• Title/Summary/Keyword: Solution combustion method

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Synthesis and Characterization of Y2O3:Eu Fine Particle

  • Park, Ji-Koon;Kang, Sang-Sik;Kwak, Min-Gi;Choi, Seung-Suk;Kim, Jae-Hyung;Nam, Sang-Hee
    • Transactions on Electrical and Electronic Materials
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    • v.6 no.4
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    • pp.169-172
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    • 2005
  • [ $Y_2O_3:Eu$ ] powder was synthesized using a solution-combustion method by dissolving $(CH_3CO_2)_3Y$ and $(CH_3CO_2)_3$ Eu in methyl-alcohol solution. Results from X-ray diffractometery (XRD), thermogravimetry (TG)-differential thermal analysis (DTA) show that $Y_2O_3:Eu$ crystallizes completely when the dry powder is sintered at $500^{\circ}C$. The investigated optical properties were the photoluminescence emission spectra, the excitation spectra and luminescence decay curve. Europium (Eu) concentration had no observable effect on the optical spectrum which depended on the emission intensity. The mean lifetime of synthesized phosphors was $2.3\~2.6 ms$.

Prediction of Radiative Heat Transfer in a Three-Dimensional Gas Turbine Combustor with the Finite-Volume Method (유한체적법에 의한 복잡한 형상을 갖는 3차원 가스터빈 연속기내의 복사열 전달 해석)

  • Kim, Man-Yeong;Baek, Seung-Uk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.8
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    • pp.2681-2692
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    • 1996
  • The finite-volume method for radiation in a three-dimensional non-orthogonal gas turbine combustion chamber with absorbing, emitting and anisotropically scattering medium is presented. The governing radiative transfer equation and its discretization equation using the step scheme are examined, while geometric relations which transform the Cartesian coordinate to a general body-fitted coordinate are provided to close the finite-volume formulation. The scattering phase function is modeled by a Legendre polynomial series. After a benchmark solution for three-dimensional rectangular combustor is obtained to validate the present formulation, a problem in three-dimensional non-orthogonal gas turbine combustor is investigated by changing such parameters as scattering albedo, scattering phase function and optical thickness. Heat flux in case of isotropic scattering is the same as that of non-scattering with specified heat generation in the medium. Forward scattering is found to produce higher radiative heat flux at hot and cold wall than backward scattering and optical thickness is also shown to play an important role in the problem. Results show that finite-volume method for radiation works well in orthogonal and non-orthogonal systems.

A Study on the Characteristic and Droplet Uniformity of Spray Injection to Exhaust Gas Flow from Urea Solution Injector (Urea 수용액의 배기가스 유동장내 분무 특성과 분무 균일도에 관한 연구)

  • Oh, Jung-Mo;Cha, Won-Sim;Kim, Ki-Bum;Lee, Jin-Ha;Lee, Ki-Hyung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.3
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    • pp.83-89
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    • 2011
  • Diesel engines can produce higher fuel efficiency and lower $CO_2$ emission, they are subject to ever more stringent emission regulation. However, there are two major emission concerns fo diesel engines like such as particulate matter (PM) and nitrogen oxides (NOx). Moreover, it is not easy to satisfy the regulations on the emission of NOx and PM, which are getting more strengthened. One of the solutions is to apply the new combustion concept using multistage injection such as HCCI and PCCI. The other solution is to apply after-treatment systems. For example, lean NOx trap catalyst, Urea-SCR and others have various advantages and disadvantages Especially, Urea-SCR system have advantages such as a high conversion efficiency and a wide operation conditions. Hence the key factor to implementation of Urea-SCR technology, good mixing of urea(Ammonia) and gas, reducing Ammonia slip. Urea mixer components are required to facilitate evaporation and mixing because the liquid state of urea poses significant barriers for evaporation, and the distance to mixer is the most critical that affect mixer performance. In this study, to find out the distance from injector to mixer and simulation factor, a laser diagnostics and high speed camera are used to analyze urea injector spray characteristics and to present a distribution of urea solution in transparent manifold In addition, Droplet Uniformity Index is calculated from the acquired images by using image processing method to clarify the distribution of spray.

Energy Storage Characteristics In Fixed Beds (Charging, Storing, Discharging)

  • Hassanein, Soubhi A.;Choi, Sang-Min
    • 한국연소학회:학술대회논문집
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    • 2004.11a
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    • pp.17-23
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    • 2004
  • In the present work, the numerical model was refined to predict the thermal analysis of energy storage in a fixed beds during (charging ,storing, discharging) mode. The governing energy equations of both fluid and the solid particles along with their initial and boundary conditions are derived using a two-phase, one dimensional model. The refined model is carried out by taking into account change of (air density , air specific heat) with air temperature and also by taking into considerations heat losses from bed to surrounding. Finite difference method was used to obtain solution of two governing energy equations of both fluid and solid particles through a computer program especially constructed for this purpose. The temperature field for the air and the solid are obtained, also efficiency of energy stored inside the bed is computed. Finally using refined model the effect of air flow rate per unit area Ga (0.2, 0.3, and 0.4 kg/$m^2$-s), and inlet air temperature (200, 250, 300 $^{\circ}C$) on energy storage characteristics was studied in three mode ( charging ,storing, discharging). The rock particles of diameter 1 em is used as bed material in this research.

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A Study of Thermal and flow Characteristics Induced by Fire in a Partial Enclosure (부분밀폐공간내에서 화재로 야기되는 열 및 유동특성에 관한 연구)

  • 박희용;한철희;박경우
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.5
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    • pp.1288-1300
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    • 1994
  • Mathematical modeling and numerical calculation on the flow and thermal characteristics induced by fire in a partial enclosure are performed. The solution procedures include the Shvab-Zeldovich approximation for the physical transport equations, low Reynolds number k-.epsilon. model for the turbulent fluid flow and Discrete Ordinate method(DOM) to calculate the radiative heat transfer. PMMA(Polymethylmethacrylate) is adopted as a solid fuel. Two different cases are considered : combustions with and without gas radiation occuring in a open cavity for variable pyrolyzing location of PMMA. When the fire source is located at the left-wall, the flow region of flame gas is limited at the left-wall and ceiling and recirculation region of inlet gas is formulated at neat the floor. In case of neglecting the radiative heat transfer, more large flame size and higher temperature is predicted. It is essential to consider the radiative heat transfer for analysis of fire phenomenon.

A Study on the Effect of Exhaust Pipe Length of 4 Cycle 4 Cylinder S.I. Engine on the Performance (배기관의 길이변화가 4사이클 4기통 전기 점화기관의 성능에 미치는 영향에 관한 연구)

  • 정수진;김태훈;조진호
    • Journal of the Korean Society of Safety
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    • v.8 no.3
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    • pp.3-12
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    • 1993
  • In reciprocating internal combustion engine, engine performance Is greatly affected by volumetric efficiency. For gas flow, the dynamic effects caused by the pressure pulsation have influence on the volumetric efficiency and correlate to the configuration and pipe length of intake-exhaust system. In this study, the analytic investigation of the unstudy flow In exhaust pipe has been carried out by using the method of characteristics to predict volumetric efficiency. In conculusion, it is possible to take account of the exhaust pipe tuning effect in predicting the engine performance, by the analytic solution of the unsteady flow in the pipes, and comparision of prediction with experimental datas show a good agreement on the pressure varision in the exhaust pipe which has Influence on the volumetric efficiency and performance of engine.

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Energy Storage Characteristics in Fixed Beds;Part 1. Charging Mode

  • Hassanein, Soubhi A.;Choi, Sang-Min
    • 한국연소학회:학술대회논문집
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    • 2004.06a
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    • pp.158-164
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    • 2004
  • In the present work, the numerical model was refined to predict the thermal analysis of energy storage in a fixed beds during charging mode. The governing energy equations of both fluid and the solid particles along with their initial and boundary conditions are derived using a two-phase, one dimensional model. The refined model is carried out by taking into account change of (air density , air specific heat) with air temperature and also by taking into considerations heat losses from bed to surrounding. Finite difference method was used to obtain solution of two governing energy equations of both fluid and solid particles through a computer program especially constructed for this purpose. The temperature field for the air and the solid are obtained, also energy stored inside the bed is computed. A comparison between refined model and non refined model is done. Finally using refined model the effect of bed material (Glass, Fine clay ,and aluminum ), and air flow rate per unit area Ga (0.3, 0.4, and 0.5 kg/$m^2$-s) on energy storage characteristics was studied.

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Quantitative Vapor Phase Exciplex Fluorescence Measurements at High Ambient Temperature and Pressure

  • Kim, Tongwoo;Jaal B. Ghandhi
    • Journal of Mechanical Science and Technology
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    • v.17 no.1
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    • pp.157-167
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    • 2003
  • The exciplex fluorescence technique with the TMPD (tetamethyl-Ρ-phenylene-diamine) / naphthalene dopant system was applied in a combustion-type constant-volume spray chamber. A detailed set of calibration experiments has been performed in order to quantify the TMPD fluorescence signal. It has been demonstrated that the TMPD fluorescence intensity was directly proportional to concentration, was independent of the chamber pressure, and was not sensitive to quenching by either water vapor or carbon dioxide. Using a dual heated-jet experiment, the temperature dependence of TMPD fluorescence up to 1000 K was measured. The temperature field in the spray images was determined using a simple mixing model, and an iterative solution method was used to determine the concentration and temperature field including the additional effects of the laser sheet extinction. The integrated fuel vapor concentration compared favorably with the measured amount of injected fuel when all of the liquid fuel had evaporated.

Study on Exhaust Gas Composition in the Four Ctcle Gasoline Engind -Nonequilibrium Calculation of $NO_{\chi}$ - (4사이클 가솔린기관의 배기조성에 관한 연구 -$NO_{\chi}$의 비평형 계산-)

  • ;;Oh, Yeong Il
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.1 no.4
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    • pp.171-181
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    • 1977
  • This paper is aiming at calculating NOx concentration, which is one of the harmhul components of emission from the gasoline engine, formed in the combustor through the presess of combustion. Instantaneous temperature and concentration of each components for each division can be determined by the solution of simulatneous equation of reaction equation and equation of energy conservation, inputting the estimated temperature with a considerably wide rage of temperature. After determining instantaneous temperature and instantanous concentration of each components, the nonequilibrium calculation is performed based on the reaction kinetics in order to determine NOx concentration. To summarize the result abtained from the above method ;through the passage of NO concentration, NO concentration is the highest in the first division and it is gradually decreasing through the following divisions In the final division, NO concentation is the lowest.

A study on the performance prediction of 4 cycle 4 cylinder S.I. engine considering the unsteady flow in the intake and exhaust pipes (흡배기 관내의 비정상 유동을 고려한 4사이클, 4기통 전기.점화 기관의 성능 예측에 관한 연구)

  • 박성서;김응서
    • Journal of the korean Society of Automotive Engineers
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    • v.13 no.6
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    • pp.72-81
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    • 1991
  • In this study, the analytic investigation of the unsteady flow in the intake and exhaust pipes has been carried out using the method of characteristics in one direction to predict volumetric efficiency. Based on the calculated volumetric efficiency, three zone predictive analysis using Wiebe function was applied to predict the engine performance and the results were compared with experiment. Mixture in the cylinder is subdivided into three zones during combustion process in this analysis; adiabatic core zone, thermal boundary layer zone and unburned zone. In each zone, pressure, temperature and gas composition have been calculated. In conclusion, it is possible to take account of the intake and exhaust pipe tuning effect in predicting the engine performance, by the analytic solution of the unsteady flow in the pipes, and comparison of prediction with experimental results shows a good agreement on the pressure variation in the intake and exhaust pipes which has a direct influence on the volumetric efficiency and performance of the engine.

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