• Bulletin of the Korean Chemical Society
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• 제20권10호
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• pp.1209-1212
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• 1999

The entropies and chemical potentials of hard-sphere solutes solvated in hard-sphere solids were calculated by Monte Carlo method using the radial free-space distribution function. This method is based on calculating the entropy by comparing the free volume of a molecule with that of an ideal gas, and is applicable even when the size of solute is very large and the solvent is a solid. When the diameter of hard-sphere solute is small the solute molecule behaves as like as a fluid in solid structures, but when the diameter of solute becomes large, a fluid-to-solid phase transition takes place. The fluid-to-solid phase transition occurs at the region of the smaller size of solute with the more increase of solvent density. The least square fit values of analytical form of the radial free-space distribution functions of solute molecules are presented for future uses.

• Metals and materials international
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• 제24권6호
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• pp.1275-1284
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• 2018

A rotating magnetic field (RMF) was applied in the solidification process of Cu-8Fe alloy. Focus on the mechanism of RMF on the solid solution Fe(Cu) atoms in Cu-8Fe alloy, the influences of RMF on solidification structure, solute distribution, and material properties were discussed. Results show that the solidification behavior of Cu-Fe alloy have influenced through the change of temperature and solute fields in the presence of an applied RMF. The Fe dendrites were refined and transformed to rosettes or spherical grains under forced convection. The solute distribution in Cu-rich phase and Fe-rich phase were changed because of the variation of the supercooling degree and the solidification rate. Further, the variation in solute distribution was impacted the strengthening mechanism and conductive mechanism of the material.

• 대한토목학회논문집
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• 제29권1B호
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• pp.73-81
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• 2009

본 연구에서는 개수로 흐름에서 오염물질 이동 현상에 대한 이차흐름의 영향을 분석하였다. 운동량 방정식과 스칼라 수송 방정식에서의 난류 폐합을 위해 레이놀즈응력 모형 및 GGDH 모형을 사용하였다. 개발된 모형을 이용하여 조 세립상의 횡방향 연속구조를 갖는 개수로 흐름에서의 오염물질 이동에 대한 이차흐름의 영향을 분석하였다. 그 결과, 이차흐름의 영향으로 인해 최대 농도 값의 발생 위치가 이동하는 것으로 나타났으며, 농도 분포 역시 정규 분포에서 거리에 따라 점차 왜곡 되는 것으로 확인되었다. 또한, 이차흐름의 영향으로 자유수면 근처에서는 매끄러운 하상에 비해 거친 하상에서의 오염물질 농도가 더 크게 발생되었으며, 스칼라-흐름률을 계산한 결과, 오염물질의 수직방향 확산은 매끄러운 하상에 비해 거친 하상에서 더 빨리 진행되는 것으로 확인되었다. 한편, 농도 분포 변화에 대한 이차흐름 및 스칼라-흐름률의 영향을 살펴보기 위하여 스칼라 수송률 분석을 수행하였다.

• Bulletin of the Korean Chemical Society
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• 제21권1호
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• pp.105-109
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• 2000

High-performance liquid chromatography is suitable for getting thermodynamic information about solute-solvent interactions. We used a squalane impregnated $C_{18}$ phase as a presumably bulk-like stationary phase to secure a simple partition mechanism for solute retention in reversed phase liquid chromatographic system. We measured retention data of some selected solutes (benzene, toluene, ethylbenzene, propylbenzene, butylbenzene, phenol, benzylalcohol, phenethylalcohol, benzylacetone, acetophenone, benzonitrile, benzylcyanide) at 25, 30, 35, 40, 45, and 50 $^{\circ}C$ in 30/70, 40/60, 50/50, 60/40 and 70/30 (v/v%) acetonitrile/water eluents. The van't Hoff plots were nicely linear, thus we calculated dependable thermodynamic values such as enthalpies and entropies of solute transfer from the mobile phase to the stationary phase based on more than four retention measurements on different days (or weeks). We found that the cavity formation effect was the major factor in solute distribution between the mobile and stationary phases in the system studied here. Our data were com-pared with some relevant literature data.

• Water Engineering Research
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• 제6권2호
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• pp.49-61
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• 2005

This paper presents the numerical study to examine characteristics of fluid flow and solute transport in a rough fracture subject to effective normal stresses. The aperture distribution is generated by using the self-affine fractal model. In order to represent a nonlinear relationship between the supported normal stress and the fracture aperture, we combine a simple mechanical model with the local flow model. The solute transport is simulated using the random walk particle following algorithm. Results of numerical simulations show that the flow is significantly affected by the geometry of aperture distribution varying with the effective normal stress level while it is slightly affected by the fractal dimension that determines the degree of the fracture surface roughness. However, solute transport is influenced by the effective normal stress as well as the fracture surface roughness.

• 대한금속재료학회지
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• 제47권2호
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• pp.71-78
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• 2009

The precipitation behavior of solute carbon and nitrogen strongly affects the mechanical properties of low-carbon automotive panel. In the present study, the effects of aluminum and solute nitrogen on the bake hardenability and strain aging of extremely low-carbon steel with carbon content below 15 ppm has been investigated. The ferrite grain size and distribution of precipitates were varied with the amount of aluminum content of 0.003 to ~ 0.100 wt% in a constant solute carbon and nitrogen. With increasing the aluminum content, the ferrite grain size is increased and strain aging is delayed. The strain aging is also delayed by increasing the annealing temperature, although the ferrite grain size is not much changed.

• 한국주조공학회지
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• 제10권3호
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• pp.219-224
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• 1990

In this, we have investigated the solute behavior in front of solid-liquid interface according to the change of the cooling rate in bronze alloy and phosphor bronze alloy. The conclusive summary is as follows: 1) The secondary dendrite arm spacing was decreased with increasing the cooling rate. 2) The minimum solute concentration happened to along centerline of primary arm, and the maximum solute concentration was found at the boundary of arm or between the arms the minimum solute concentration was increased with the cooling rate. 3) Segregation Index S was decreased with increasing the cooling rate and content of P. 4) The degree of the microsegregation was decreased with increasing the cooling rate. The effective distribution coefficient, Ke was increased with addition of P in Cu-Sn.

• 한국수자원학회논문집
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• 제32권6호
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• pp.751-762
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• 1999

본 연구에서는 천이상태의 비포화 오염원 이송확산 특성을 분석하기 위하여 토양의 물리, 화확적 특성을 알고 있는 두 종류의 현장토양(SUS,KUS)을 이용하여 1차원 실내실험을 수행하였는데, 천이상태의 토양내 함수량과 오염원의 농도를 측정하기 위하여 본 연구에서 개발한 TDR을 이용한 농도측정법을 이용하였으며, 질량평형을 이용하여 측정방법의 정도도 분석하였다. 실험결과에 의하면 급격한 습윤전선의 전진에 따른 종형의 함수량 변화를 관측할 수 있었고, 이때 오염원의 이송확산은 습윤전선을 추월하지 않으면서 농도 천이구간의 중심점으로부터 전방영역의 농도분포가 습윤전선에서의 함수량 분포와 유사한 종형을 이루고 있음을 관측할 수 있었다. 본 연구에서 제안한 측정법을 적용한 결과 함수량이 0.15이상일 경우 매우 좋은 결과를 보였으며, 측정오차를 검토한 결과 10%이하의 오차율을 보였다. 따라서 본 논문에서 개발된 천이상태의 오염원 농도 측정법은 기존의 방법에 비하여 정확하고 적용이 용이한 측정방법으로 판단된다. 수치모형 HYDRUS를 수행한 수치결과와 실험결과를 비교하였는데, 비포화 흐름특성은 실험결과와 수치결과가 일치하고 있으나, 오염원 이송확산 특성은 수치결과가 실험결과를 더 많이 확산되는 경향을 보였다. 따라서 수치모형을 현장에 적용할 경우 수치모형에 적용할 확산지수는 BTC 실험을 통하여 측정한 확산지수, 수차확산, 흡착계수, 적용영역의 크기 등을 고려하여 결정하여야 할 것으로 판단된다.

• 한국막학회:학술대회논문집
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• 한국막학회 1991년도 추계 총회 및 학술발표회
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• pp.4-8
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• 1991

The characterization of pore properties (mean pore size and pore size distribution) of the active layer in a UF membrane is important not only in order to obtain information about the factors affecting pore formation during membrane manufacturing but also to understand deeply the mechanism of solute and solvent transport through pores. Many methods of characterizing quantitatively the pore properties of UF membranes have been suggested in the literature: solvent and gas flow measurement, bubble point determination, electron microscopy, gas adsorption/desorption measurement, rejection measurement etc. But most of these methods involve time-consuming procedures and involve some wellknown problems and uncertainties.

• 한국주조공학회지
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• 제16권6호
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• pp.556-564
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• 1996

Variation of shape and size of solid particles and solute redistribution in Mg-9wt.%Al, AI-4.5wt.% Cu, and AI-7wt.%Si alloys were investigated when they were heated to semi-solid temperatures and held without stirring. In the case of Mg-9wt.% Al and Al-4.5wt.%Cu alloys, the polygonal shaped solid particles were agglomerated with non-uniform distribution, and there were no disappearance of the solid/solid boundary until the end of melting. But in the case of an Al-7wt.%Si alloys, two or three spherical shaped particles were coalesced or separated individually, and the coalesced particles had no solid/solid interface on the contrary to the prevous case. The maximum size of solid particles during isothermal heating at high temperature was smaller than that at lower temperature, but the time required to reach the maximum size at high temperature was shorter than that at lower temperature. The concentrations of main solute atom whose distribution coefficient is lower than 1, decreased in the primary solid particles as the liquid fraction increased, and the gradient of solute concentration was steeper in Mg-9wt.%Al alloy and Al-4.5wt.%Cu alloy than that of Al-7wt.%Si alloy.