ag

  • Oh, Won-Chun;Lim, Chang-Sung
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.14 no.2
    • /
    • pp.37-46
    • /
    • 2004
  • The electrochemical adsorption of the Ag ions from aqueous solution on pelletized activated carbon monolith was investigated over wide range of operation time. The adsorption capacities of pelletized activated carbon monolith are associated with their internal porosity and are related properties such as surface area, pore size distribution. The chemical industry generates wastewater that contains toxic matters like heavy metals in small concentrations so that their economic recovery is not feasible. But, the method using activated carbon monolith can be used to withdrawal of heavy metals in waste water. After the electrochemical treatment, the quantitative properties in Ag ion solutions are also examined by pH concentration and studied elemental analysis by ICP-Atomic Emission Spectrometer and Energy Disperse X-ray (EDX) spectra. It is consider that the pH is very important factor at the reason of water pollutant with increasing acidity in industrial field. The result of quantitative analysis using Inductively Coupled Plasma-Atomic Emission Spectrometer of metal after electrochemical reaction in Ag ions solution depending on time are shown that the amount of Ag ions deposited was decreased with growth of Ag particles on the carbon surfaces as increasing electrochemically treated time. And, surface morphologies are investigated by scanning electron microscopy (SEM) to explain the changes in adsorption properties.

In situ growth of Mg-Al hydrotalcite film on AZ31 Mg alloy

  • Song, Yingwei;Chen, Jun;Shan, Dayong;Han, En-Hou
    • Proceedings of the Korean Institute of Surface Engineering Conference
    • /
    • 2012.11a
    • /
    • pp.12-13
    • /
    • 2012
  • An environmentally friendly method for in situ growth of Mg-Al hydrotalcite (HT) film on AZ31 magnesium alloy has been developed. The growth processes and corrosion resistance of the HT film were investigated. Then the HT film was surface modified by phytic acid solution to further improve the corrosion resistance. The film formation involves the dissolution of AZ31 substrate, adsorption of the ions from solution, nucleation of the precursor, followed by the dissolution of $Al^{3+}$, exchanging of $OH^-$ by $CO{_3}^{2-}$ and growth of the HT film. The HT film is very compact and acts as a barrier against $Cl^-$ attack in the early stage of corrosion, and then the surface of the film is dissolved gradually. This dense HT film can provide effective protection to the AZ31 alloy. The HT film with surface modification by phytic acid presents a self-healing feature and exhibits better corrosion resistance.

  • PDF

The growth of large KTP crystal and the study of its optical inhomogeneity (대형 KTP 단결정 성장 및 광학적 불균일성에 관한 연구)

  • Han, J.Y.;Lee, S.K.;Ma, D.J.;Kim, Y.H.;Park, S.S.;Lee, S.H.
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.4 no.1
    • /
    • pp.76-82
    • /
    • 1994
  • Single crystals of Potassium Titanyl Phosphate (KTP) were grown from the flux of $K_6P_4O_13(K_6)$ using a high temperatures solution growth method. To grow the large KTP crystal without inclusion, the temperature gradient in furnace, crystal rotation, orientation of seed crystal, and the cooling rate were controled. The KTP crystals are up to $10(a){\times}28(b){\times}33(c)mm^3$ in size. We investigated the optical inhomogeneity in this KTP crystal by the SHG power measurement and TEM analysis.

  • PDF

Preparation of the Cobalt Oxide Powder by Hot Petroleum Drying Method (석유증발법에 의한 Cobalt Oxide의 분말제조)

  • 윤상옥;정형진
    • Journal of the Korean Ceramic Society
    • /
    • v.24 no.3
    • /
    • pp.257-262
    • /
    • 1987
  • The characteristics of cobalt oxide powders prepared by hot petroleum drying method from the cobalt acetate were evaluated by DTA/TGA, XRD, BET, SEM and density measurement. The cobalt oxide powder could be prepared by hot petroleum drying of the emulsion of cobalt acetate salt solution and the subsequent thermal decomposition of the acetate at 300$^{\circ}C$. As the concentration of the salt solution and the calcination temperature of the dried powder increased, the surface area of the synthesized powder decreased due to the particle growth, so that after sintering the density and grain size decreased. For the same concentration of the salt solution, the surface area and sinterability of the powder by hot petroleum drying increased in comparision with those by conventional drying.

  • PDF

Ag Nanowires Prepared by a Modified Polyol Method with 1,4-Benzoquinone Additives

  • Kang, Miseon;Chung, Eunseon;Kim, Sang-Ho;Rhee, Seog Woo
    • Bulletin of the Korean Chemical Society
    • /
    • v.35 no.11
    • /
    • pp.3209-3212
    • /
    • 2014
  • This paper describes a selective synthetic method of fabricating Ag nanowires by using a modified polyol process. To synthesize the Ag nanowire, an ethylene glycolic solution of silver nitrate and an ethylene glycolic solution of polyvinylpyrrolidone solution containing a small amount of organic oxidant, 1,4-benzoquinone, were slowly added to a hot ethylene glycol medium at $160^{\circ}C$ for 8 min using a syringe pump. The reaction mixtures were heated for an additional 45 min and cooled to room temperature. Finally, the silver nanomaterials were isolated from the mixture by centrifugation. The crystal structure of the nanomaterials was investigated by powder X-ray diffraction analyses, and their morphology was investigated by scanning electron microscopy. A small amount of organic oxidant, 1,4-benzoquinone, played a significant role in controlling the morphology during crystal growth. Consequently, Ag nanowires rather than Ag nanoparticles were selectively obtained.

Effects of Nutrient Solution Application Methods and Rhizospheric Ventilation on Vegetative Growth of Young Moth Orchids without a Potting Medium in a Closed-Type Plant Factory

  • Min, Sang Yoon;Oh, Wook
    • Journal of People, Plants, and Environment
    • /
    • v.23 no.5
    • /
    • pp.545-554
    • /
    • 2020
  • Background and objective: Moth orchids in the vegetative stage are suitable for a multi-layer growing environment in a closed-type plant factory which can be a good alternative that can reduce production costs by reducing cultivation time and energy cost per plant. This study was conducted to find out the optimal rhizospheric environment for different irrigation methods without a potting medium and rhizospheric ventilation for the vegetative growth of young Phalaenopsis hybrid 'Blanc Rouge' (P. KV600 × P. Kang 1) and Phalaenopsis Queen Beer 'Mantefon' in a closed-type plant factory system. Methods: The one-month-old clonal micropropagules with bare roots rapped with a sponges were fixed on the holes of styrofoam plates above growth beds, and were watered using the ebb-and-flow (EBB) and aeroponic (AER) methods with Ichihashi solution (0.5 strength) once a day at 06:00 (P) or 18:00 (S), and both (PS). Rhizospheric ventilation (V) was also applied to change the temperature, relative humidity, and CO2 concentration of the beds. Plants potted into sphagnum moss and watered once a week were used as the control group. Results: After 12 months of treatment, the growth characteristics of the EBB groups were the best among the treatment groups without a medium, but no effect of irrigation timing was observed. V reduced the temperature, relative humidity and CO2 concentration of the beds. Whereas, EBB+V (ebb-and-flow with ventilation) improved plant growth and reduced the occurrence of disorders and withering. Especially, EBB+V showed a similar performance to the control group. Conclusion: The results indicated that the optimal irrigation method without a potting medium for producing middle-aged potted moth orchids was the EBB system with forced rhizospheric ventilation. Therefore, further studies on the optimal ventilation method and moisture control of the crown need to be carried out to develop the irrigation system without a potting medium for vertical farming in closed-type plant factories.

Physicochemical Treatment for the Reduction of Fusarium spp. Infested in Adlay (Coix lacryma-jobi L.) Seeds (율무 종자 오염 Fusarium 속 진균 저감화를 위한 이화학적 처리)

  • An, Tae Jin;Kim, Young Guk;Hur, Mok;Lee, Jeong Hoon;Lee, Yun Ji;Cha, Sun Woo;Oh, Sang Keun
    • Korean Journal of Medicinal Crop Science
    • /
    • v.23 no.6
    • /
    • pp.460-467
    • /
    • 2015
  • Background : The aim of the present study was to identify an effective physicochemical control method to reduce Fusarium species infestation in adlay (Coix lacryma-jobi L.) before and after harvesting. Methods and Results : We observed that prochloraz emusifiable concentrate and hexaconazol prochloraz emusifiable concentrate strongly inhibited the mycelial growth of 10 Fusarium species. Strong growth inhibitions and cell lysis were observed following treatment with 4% NaOCl solution. The total number of fungi detected were lower follwing treatment with thiophanatemethyl triflumizole wettable powder ($1.1{\times}10^4CFU/g$), hexaconazol prochloraz emulsifiable concentrate ($1.2{\times}10^4CFU/g$), carboxin thiram dustable powder ($1.6{\times}10^4CFU/g$) and prochloraz emulsifiable concentrate ($1.7{\times}10^4CFU/g$) than in the non-treated control ($7.7{\times}10^4CFU/g$). The reduction of Fusarium fungi varies with the concentration and soaking time of NaOCl solution. Fungal detection was not observed after soaking in NaOCl solution for 24 h and harmful effects were not observed for plant growth by NaOCl after soacking for 6 - 12 h. Conclusion : Soaking seed for 6 - 12 h in 4% NaOCl could be an effective method of disinfectant treatment for the control of Fusarium fungi in adlay seeds.