• Journal of Environmental Science International
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• v.20 no.9
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• pp.1069-1078
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• 2011

The environmental changes related to hypoxic water mass were investigated at Gamak bay in summer times, June, July and August 2006. The hypoxic water mass was found, in first, at the northern area of Gamak bay on 27 June. This water mass has been sustained until the end of August and disappear on 13 September. In Gamak bay, the hypoxic water mass was closely related to geography. During the formation of oxygen deficiency, changes in dissolved nutrients was studied and found that on surface layer and lower layer, DIN were 0.80 ${\mu}M$~19.8 ${\mu}M$(6.03 ${\mu}M$) and 1.13 ${\mu}M$～60.83 ${\mu}M$(10.66 ${\mu}M$), and DIP were 0.01 ${\mu}M$～0.92 ${\mu}M$(0.24 ${\mu}M$), and 0.01 ${\mu}M$～3.57 ${\mu}M$(0.49 ${\mu}M$), respectively, far higher distribution on lower layer of the water where hypoxic water mass was occurred. The configuration of phosphorus was analyzed to figure out the possibility of release of phosphorus from sediments. It was found that the Labile-Phosphorus, which is capable of easy move to water layer by following environmental change was found more than 70%. Therefore, in Gamak bay, it was found that the possibility of large amount of release of soluble P into the water, while hypoxic water mass was occurred in deep layer was higher. It is suggested that DIP in the northern sea of Gamak bay mainly sourced from the soluble P from lower layer of the waters where hypoxic water mass was created more than that from basin. However, existence form of phosphorus in sediments during normal times, not during creation of hypoxic water mass, needs further study.

• Animal cells and systems
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• v.7 no.4
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• pp.289-294
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• 2003

To quantify nutrient loading from emergent macrophytes through leaching in the littoral zones of Paldang Reservoir, we conducted incubation experiments using leaf litter of the emergent macrophyte, Zizaniz latifolia. To separate the leaching process from microbial decay, we used $HgCl_2$ to suppress microbial activity during the experiment. We measured electric conductivity, absorbance at 280nm, total nitrogen and dissolved inorganic nitrogen, total phosphorus and soluble reactive phosphorus, Na, K, Mg and Ca amounts in leaf litter and in water. In addition, we examined the effects of water temperature and ion concentrations of ambient water on the leaching process. A total of 6% of the initial ash-free dry mass of leaf litter was lost due to leaching during incubation (four days). Electric conductivity and A280 continued to increase and saturate during the incubation. To compare reaching rates of different nutrients, we fitted leaching dynamics with a hyperbolic saturation function [Y=AㆍX/(B+X)]. From these fittings, we found that ratios of leaching amounts to nutrient concentration in the litter were in the order of K > Na > Mg > P > Ca > N. Leaching from leaf litter of Z. latifolia was dependent on water temperature while it was not related with ion concentrations in the ambient water. Our results suggest that the leaching process of nutrients, especially phosphorus, from aquatic macrophytes provides considerable contribution to the eutrophication of the Paldang Reservoir ecosystem.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.1
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• pp.78-83
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• 2011

Phosphorus (P) which is required by all living plants and animals is an important input for economic crop and livestock production systems. Phosphorus containing compounds are essential for photosynthesis in plants, for energy transformations and for the activity of some hormones in both plants and animals. Loss of soil P to water can occur in particulate forms of P with eroded surface soil and in soluble forms in runoff, soil interflow, and deep leaching. The excessive losses of P from agricultural systems can degrade water quality of surface waters, resulting in accelerating eutrophication. Thus, P is often the limiting element and its control is of prime importance in reducing the accelerated eutrophication of surface waters. However, reserves of phosphate begin to run out, the impacts are likely be immense in terms of rising food prices, growing food insecurity. This paper reviews underappreciated resource as a key component of fertilizers and one of controversial pollutant in terms agronomy and environment.

• Journal of Environmental Science International
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• v.22 no.12
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• pp.1643-1650
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• 2013

This study investigated water quality of effluents and stream from the sewage treatment plants located at Gumi Complex 4, Gumi, and Wonpyeong in Gumi. Downstream region was found to increase the concentration of nutrients for sewage treatment plant effluent. Both phosphorus and nitrogen were accounted most as soluble form. In particular, the high ratio of dissolved effluent of sewage treatment plants were investigated. In the streams, Phosphorus concentration was high during rainy season and nitrogen concentration was high in the dry season. Sewage treatment plant effluent was relatively less microbial activity and nutrient concentrations were higher in the winter. TN/TP ratio was the highest in the upstream region and the lowest in the sewage treatment plant effluent. The effect of the nutrient matter from a discharge of a sewage treatment plant on rivers varied depending on the size of the river and the treatment plant. However, the influence of the concentration was greater than that of flowrate. Sewage treatment plant effluent loads phosphorus, nitrogen accounted for 8% and 6% respectively at the point N3 of the Nakdong river.

• Membrane and Water Treatment
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• v.9 no.3
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• pp.181-188
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• 2018

A sidestream contains the filtrate or concentrate from the belt filter press, filter backwash and supernatant from sludge digesters. The sidestream flow, which heads back into the sewage treatment train, is about 1-3% less than the influent flow. However, the sidestream can increase the nutrient load since it contains high concentrations of phosphorus and nitrogen. In this study, the removal of PO4-P with organic matter characteristics and bacteriological changes during the sidestream treatment via ladle furnace (LF) slag was investigated. The sidestream used in this study consisted of 11-14% PO4-P and 3.2-3.6% soluble chemical oxygen demand in influent loading rates. LF slag, which had a relatively high $Ca^{2+}$ release compared to other slags, was used to remove $PO_4-P$ from the sidestream. The phosphate removal rates increased as the slag particle size decreased 19.1% (2.0-4.0 mm, 25.2% (1.0-2.0 mm) and 79.9% (0.5-1.0 mm). The removal rates of dissolved organic carbon, soluble chemical oxygen demand, color and aromatic organic matter ($UV_{254}$) were 17.6, 41.7, 90.2 and 77.3%, respectively. Fluorescence excitation-emission matrices and liquid chromatography-organic carbon detection demonstrated that the sidestream treatment via LF slag was effective in the removal of biopolymers. However, the removal of dissolved organic matter was not significant during the treatment. The intact bacterial biomass decreased from $1.64{\times}10^8cells/mL$ to $1.05{\times}10^8cells/mL$. The use of LF slag was effective for the removal of phosphate and the removal efficiency of phosphate was greater than 80% for up to 100 bed volumes.

• Journal of Environmental Science International
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• v.28 no.5
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• pp.511-520
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• 2019

This study was investigated to improve the phosphorus release and water quality by transformation of sedimentary P fraction for application of $CaO_2$. For the experiment, 0.5% (w/w) of $CaO_2$ was homogenized in the sediment and incubated with the control for 20 days. The analytical results showed that pH increased with $CaO_2$ and redox potential (ORP) was improved in the sediment of the reactor. The growth rate of chlorophyll-a was lower in the $CaO_2$ reactor and Dissolved Oxygen (DO) of overlying water maintained higher than that of the control. Total phosphorus (T-P) concentration in the overlying water increased from the initial concentration to 0.304mg/L in the control at 20 days. The reactor of $CaO_2$ was lowered by 29.3%. Ex-P, Fe-P and Ca-P in sediment P fraction were increased with the $CaO_2$. The formation of bound Fe-P and Ca-P in the sediments seemed to control the release of P by removing the Soluble Reactive Phosphorus (SRP) presented in the pore water. From the result, this indicated that the reduction of P release from the sediments seems to be effective in suppressing the eutrophication of P and improving the oxygen condition in the water quality with the application of $CaO_2$.

• Journal of Environmental Science International
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• v.18 no.5
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• pp.589-594
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• 2009

The goals of this study were conducted to investigate the effects of applying liquid aluminum chloride ($AlCl_3$) to rice hulls on pH and soluble reactive P (SRP). A total of 800 broiler chicks (4 treatments $\times$ 4 replicates $\times$ 50 birds) were housed into 16 floor pens in a single house for 5 weeks. The treatments were divided into 4 groups: control, 100 g of liquid $AlCl_3/kg$ of rice hulls, 200 g of liquid $AlCl_3/kg$ of rice hulls, and 300 g of liquid $AlCl_3/kg$ of rice hulls. Liquid $AlCl_3$ was sprayed on the rice hulls surface at a rate of 100 g, 200 g, and 300 g liquid $AlCl_3$ per kg rice hull. pH values and SRP contents were significantly decreased (P<0.05) with the increased liquid $AlCl_3$ levels in comparison with control. However, no significant differences in SRP contents were observed among all treatments at 3 and 4 weeks. Applying 100 g, 200 g, and 300 g liquid $AlCl_3$ to rice hulls reduced SRP contents by 18, 25, and 52% for 5 weeks, respectively, compared with the controls. In conclusion, these results suggest that using liquid $AlCl_3$ on rice hulls should be promising for reducing water contamination and resulted in a reduction in SRP contents, which reduced pH.

• Korean Journal of Environmental Agriculture
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• v.17 no.4
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• pp.362-367
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• 1998

To investigate the effects of simulated acid rain(SAR) on the downward movement of mineral nutrients, SARs of different pH were applied to the soil. SAR of pH 2.0 decreased the soil pH greatly, while SAR of pH 4.0 and 6.0 did not change the soil pH to compare to that of SAR of pH 2.0. Decrease in soil pH was in the order of sandy loam > loam > clay loam. The amoumt of leached exchangeable and soluble bases from the soil due to the penetration of SAR was in the order of Ca >Mg > K. After application of 1200mm SAR of pH 2.0 in to the soil downward mean movements of the exchangeable and soluble bases was in the order of Mg > Ca > K in sandy loam and loam soil and Ca > Mg > K in clay loam soil. Downward movements of the those bases under pH 4.0 into the soil was in the order of Mg > K > Ca in sandy loam and clay loam, and K > Mg > Ca in loam soil. Available phosphorus moved slightly downward with increasing acidity of the SAR.

• 한국해양학회지
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• v.5 no.1
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• pp.14-29
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• 1970

Tidal variations of various chemical constituents in the laver bed sea waters in Wan Do Gun were determined over one spring tidal cycle from Oct. 1968 to Feb. 1969. Total ranges and means of the contents at Pyung-il Do and Wan Do are as follows. Although the average monthly variations of each content at Pyung-il Do were similar to those at Wan Do, most of the contents at Pyung-il Do were at a slightly higher level than at Wan Do. The values of silicate-silicon, phosphate- phosphorus and soluble iron, however, showed high levels at Wan Do. Chlorinity, magnesium, calcium, dissolved oxygen, silicate-silicon and phosphate-phosphorus contents increased from Oct. 1968 to Feb. 1969, though the content of soluble iron decreased before December and slightly increased in January and February. The average monthly variations of ammonia-nitrogen and nitrate-nitrogen contents were irregular. The nitrite-nitrogen content appeared in trace amounts in the months with a comparatively high water temperature, i.e., October and November, but in midwinter it was undetected. The ranges of the tidal variations of the contents of each chemical constituent were not significantly wide, though the contents varied excessively by the hour, and this may show the irregularity of the water quality in Wan Do Gun coastal area. As a rule, no regular tidal variation of the chlorinity was observed except slightly decreased value at ebb tide at Wan Do. In general, although the pattern of the variations of calcium and magnesium contents were similar to that of the chlorinity, no definite relationships between these constituents and chlorinity were observed. Tidal variations of the dissolved oxygen content, nutrient salts and soluble iron were irregular.

• Journal of Plant Biology
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• v.15 no.4
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• pp.1-12
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• 1972

To study on the annual height growth of Pinus densiflora within natural pine stands in central Korea, twenty two pure closed Pinus densiflora stands were selected subjectively in the west-central region of Korea. In each stand twenty trees were chosen randomly. For each tree, abotu ten to fifteen measurements of internodal lengths were made from leader top to trunk base. A total of one hundred thirty four soil samples was collected. Each soil sample was bulked with three subsamples. The ranges of the growth measurements per stand, per tree and per observation were 14.9-35.4cm, 9.0cm-54.4cm and 2.4cm-69.0cm respectively. The total mean value was 23.5cm. The Student-Newman-Keul's tests for the multiple comparison among the mean values of the height growth per stand were very highly significant. The resutls of the analysis of variance of the height growth data for the selected fifteen stands among the twenty two stands indicate that sampling efficiency might be increased to 744% if measurement of the growth were made on fifteen trees per stand from twenty stands instead of twenty trees per stand from fifteen stands. The annual height growths of Pinus densiflora and Pinus koraiensis for the period from 1960 to 1968 were 21.74$\pm$5.29cm (10) and 20.56$\pm$5.59cm (10) respectively. The total means of easily-soluble phosphorus, total nitrogen, loss on ignition and pH for the soil samples were 2.8 ppm, 0.09%, 5.4% and 4.7 respectively. The ranges of those amounts were 18.7-1.7ppm, 0.17-0.05%, 11.6%-3.1%, 3.9-5.1 respectively. The relationship of the annual height growth of P. densiflora to soil was studied in terms of standard partial multiple regression. Among soil properties such as non-capillary pore space, capillary pore space, maximum field capacity, loss on ignition, soil reaction, total nitrogen and easily-soluble phosphoros investigated, the easily soluble phosphorus in one analysis and loss on ignition and soil reaction in the other analysis seem to have significant positive influence on the annual height growth.