• 제목/요약/키워드: Solution Temperature

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Study on Characteristics of Change of Urea and Biuret Content by Temperature Variation in Urea Solution (요소수(Urea solution)의 온도변화에 따른 요소 및 뷰렛함량 변화 특성 연구)

  • Doe, Jin-woo;Park, Tae-sung;Lee, Yu-rim;Yim, Eui-soon;Lee, Joung-min;Kang, Hyung-kyu
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.4
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    • pp.1307-1319
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    • 2018
  • As interests in the air pollution increases, many kinds of researches are underway on the reduction of air pollutants. The removal of nitrogen oxides from the emission gas of diesel vehicles using urea solution has shown a great effect. The quality of urea solution is strictly defined by domestic law, but the increase of impurities in urea solution reduces the effect of reducing nitrogen oxides. Therefore, in this study, the change of physical properties of urea solution was analyzed after heating the urea solution for a certain temperature and time. Also, the changes of physical properties of urea solution were analyzed according to kinds of storage container and temperature for storing the urea solution. After heating the urea solution for a certain period of time, the biuret content in urea solution increased and the content of urea decreased. As the urea content decreased, both density and refractive index decreased. In the storage stability test carried out at a constant temperature with iron and PET containers, no change in physical properties was observed.

Interaction between Poly(L-lysine) and Poly(N-isopropyl acrylamide-co-acrylic acid) in Aqueous Solution

  • Sung, Yong-Kiel;Yoo, Mi-Kyong;Cho, Chong-Su
    • Macromolecular Research
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    • v.8 no.1
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    • pp.26-33
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    • 2000
  • A series of pH/temperature sensitive polymers were synthesized by copolymerizing N-isopro-pyl acrylamide(NIPAAm) and acrylic acid(AAc) . The influence of polyelectrolyte between poly(allyl amine) (PAA) and poly(L-lysine)(PLL) on the lower critical solution temperature(LCST) of pH/temperature sensitive polymer was compared in the range of pH 2∼12. The LCST of PNIPAAm/water in aqueous poly(NIPAAm-co-AAc) solution was determined by cloud point measurements. A polyelectrolyte complex was prepared by mixing poly(NIPAAm-co-AAc) with poly(allyl amine) (PAA) or poly(L-lysine) (PLL) solutions as anionic and cationic polyelectrolytes, respectively. The effect of polyelectrolyte complex formation on the conformation of PLL was studied as a function of temperature by means of circular dichroism(CD). The cloud points of PNIPAAm in the aqueous copolymers solutions were stongly affected by pH, the presence of polyelectrolyte solute, AAc content, and charge density. The polyelectrolyte complex was formed at neutral condition. The influence of more hydrophobic PLL as a polyelectrolyte on the cloud point of PNIPAAm in the aqueous copolymer solution was stronger than that of poly(allyl amine)(PAA). Although polymer-polymer complex was formed between poly(NIPAAm-co-AAc) and PLL, the conformational change of PLL did not occur due to steric hinderance of bulky N-isopropyl groups of PNIPAAm.

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The effects of Se evaporation temperature on CIS absorber layer fabricated by non-vacuum process (Se 증발온도가 비진공 공정으로 제조한 CIS 광흡수층에 미치는 영향)

  • Park, Myoung-Guk;Ahn, Se-Jin;Yoon, Jea-Ho;Yoon, Kyung-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.441-443
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    • 2008
  • A non-vacuum process for fabrication of $CuInSe_2$ (CIS) absorber layer from the corresponding Cu, In solution precursors was described. Cu, In solution precursors was prepared by a room temperature colloidal route by reacting the starting materials $Cu(NO_3)_2$, $InCl_3$ and methanol. The Cu, In solution precursors were mixed with ethylcellulose as organic binder material for the rheology of the mixture to be adjusted for the doctor blade method. After depositing the mixture of Cu, In solution with binder on Mo/glass substrate, the samples were preheated on the hot plate in air to evaporate remaining solvents and to burn the organic binder material. Subsequently, the resultant CI/Mo/glass sample was selenized in Se evaporation in order to get a solar cell applicable dense CIS absorber layer. The CIS absorber layer selenized at $530^{\circ}C$ substrate temperature for 30 min with various Se gas evaporation temperature was characterized by XRD, SEM, EDS.

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A Study on the Stability of Diluted Bee Venom Solution (봉약침액(蜂藥鍼液)의 안정성(安定性) 연구(硏究))

  • Kang, Mi-Suk;Byun, Im-Jeung;Lee, Seong-No;Kim, Kee-Hyun
    • Journal of Pharmacopuncture
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    • v.6 no.2
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    • pp.105-111
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    • 2003
  • Objective : The purpose of this study was to investigate the stability of bee venom according to the keeping method and period. Method : The author observed microbial contamination of bee venom in nutrient agar, broth, YPD agar and YPD media and antibacterial activity for S. aureus, E. coli manufactured 12, 6 and 3 months ago as the two type of room temperature and $4^{\circ}C$ cold storage. Results : 1. 1:3,000 and 1:4,000 diluted bee venom solution did not show microbial contamination both room temperature and cold storage within twelve months. 2. There was antibacterial activity of diluted bee venom for S. aureus in cold storage within twelve months and there was no antibacterial activity of diluted bee venom for S. aureus in twelve months, room temperature storage. 3. We could not observe the zone of inhibition around paper disc of all for E.coli. in 1:3,000, 1:30,000 and 1:3,000,000 diluted bee venom solution, respectively. According to results, we expect that diluted bee venom solution is stable both cold and room temperature storage within twelve months.

Performance Experiment of Generator for Household Absorption Chiller and Heater (가정용 흡수식 냉난방기 개발을 위한 재생기 성능실험)

  • Yu, Sun-Il;Kwon, Oh-Kyung;Yoon, Jung-In
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.23 no.10
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    • pp.1347-1354
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    • 1999
  • Recently, the markets of the air conditioner are enlarging. The market size will reach 2.0 billion won in 2000. Electric heat pumps have been utilized as main residential air conditioners. especially in Korea. They cause a surge up electric power demand during summer. Moreover, the use of HCFCs and HFCs causes serious problem to the global environment such as global warming and ozone layer destruction. Absorption chiller and heater could solve such problems. It was built and tested for analyzing the performance of the generator for absorption chiller and heater. Experiment was done with a high temperature generator, a low temperature generator, heat exchangers, a condenser and a solution tank. It was tested that the double effect series flow cycle with two kinds of solution cycle. Solution cycle B showed better than solution cycle A. Two kinds of heat exchanger were used, where one's heat transfer area is bigger than the other. Bigger one increased a little performance of absorption chiller and heater. But it was not economical. From this study, we got that the coefficient of performance(COP) is 0.82 and the capacity is 7.24 kW for an absorption chiller and heater.

Study on the Performance Characteristics with the Height of a Regenerator and Dehumidifier for Liquid Desiccant Dehumidification System (액체식 제습시스템을 위한 재생기와 제습기의 높이에 따른 성능특성에 관한 연구)

  • 이수동;박문수;정진은;최영석
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.7
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    • pp.630-638
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    • 2004
  • Liquid desiccant dehumidification systems have the ability to provide efficient humidity and temperature control while saving the electrical energy requirement for air conditioning as compared to a conventional system. The dehumidifier and the regenerator form the heart of this system. The latent part of the cooling load is overcome using liquid desiccant. The model regenerator has been designed to study the absorption characteristic of the aqueous triethylene glycol (TEG) solution which is in the flow range from 20 to 50 LPM. Also, this system designed that was able to change the height of the regenerator and dehumidifier. Because the effect of performance have different result according the height. The effect of performance factors of the regenerator with inlet solution flow rate, air flow rate, solution concentration, solution temperature, brine temperature, air temperature and inlet air relative humidity have been analyzed. Data obtained are useful for design guidance and performance analysis of the hybrid air conditioning system.

The effect of high-temperature on foamed concrete

  • Canbaz, Mehmet;Dakman, Hafid;Arslan, Baris;Buyuksungur, Arda
    • Computers and Concrete
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    • v.24 no.1
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    • pp.1-6
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    • 2019
  • Within the scope of this study, the foam solution was prepared by properly mixing sulfonate based foam agent with water. Furthermore, this solution was mixed with the mixture of fine sand, cement, and water to produce foamed concrete. The mixture ratios which are the percentage of foam solution used in foam concrete were chosen as 0, 20, 40 and 60% by vol. After these groups reached 28 days of strength, they were heated to 20, 100, 400 and $700^{\circ}C$ respectively. Afterward, high-temperature effects on the foamed concrete were obtained by employing physical and mechanical properties tests. Additionally, SEM (scanning electron microscope) and EDX (energy-dispersive X-ray spectroscopy) tests were employed to analyze the microstructure, and ${\mu}-CT$ (micro computed tomography) images were used to reconstruct 3-D models of the heat-treated specimens. Then, these models are analyzed to examine the void structures and the changes in these structures due to the high temperatures. The study has shown that the void structures reduce the high-temperature effects and the foam solution could be mixed with concrete up to 40 % by vol. where the high strength of foamed concrete is non-mandatory.

Measurement of the Corrosion Rate of Aluminum in Alkaline Solution (알칼리 용액에서 알루미늄의 부식속도 측정)

  • Shim Eun-Gi;Hwang Young-Gi;Chun Hai-Soo
    • Journal of the Korean Electrochemical Society
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    • v.2 no.3
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    • pp.117-122
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    • 1999
  • This study investigated the corrosion rate of aluminum in alkaline solution. It was performed to observe the effects of alloy element, alkalinity (KOH concentration), solution temperature, and inhibitor and its concentration in the solution. Among species of aluminum, AA-1050 showed the lowest corrosion rate due to its high purity $(>199\%)$, whereas alloys containing Mg anuor Mn were highly corroded, relatively. The corrosion rate could be reduced over than $50\%$ by saturating the solution with ZnO, while ZnAc did not work as an inhibitor. The inhibition effect of ZnO increased with increasing the alkalinity and solution temperature. It was found that the corrosion rate linearly increased with the concentration of KOH in first order and exponentially decreased with the inverse of the solution temperature. An analysis of the corroded material covered the surface of aluminum was made by SEM and EDS. According to the analytical results by using XRD, it was confirmed that $Al(OH)_3$ was produced from the corrosion of aluminum in KOH solution.

Physical and Chemical Effects on the Sonication Treatment of Chitosan Solution

  • LEE Keun-Tai;PARK Seong-Min;PARK Chan-Kyu;KIM Sang-Moo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.29 no.6
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    • pp.843-848
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    • 1996
  • As the first step of studies related to production of chitooligosaccharides by physical methods, chitosan solution were sonicated with 20 kHz and various treatment effects were examined to present fundamental data of sonicated chitosan solution. Intrinsic viscosity of chitosan solution sharply decreased from 3.76 dl/g to 2.90 dl/g until 5 minutes of sonication and then slowly decreased. With low volume of chitosan solution, sonication was very effective and temperature of chitosan solution slightly affected the efficiency of sonication. In case of changing the solvent, no significant differences were observed on the effect of sonication, however, acetate buffer had highest sonication effect among various solvents. The sonication effect was increased as the increasement of the value of pH, on the contrary, ionic strength and type of counterions showed no effect on sonication. With these results, we assumed that optimal sonication treatment would be as follows, solution volume was $10\~20\;ml$, temperature range was $20\~30^{\circ}C$, pH value of solution was 4.5 and type of solvent was acetate buffer.

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Effect of Solution Temperature on the Cavitation Degradation Properties of Epoxy Coatings for Seawater Piping

  • Jeon, J.M.;Yoo, Y.R.;Jeong, M.J.;Kim, Y.C.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.20 no.6
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    • pp.335-346
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    • 2021
  • Since epoxy resin coating shows excellent properties in formability, adhesion, and corrosion resistance, they have been extensively used in many industries. However, various types of damages in the epoxy coated tube within a relative short time have been reported due to cavitation erosion, liquid impingement, variation of temperature and pressure. Nevertheless, there has been little research on the effect of temperature on the cavitation degradation of epoxy coatings. Therefore, this work used an ultrasonic cavitation tester to focus on the effect of solution temperature on the cavitation properties of 3 kinds of epoxy coatings in 3.5% NaCl. The cavitation properties were discussed basis on the material properties and environmental aspects. As the solution temperature increased, even though with large fluctuation, the cavitation degradation rates of A and B coatings were reduced rapidly, but the rate of C coating was decreased gradually. In addition to the cushioning effect, the reason that the cavitation degradation rate reduced with solution temperature was partly related to the brittle fracture and water absorptivity of the epoxy coatings, and the water density, but was little related to the shape and composition of the compound in the coatings or the phase transition of the epoxy coating.