• 제목/요약/키워드: Solution diffusion

검색결과 1,029건 처리시간 0.025초

제설제로부터 기인한 염화물의 콘크리트 확산특성 (Chloride Diffusion of Concrete in Presence of De-icing Salt)

  • 정해문;안태송
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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    • pp.507-510
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    • 2005
  • In winter, a large amount of de-icing salts such as $CaCl_2$, NaCl have been used on highways for road safety. They make concrete structures deteriorated. In this study, the chloride diffusion of concrete in presence of de-icing salt was investigated. The diffusion coefficient of chloride in presence of $CaCl_2$ solution was larger than in presence of NaCl solution. Therefore, it is necessary to assess chloride profile in presence of $CaCl_2$ by different way from the case in presence of NaCl solution or seawater.

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복사 열손실로 인한 확산 화염의 맥동 불안정에 관한 연구 (Radiation-Induced Oscillatory Instability in Diffusion Flames)

  • 손채훈;김종수
    • 대한기계학회논문집B
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    • 제23권9호
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    • pp.1185-1191
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    • 1999
  • Radiation-induced oscillatory instability in diffusion flames is numerically investigated with nonlinear dynamics considered. As the simplest flame model, a diffusion flame established in the stagnant mixing layer is employed with optically thin gas-phase radiation and unity Lewis numbers for all species. Attention is focused on the radiation-induced extinction regime, which occurs at large $Damk\ddot{o}hler$ number. Once the steady flame structure is obtained for a prescribed value of the initial $Damk\ddot{o}hler$ number, transient solution of the flame is calculated after a finite amount of the $Damk\ddot{o}hler$-number perturbation is imposed on the steady flame. Transient evolution of the flame exhibits three types of flame-evolution behaviors, namely decaying oscillatory solution, diverging solution to extinction and stable limit-cycle solution. A dynamic extinction boundary is identified for laminar flamelet library.

ON STOCHASTIC EVOLUTION EQUATIONS WITH STATE-DEPENDENT DIFFUSION TERMS

  • Kim, Jai-Heui;Song, Jung-Hoon
    • 대한수학회지
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    • 제34권4호
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    • pp.1019-1028
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    • 1997
  • The integral solution for a deterministic evolution equation was introduced by Benilan. Similarly, in this paper, we define the integral solution for a stochastic evolution equation with a state-dependent diffusion term and prove that there exists a unique integral solution of the stochastic evolution euation under some conditions for the coefficients. Moreover we prove that this solution is a unique strong solution.

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촉매담체내에서 방향족 화합물의 역확산 (Counter-diffusion of Aromatic Compounds in Catalyst Supports)

  • 정경환;서곤
    • 공업화학
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    • 제10권4호
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    • pp.608-614
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    • 1999
  • 촉매 담체로 사용되는 알루미나와 실리카-알루미나에 흡착된 tetra-phenylprophine과 coronene이 아세톤의 주입에 의해 탈착되는 역확산 과정과, coronene이 tetra-phenylporphine 용액에 의한 역확산 과정을 조사하였다. 이상흡착용액 이론을 적용한 역확산 모델을 이용하여 역확산 과정을 해석하고 모사한 결과로부터 역확산 계수를 결정하였다. 과량의 아세톤 주입에 의한 탈착에서 tetra-phenylporphine과 coronene의 역확산 계수는 ${\sim}10^{-15}m^2/sec$ 범위로 얻어졌다. 흡착용액과 비슷한 농도를 갖는 tetra-phenylprophine 용액에 의한 역확산의 경우 탈착되는 coronene의 역확산 계수의 값도 ${\sim}10^{-15}m^2/sec$ 범위에 있으며, 세공내로 들어가는 tetra-phenylporphine의 확산 계수는 ${\sim}10^{-11}m^2/sec$ 이었다. 흡착제 밖으로 탈착되어 나오는 coronene의 역확산 계수는 아세톤이나 tetra-phenylporphine 용액의 주입에 의한 흡착-탈착의 경우 탈착제는 종류와 양에 관계없이 모두 비슷한 범위의 값을 보여 주었다. 역확산계수는 비어 있는 세공내로의 확산에 대한 유효확산계수에 비해 현저히 감소하였다. 이러한 현상은 역확산 과정에 나타나는 확산 흐름의 교차에 기인하는 것으로 설명되었다.

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수용액에서 입상활성탄에 의한 페놀류의 제거 (Removal of Phenols by Granular Activated Carbon in Aqueous Solution)

  • 권성헌;강원석
    • 한국환경과학회지
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    • 제7권4호
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    • pp.541-548
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    • 1998
  • Aqueous phase adsorption of phenols by granular activated carbon was studied in a batch adsorption vessel. Adsorption Isotherms of phenol(Ph), p-chlorophenol(PCP) and p-nitrophenol (PNP) from aqueous solution on granular activated carbon have been obtained. The experimental data were analyzed by the surface and pore diffusion models. Both models could be applied to predict the adsorption phenomena. However, the pore diffusion model was slightly better than the surface diffusion model In representing the experimental data for the initial concentration changes. Therefore, the pore diffusion model was used to predict the change of operating variables such as the agitation speed and Particle size of adsorbent which have influence on the film resistance and intraparticle diffusion.

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Evaluation of Diffusibility of Boron in Wood under Water Leaching Conditions

  • Ra, Jong-Bum;Kim, Gyu-Hyeok
    • Journal of the Korean Wood Science and Technology
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    • 제34권5호
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    • pp.98-103
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    • 2006
  • Radial and tangential diffusion coefficients of boron in wood under water leaching conditions were determined from the change of concentration profiles of boron. Egner's solution was used to obtain variable diffusion coefficients of boron because it has been known to be the only method to determine variable diffusion coefficients with no cumbersome assumption. The values of diffusion coefficients were between $0.18{\times}10^{-6}m^2/sec$ and $25.6{\times}10^{-6}cm^2/sec$. They increased with the increase of sample thicknesses, and decreased with the increase of leaching times. There was a region where Egner's method was not valid. However, Egner's solution illustrates a convenient way to evaluate diffusion characteristics of boron from wood under water leaching conditions. The diffusion coefficients at wood surface may be regarded as leaching coefficients.

희석된 메탄/산소 대향류 확산화염에서 확산-열 불안정으로 인한 화염의 비선형 동적 거동에 관한 수치해석 (A Numerical Study on Nonlinear Dynamic Behavior of Diffusive-Thermal Instability in Diluted CH4/O2 Conterflow Diffusion Flames)

  • 손채훈
    • 대한기계학회논문집B
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    • 제28권6호
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    • pp.688-696
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    • 2004
  • Nonlinear dynamic behavior of diffusive-thermal instability in diluted CH$_4$/O$_2$ diffusion flames is numerically investigated by adopting detailed chemistry and transport. Counterflow diffusion flame is adopted as a model flamelet. Particular attention is focused on the pulsating-instability regime, which arises for Lewis numbers greater than unity, and the instability occurs at high strain rate near extinction condition in this flame configuration. Once a steady flame structure is obtained for a prescribed value of initial strain rate, transient solution of the flame is calculated after a finite amount of strain-rate perturbation is imposed on the steady flame. Transient evolution of the flame depends on the initial strain rate and the amount of perturbed strain rate. Basically, the dynamic behaviors can be classified into two types, namely non-oscillatory decaying solution and diverging solution leading to extinction. The peculiar oscillatory solution, which has been found in the previous study adopting one-step chemistry and constant Lewis numbers, is net observed in this study, which is attributed to both convective flow and preferential diffusion effects.

메탄/산소 대향류 확산화염에서 확산-열 불안정으로 인한 화염의 거동에 관한 수치적 연구 (Numerical Study on Dynamic Behavior of Diffusive-Thermal Instability in $CH_4/O_2$ Conterflow Diffusion Flames)

  • 손채훈
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2004년도 제28회 KOSCO SYMPOSIUM 논문집
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    • pp.95-101
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    • 2004
  • Dynamic behavior of diffusive-thermal instability in diluted $CH_4/O_2$ diffusion flames is numerically investigated by adopting detailed chemistry and transport. Counterflow diffusion flame is adopted as a model flamelet. Particular attention is focused on the pulsating-instability regime, which arises for Lewis numbers greater than unity, and the instability occurs at high strain rate near extinction condition in this flame configuration. Once a steady flame structure is obtained for a prescribed value of initial strain rate. transient solution of the flame is calculated after a finite amount of strain-rate perturbation is imposed Oil the steady flame. Transient evolution of the flame depends on the initial strain rate and the amount of perturbed strain rate. Basically, the dynamic behaviors can be classified into two types, namely non-oscillatory decaying solution and diverging solution leading to extinction. The peculiar oscillatory solution. which has been found in the previous study adopting one-step chemistry and constant Lewis numbers, is not observed in this study, which is attributed to both convective flow and preferential diffusion effects.

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확산형 흡수식 냉동기용 기포펌프의 운전특성에 관한 연구 (Operating Characteristics of a Bubble Pump for Diffusion-Absorption Refrigerator)

  • 이현경;김선창;이재헌
    • 설비공학논문집
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    • 제13권9호
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    • pp.878-887
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    • 2001
  • Experimental investigation has been carried out to examine the operating characteristics of a bubble pump for diffusion absorption refrigerator. The effects of heat input and delivery height on generation rate of refrigerant vapor and circulation rate of solution have been investigated. as a result heat input and delivery height increase, circulation rate of solution increases. And the smaller the tube diameter, the larger the circulation rate of solution. Pumping ratio increases to a critical point and then decrease with the increase of heat input, and it increases with the increase in delivery height. In this paper, Marcus's analytical theory was also examined. It was found that the Marcus\`s analytical theory of a bubble pump was not appropriate for a bubble pump using ammonia aqueous solution as a working fluid.

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