• Title/Summary/Keyword: Soluble ion

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The Experiment Study on Chloride Binding of Cement Paste According to The Al/Ca+Si Ratio (Al/Ca+Si 비에 따른 시멘트 페이스트의 염화물 고정에 관한 실험적 연구)

  • Lee, Yun-Su;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.05a
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    • pp.51-52
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    • 2016
  • This paper researches the Chloride Binding of Cement Paste according to the Ca/Si and Ca/Al Ratio. The mechanisms of chloride ion binding are not completely known, although it is believed that Alumina contents in cementitious system have an important role. For changing cement paste composition, Ordinary Portland Cement(OPC) paste is substituted by Granulated Ground Blast Slag(GGBS). With increasing the ratio of GGBS substitution(Thus alumina contents is increasing), The chloride binding capacity has a tendency to increase of binding chloride ion capacity.

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Purification of Cytochrome c-551 from Photosynthetic Bacterium Rhodopseudomonas Gelatinosa ATCC 17013 (광합성 세균인 Rhodopseudomonas gelatinosa ATCC 17013에서 Cytochrome c-551의 정체)

  • 강대길;최원기
    • Korean Journal of Microbiology
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    • v.29 no.2
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    • pp.92-96
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    • 1991
  • The soluble cytochrome c-551 of photosynthetic bacterium, Rhodopseudomonas gelatinosa ATCC 17013 was purified through a sequene of four step chromatography including CM-cellulose ion-exchange chromatography, DEAE-Sephacel chromatography, Sephacryl s-200 gel permeation chromatography, and HPLC (SP-5PW). The molecular weight of the purified cytochrome c-551 was 14, 600 Da, and this protein shows the absorption peak at 551 nm, 522 nm, and 417 nm as the reduced form, and at 412 nm as the oxidized form. The cytochrome c-551 seems to be a substrate for the terminal oxidase in the electron transport chain.

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Absorption Rate of Oxygen in water soluble inks on the Printing Rollers. (인쇄용 로울러에서 수용성 잉크의 산소흡수 속도에 관한연구)

  • JongTaeYoun
    • Journal of the Korean Graphic Arts Communication Society
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    • v.7 no.1
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    • pp.16-30
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    • 1989
  • The anodixed aluminium film by sulfuric acid - method has many pores, the inner, called barrier layers, is active. They have strong absorption of dye. on be other, the absorption of dye is lost by Sealing, the surface is not dyed. We make IMAGE FORMATION on the film by the chemical behavior. This study made sure whether ion absorption is not in the barrier layer by IRRS and ESCA, considerated the mechanism of inage formation.

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Study on Size Distribution of Total Aerosol and Water-soluble tons During an Asian Dust Storm Event at Jeju Island (황사기간중 제주지역의 에어로졸과 수용성이온의 크기분포)

  • Park Seong-Hun;Song Chang-Byeong;Kim Min-Cheol;Gwon Sun-Park;Lee Gyu-Won
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.04a
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    • pp.159-160
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    • 2002
  • Soil dust particles transported from loess regions of the Asian continent, called Asian dust, highly influences the air quality of north-eastern Asia and the northern Pacific Ocean. The effects of these dust storms, on the chemical composition of atmospheric aerosol particles with different size, was investigated. Measurements of size distributions of total aerosol and major ion species were carried out on Jeju Island, Korea. (omitted)

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Influence of the C.T.I of phenolic resin (페놀수지의 C.T.I에 미치는 영향)

  • 이보호;박동화;정인성
    • Electrical & Electronic Materials
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    • v.1 no.1
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    • pp.70-77
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    • 1988
  • This paper describes the influence of the electrode materials, moisture content, electrolyte density, temperature, surface state, ion absorbent on the C.T.I of phenolic resin by the I.E,C, 112 method. C.T.I are increased for electrode materials with low hydrogen overvoltage and high soluble point. Increusing moisture content of samples increased by logarithmical on the droplet number to tracking breakdown. Increasing electrolyte temperature region above 70-80(.deg.C) decreased hydrogen over-voltage, following the density changes are decreased by C.T.I=1/aD$^{2}$-bD+C.

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Synthesis, and Structural and Thermal Characterizations of Tetrasulfonated Poly(arylene biphenylsulfone ether) Copolymer Ion Conducting Electrolytes

  • Yoo, Dong-Jin;Hyun, Seung-Hak;Kim, Ae-Rhan;Kumar, G. Gnana;Nahm, Kee-Suk
    • Bulletin of the Korean Chemical Society
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    • v.32 no.11
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    • pp.4041-4048
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    • 2011
  • High molecular weight tetrasulfonated poly(arylene biphenylsulfone ether) (TsPBPSEH) copolymers containing up to four pendant sulfonate groups per repeat unit were synthesized via aromatic nucleophilic displacement condensation from 4,4'-bis(4-chloro-3-sulfonatophenylsulfonyl)biphenyl-2,2'-disulfonate (SBCSBPD), 4,4'-dichlorodiphenylsulfone (DCDPS) and 4,4'-(hexafluoroisopropylidene)diphenol (6F-BPA). The synthesized copolymers were structurally characterized using $^1H$ NMR and FT-IR techniques. They were analytically pure, amorphous and were readily soluble in a wide range of organic solvents. Electrolyte membranes were successfully cast using the synthesized polymers with various sulfonation levels and N-methyl-2-pyrrolidinone. This new class of polymer membranes exhibited elevated thermal and physical stabilities and reduced swelling at high temperatures. An increase of acidic functional groups in the copolymer yielded high ion exchange capacity and moderate ionic conductivity values even at higher temperatures, which makes them potential ion conducting candidates.

A Study on Chemical Characterization of Precipitation in the Central Part of Korea from 1994 to 1997 (1994~1997년 중부지방에 내린 강수의 화학적 특성에 관한 연구)

  • 조하만;최재천
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.6
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    • pp.589-598
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    • 1998
  • This study was conducted to investigate the chemical characteristics of Precipitation at Seoul, Yangpyong, Hongchon and Inje in the central part of Korean peninsula during the period from March 1994 to November 1997. The precipitation samples were collected by automatic wet-only sampler. The samples were analyzed for major anions (SO42-, NO3-, Cl-, F-) and cations(NH4+, Ca2+, Mg+, Na+, K+), in addition to acidity and electrical conductivity. The analytical instrument for water soluble ionic components was ion chromatography. The volume - weighted mean PH were 4.73, 4.87, 4.89 and 4.81 at Seoul, Yangpyong, Hongchon and Inje, respectively. The sums of cation concentrations was slightly greater than the sums of anion concentrations. Also, the highest ion component was SO42- in anions and NH4+ in cations. The mean equivalent ratios of SO42- to NO3- were found by 2.96, 2.71, 2.43 and 2.25 at Seoul, Yangpyong, Hongchon and Inje, respectively. The factor analysis was conducted in order to make the large and diverse data set as manageable levels and to qualitatively examine the relationship between the variables. It showed that major sources of pollutants in precipitation were from the anthropogenic in Seoul, the natural in Hongchon, and the anthropogenic and natural in Yangpyong and Inje.

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Study on Chemical Characterization of $PM^{10}$ Observed in Korean Peninsula, 1998 ~ 2001

  • Bang, So-Young;Oh, S.N.;Choi, J.C.;Choi, B.C
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.11a
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    • pp.61-64
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    • 2003
  • This study was conducted to investigate the chemical characteristics of $PM^{10}$ at Anmyeon-do during the periods from January 1998 to December 2001. The $PM^{10}$ samples ($PM^{10}$) were collected by High Volume Air sampler (HVAS). The measured items were mass concentration of $PM^{10}$ with the major ions ($Cl^{-}$, ${SO_{4}}^{2-}$, ${NO_3}^{-}$, ${Mg}^{2+}$, ${Ca}^{2+}$, ${K}^{+}$etc.) and metallic elements (AI, Fe, Mn, Cr, Zn, Pb etc.). The chemical analysis of major ion components were made by Ion Chromatography (DX-500) and that of metallic elements were made by Inductively Coupled Plasma Spectrometer (ICP-AES, ICP-Mass). The average mass concentration of $PM^{10}$ increased substantially during the heavy dust periods (Asian Dust cases). For water-soluble ions, concentrations of ${Ca}^{2+}$, ${SO_{4}}^{2-}$ and ${NO_3}^{-}$ were remarkably enhanced. Concentrations and mass fraction of crustal elements such as Na, Mg, Ca, Fe, Mn were highly elevated, but those of pollution-derived heavy metals were appreciably decreased. The factor analysis was conducted in order to make the large and diverse data set as manageable levels and to qualitatively examine the relationship between the variables.

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Development of a Functional Mortar for Restraining Surface Algal Growth

  • Park, Soon-young;Kim, Jinhyun;Kang, Hojeong
    • Ecology and Resilient Infrastructure
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    • v.5 no.2
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    • pp.82-87
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    • 2018
  • Proliferation of algae on the surface of concrete or mortar in aquatic habitat has a negative impact on maintenance of concrete-based structures. Growth of algae may decrease stability of structure by bio-deterioration. In this study, we developed a functional mortar for restraining bio-deterioration by using $Cu^{2+}$ ion. The mortar contains soluble glass beads made of $Cu^{2+}$ ion, which can dissolve into water slowly. Mortars prepared with different ratio of glass beads (0, 2, 5, 10, and 15%) were placed in a culture medium with algae and incubated over a month period. Water chemistry, chlorophyll-a, and extracellular enzyme activities were measured. The incubation was conducted in both freshwater and seawater conditions, to assess applicability to both aquatic conditions. Overall, mortar with Cu glass exhibited lower chlorophyll-a content, suggesting that the functional mortar reduced algal growth. DOC concentration increased because debris of dead algae increased. Cu glass also decreased phosphatase activity, which is involved in the regeneration of inorganic P from organic moieties. Since, P is often a limiting nutrient for algal production, algal growth may be inhibited. Activities of ${\beta}$-glucosidase and N-acetylglucosaminidase were not significantly affected because carbon and nitrogen mineralization may not be influenced by the Cu glass beads. Our study suggests that functional mortar with Cu glass beads may reduce the growth of algae on the surface, while it has little environmental impact.