• Transactions of the Korean hydrogen and new energy society
• /
• v.1 no.1
• /
• pp.48-54
• /
• 1989

Semiconductive property of the passivating $TiO_2$ film was investigated by measuring the impedance of passivated titanium electrode in a 0.1 N NaOH solution. The passive film was prepared galvanostatically with $10mA/cm^2$ at formation potential of 50 V in a 1 N $H_2SO_4$ solution. The impedance measurement was conducted by superimposing an ac voltage of 5 m V amplitude with the frequency ranging from 5 to 10000 Hz on a dc bias (applied potential). The donor distribution in the film was depicted from the analysis of the non-linear slope of Mott-Schottky plot. The region with nearly constant concentration of donors near the electrolyte/film interface amounts at about 60 percent of the total film thickness and donor concentration increases largely with distance from the surface in an inner region near the film/metal interface. In a region of the film/metal interface the donor concentration showed a frequency dependence greater than in a region of the electrolyte/film interface. The result of donor concentration against frequency suggests a transition from crystalline to amorphous state with distance from the electrolyte/film interface in the passivating $TiO_2$ films. This is also confirmed by the ac conductivity measurement.

• Transactions of the Korean hydrogen and new energy society
• /
• v.24 no.2
• /
• pp.179-185
• /
• 2013

The behavior of surface film formation was greatly dependent on the speed of potential cycling. In $LiClO_4$ / EC + DEC, cyclic voltammetry results showed that the peaks originated from surface film formation on graphite electrode at the high charge-discharge rate was shifted to the lower potentials as the charge-discharge rate decrease. This indicates that surface films with different morphology and thickness were formed by different charge-discharge rate. Transmission electron microscopy (TEM) results indicated that the properties such as thickness and morphology of the surface film were greatly affected by the charge-discharge rate. Electrochemical impedance spectroscopy (EIS) showed that the resistance of surface film was affected by the speed of potential cycling. In addition, the charge transfer resistance was also dependent on the charge-discharge rate indicating that the charge transfer reaction was affected by the nature of surface film. TEM and EIS results suggested that the chemical property as well as the physical property of the surface film was affected by the charge-discharge rate.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
• /
• 2002.10b
• /
• pp.95-96
• /
• 2002

The operation of proceeding bearing in the conditions of misaligned axis of proceeding and bush leads to the load concentration on the bearing edges causing further mixed lubrication conditions, unstable operation and intensive wear of mating parts. For the design process of proceeding bearing the knowledge of static characteristics determined from the oil film pressure and temperature distribution is very important. For the 3-lobe proceeding bearing, the pressure, temperature and viscosity fields, load capacity, minimum oil film thickness, power loss, oil flow and maximum oil film temperature have been determined by iterative solution of the Reynolds', energy and viscosity equations. The paper introduces the results of theoretical investigations of static characteristics of 3-lobe proceeding bearing operating at misaligned axis of proceeding and bush. An effect of misalignment ratio, length to diameter ratio of the proceeding bearing, the lobe clearance ratio on the static characteristics was investigated. Laminar, adiabatic model of oil film for the solution of Reynolds, energy and viscosity equations was applied.

• Electrical & Electronic Materials
• /
• v.10 no.8
• /
• pp.813-818
• /
• 1997

In this study the thin film air core and magnetic core inductors consisting of planar coil and/or CoNbZr amorphous magnetic layers on a Si substrate were fabricated as spiral type by using rf magnetron sputtering and wet etching methods. The etchant solution was achieved by iron chloride solution(17.5 mol%) mixed with HF (20 mol%) during 150 sec which etched Cu films and CoNbZr/Cu/CoNbZr multi-layer films. They were about 10${\mu}{\textrm}{m}$ of thickness and 10$\times$10 mm$^2$of size. The properties of thin film magnetic core inductor were 400 nH of Q value at 10 MHz and the resonance frequency was about 300 MHz.

• Proceedings of the Korean Society of Marine Engineers Conference
• /
• 2006.06a
• /
• pp.265-266
• /
• 2006

The chemical conversion coating formed on magnesium alloy investigated for low cost and harmless in environment by using the colloidal silica as the main component. The film formed in 298 K is thick, the film, which was thought combination of Si-O, was formed. The film formed in 313 K is thinner than that in 298 K. The quantity of film formed at high temperature such as 333 K and 353 K is smaller than dissolved quantity. At the anodic polarization experiment, corrosion resistance in sealing by hot water after chemical conversion treatment in basic solution condition get worse than that in comparison with basic solution condition. In salt spray test, the ratio of black rust on specimen that did not conducted chemical conversion treatment was five times or more compared with those of chemical conversion treated specimen. The film thickness of chemical conversion coating produced by alkali treatment process is thinner than in comparison with that of specimen produced in basic chemical conversion treatment solution condition. It is thought, however, that it showed good corrosion resistance during salt spray test because the area of microcracks is small.

• Applied Chemistry for Engineering
• /
• v.9 no.7
• /
• pp.998-1003
• /
• 1998

$BaTiO_3$ thin film was electrochemically deposited on Ti electrode in a 0.4 M $Ba(OH)_2$ solution of $85^{\circ}C$ using a current pulse waveform. Both $BaTiO_3$ crystallinity and faradaic efficiency for the film formation were enhanced with the increase of cathodic current density and pulse time. Based on the surface analysis and electrochemical studies, it was suggested that, during cathodic pulsed, the surface pH increase due to the reduction of $H_2O$ accelerates the structural changes of Ti oxides which were formed during anodic cycle. Prior to experiments, Ti oxides were intentionally grown in 0.1 M $H_2SO_4$ solution and the effect of initial oxide film thickness on the $BaTiO_3$ film formation was investigated. The migration of $Ti^{+4}$ ions through the oxide film was retarded with the increase of film thickness and it was observed that the crystallization of $BaTiO_3$ was only limited to the defect area of surface oxides.

• Journal of Advanced Marine Engineering and Technology
• /
• v.30 no.4
• /
• pp.483-493
• /
• 2006

A model for a pressure drop of water vapor flow across tube banks in a horizontal tube absorber of an absorption chiller/heater using LiBr solution as a working fluid has been developed based on a commercial 20RT(70kW) absorption chiller/heater. The numerical results show that the characteristic of the pressure drop in the shell side of the horizontal tube absorber is completely different from that in a conventional shell and tube heat exchanger. Especially, solution film thickness has significant influence on the vapor pressure drop in the horizontal tube absorber. In addition, the effects by the tube diameters, the longitudinal pitch to diameter ratio, and Reynolds number of the vapor flow, on the vapor pressure drop have been studied to evaluate the compactness of tube absorber. It was found that the vapor pressure drop decreases as tube diameter increases, the longitudinal pitch to diameter ratio increases, and Reynolds number of the vapor flow decreases. A comparison of the present study results with well-established experimental and numerical results showed a good overall agreement.

• Journal of the Korean institute of surface engineering
• /
• v.53 no.1
• /
• pp.15-21
• /
• 2020

In this study, growth and burning behavior of 6061 aluminum alloy was studied under constant anodic voltages at various temperatures and magnetic stirring rates in 20% sulfuric acid solution by analysing I-t curves, measuring thickness and hardness of aluminum anodic oxide (AAO) films, observations of surface and cross-sectional images of AAO films. AAO films were grown continuously at lower voltages than 18.5V but burning occurred when a voltage more than 19V was applied in 20% H₂SO₄ solution at 20±0.5℃ and 200 rpm of magnetic stirring. The burning was always related with an extremely large increase of anodic current density with anodizing time, suggesting that high heat generation during anodizing causes deteriorations of AAO films by chemical reaction with acidic solutions. The burning resulted in decreases of film thickness and hardness, surface color brightened and formation of porous defects in the AAO films. The burning voltage was found to decrease with increasing solution temperature and decreasing magnetic stirring rate. The decreased burning voltages seem to be closely related with increased chemical reactions between AAO films and hydrogen ions.

• Journal of Drive and Control
• /
• v.10 no.3
• /
• pp.7-13
• /
• 2013

Hydraulic vane pumps are widely used in various hydraulic systems because of its compactness and light weight. It is well known that the vanes and cam ring are separated by very thin liquid films which result in the EHL state. Contrary to the case of cylindrical roller bearings, the inlet and side boundary pressures are much higher than the atmospheric pressure. In this paper, a numerical solution of the EHL of finite line contacts between the cam ring and vane tip with profiled ends is presented. Using a finite difference method with non-uniform grids and the Newton-Raphson method, converged solutions are obtained for moderate load and material parameters. The EHL pressure distribution and film shape are considerably affected by pump delivery pressure and the side boundary condition applied. Both the maximum pressure and the minimum film thickness always occurred near the edge regions. The present results can be used in the design of optimum vane profile in hydraulic vane pump.

• Bulletin of the Korean Chemical Society
• /
• v.17 no.8
• /
• pp.707-712
• /
• 1996

Growth and changes of electronically conducting polypyrrole (PPy) in the form of thin films polymerized on metal electrodes were investigated by electrochemical and in situ three-parameter ellipsometry methods at the wavelength of 632.8 nm. Although the optical equations produced multiple sets of solution, it was possible to determine a unique set of thickness and the optical constants of a film by auxiliary measurements and/or physical reasoning. The changes in the thickness and the optical properties of the polymers during polymerization and electrochemical oxidation/reduction was successfully followed by the three-parameter ellipsometric technique. The optical properties of the polymers continuously changed as the film grew. The imaginary part of the refractive index of polypyrrole seemed to be dominantly determined by the existence of an absorption band around the visible range.