• 제목/요약/키워드: Soluble Salt

검색결과 410건 처리시간 0.028초

Chelation of Calcium Ions by Poly(${\gamma}$-Glutamic Acid) from Bacillus subtilis (Chungkookjang)

  • Tsujimoto, Takashi;Kimura, Junya;Takeuchi, Yasushi;Uyama, Hiroshi;Park, Chung;Sung, Moon-Hee
    • Journal of Microbiology and Biotechnology
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    • 제20권10호
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    • pp.1436-1439
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    • 2010
  • Many studies have clarified that poly(${\gamma}$-glutamic acid) (PGA) increases the solubility of $Ca^{2+}$, suggesting that PGA enhances calcium absorption in the small intestine. However, there has been no report on the specific interaction between PGA and $Ca^{2+}$ in water. We studied the aqueous solution properties of PGA calcium salt (PGA-Ca complex). The chelating ability and binding strength of PGA for $Ca^{2+}$ were evaluated. The PGA-Ca complex was soluble in water, in contrast to the insolubility of poly(acrylic acid) (PAA) calcium salt, and the chelating ability of PGA for $Ca^{2+}$ was almost the same as that of PAA. The globular conformation of the PGA-Ca complex in water was estimated by SEC and viscosity measurements. The chelation ability of PGA for $Ca^{2+}$ was examined by $^1H$ NMR. The present study showing the characteristics of the PGA-Ca complex will provide useful information about the calcium absorption by PGA in vivo.

폐 산화철촉매로부터 마그네타이트의 자력선별에 관한 연구 (A Study on the Magnetic Separation of Magnetite from Spent Iron-oxide Catalyst)

  • 현종영;이효숙;이우철;채영배
    • 자원리싸이클링
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    • 제11권3호
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    • pp.31-36
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    • 2002
  • 스틸렌 모노머 합성반응에서 발생하는 폐산화철 촉매로부터 마그네타이트의 품위향상을 위하여 5oo gauss와 1800 gauss에서 습식자력선별을 행하였다. 폐산화철 촉매는 주로 마그네타이트($Fe_3$$O_4$)와 세리아($CeO_2$) 및 가용성염($K_2$O, $MoO_3$)으로 이루어졌다. 습식자력선별에 의한 폐촉매중 자력산물의 회수율은 99% 이상이었으며, 마그네타이트 품위는 자력선별 전 70%에서 80%로 향상되었다. 이는 자력선별의 효과보다는 수세효과에 의한 가용성분인 K, Mo 염이 제거되었기 때문이다 자력산물 중 불순물은 주로 미세한 세리아이며 마그네타이트와 단체분리가 되지 않았다.

PSE 돈육으로 부터 추출한 근원섬유단백질의 석시닐화와 그 기능적 특성 (Succinylation of Myofibrillar Protein of PSE(pale, soft, exudative) Porcine Muscle and it's Functional Characteristics)

  • 성삼경
    • 한국식품과학회지
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    • 제16권3호
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    • pp.353-357
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    • 1984
  • PSE돈육에서 근원섬유를 추출하고, 무수석시닐산으로 수식하여 석시닐화하고, 그 조제물의 화학적, 기능적 특성을 검토하였다. 석시닐화근원섬유는 석시닐화율에 상관없이 효소적 기능이 완전히 상실하였고, 무처리근원섬유의 등전점이 pH 5.0인데 비하여 석시닐화근원섬유는 pH 3.0정도에서 침전하였다. 염농도에 따른 용해도는 무처리근원섬유가 염농도의존성이 있음에 비하여 석시닐화근원섬유는 염농도에 관계없이 용해도의 변화가 거의 없었다. 석시닐화근원섬유의 기능적 특성중 열응고성은 현저히 감소하였고, 흡수성은 개선되지 않았으며, 유화용량은 다소 향상되었다.

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Dissolution behavior of SrO into molten LiCl for heat reduction in used nuclear fuel

  • Kang, Dokyu;Amphlett, James T.M.;Choi, Eun-Young;Bae, Sang-Eun;Choi, Sungyeol
    • Nuclear Engineering and Technology
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    • 제53권5호
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    • pp.1534-1539
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    • 2021
  • This study reports on the dissolution behavior of SrO in LiCl at varying SrO concentrations from low concentrations to excess. The amount of SrO dissolved in the molten salt and the species present upon cooling were determined. The thermal behavior of LiCl containing various concentrations of SrO was investigated. The experimental results were compared with results from the simulated results using the HSC Chemistry software package. Although the reaction of SrO with LiCl in the standard state at 650 ℃ has a slightly positive Gibbs free energy, SrO was found to be highly soluble in LiCl. Experimentally determined SrO concentrations were found to be considerably higher than those present in used nuclear fuel (<2 g/kg). As Sr-90 is one of the most important heat-generating nuclides in used nuclear fuel, this finding will be impactful in the development of fast, simple, and proliferation-resistant heat reduction processes for used nuclear fuel without the need for separating nuclear materials. Heat reduction is important as it decreases both the volume necessary for final disposal and the worker handling risk.

Positive Regulator, a Rice C3H2C3-type RING Finger Protein H2-3(OsRFPH2-3), in Response to Salt Stress

  • Min Seok Choi;Cheol Seong Jang
    • 한국작물학회:학술대회논문집
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    • 한국작물학회 2023년도 춘계학술대회
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    • pp.156-156
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    • 2023
  • Salinity is a major abiotic stress that limits rice productivity in many regions of the world. In order to develop salt stress tolerant rice plants, genetic engineering is a promising approach. We characterized the molecular function of rice C3H2C3 as a really interesting new gene (RING). Oryza sativa RING finger protein H2-3 (OsRFPH2-3) was highly expressed in 100 mM NaCl. To identify the localization of OsRFPH2-3, we fused vectors that include C-terminal GFP protein (35S;;OsRFPH2-3-GFP). OsRFPH2-3 was expressed in the nucleus in rice protoplasts. An in vitro ubiquitin assay demonstrated that OsRFPH2-3 possessed E3-ubiquitin ligase activity. However, the mutated OsRFPH2-3 were not possessed any E3-ubiquitin ligase activity. Under salinity conditions, OsRFPH2-3-overexpressing plants exhibited higher chlorophyll, proline, SOD, POD, CAT, and soluble sugar contents and lower H2O2 accumulation than wild-type plants, supporting transgenic plants with enhanced salinity tolerance phenotypes. OsRFPH2-3-overexpressing plants exhibited low Na+ accumulation and Na+/K+ ratios in their roots. Theses results suggest that overexpression of OsRFPH2-3 can make plant insensitivity about salinity conditions.

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사차 암모늄 염을 함유하는 농축된 콜로이드 액상 에이프런의 연속상에서의 안정성 (Stability of concentrated Colloidal Liquid Aphrons containing a quaternary ammonium salt in the continuous phase)

  • 함형철;홍원희;이철호
    • 청정기술
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    • 제7권4호
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    • pp.291-297
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    • 2001
  • 본 연구는 중금속 추출 공정에 쓰이는 사차 암모늄 염인 Aliquat 336을 포함하는 콜로이드 액상 에이프런 (colloidal liquid aphrons, CLAs)을 지용성 계면활성제와 수용성 계면활성제를 사용하여 제조하였고 연속상에서 농축된 CLAs의 안정성을 표면으로 떠오르는 유기 용매의 양을 시간에 따라 측정하여 평가하였다. 다양한 조건에서 CLAs의 안정성을 비교하기 위해서 반감기가 도입되었다. 전해질의 첨가나 pH의 변화와 같은 연속상의 상태 변화는 CLAs의 파괴(break-up) 속도에 상당히 영향을 미치는데 이 파괴 속도가 급격히 변화하는 임계 응집 농도가 존재한다. pH의 변화에 따른 임계 응집 농도를 측정하였고 이온의 세기, 수용성 계면활성제 Sodium Dodecyl Sulfonate (SDBS)의 농도에 대한 CLAs의 안정성에 대한 영향을 고찰하였다.

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해안지역에서 입자상물질의 특성에 관한 연구 (A Study on the Characteristics of Particulate Matter in the Coastal Regions)

  • 최민규;조기철;강충민;여현구;김희강
    • 한국환경보건학회지
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    • 제24권3호
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    • pp.114-123
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    • 1998
  • Particulate matters(less than 10 $\mu$m, PM10) at Kanghwa and Yangyang, which are located in the western and the eastern coastal regions in Korea, were measured in using low volume air sampler from December 1995 to November 1996, and their characteristics were investigated from the view point of background level.(and in order to characterize the particulate matters.) The particulate matters were analyzed for major water soluble ionic components(SO$_{4}^{2-}$, NO$_{3}^{-}$, Cl$^{-}$, Na$^{+}$, NH$_{4}^{+}$, K$^{+}$, Mg$^{2+}$ and Ca$^{2+}$) by ion chromatography. Mass concentrations of particulate matters were $48.77 \pm 22.45 \mug/m^{3}$ at Kanghwa and $54.04 \pm 32.98 \mug/m^{3}$ at Yangyang and SO$_{4}^{2-}$, NO$_{3}^{-}$ and NH$_{4}^{+}$ contributed largely to water soluble ionic components. nss(non sea salt)-SO$_{4}^{2-}$, contributed more than 95 percentage to SO$_{4}^{2-}$ and nss-K$^{+}$ and nss-Ca$^{2+}$ also contributed high percentages to K$^{+}$ and Ca$^{2+}$. It was supposed that most SO$_{4}^{2-}$, was originated from anthropogenic sources, and K$^{+}$ and Ca$^{+}$ were mainty originated from soil. The results of factor analysis suggested possibility of interpreting the correlation between air pollutants and regional characteristics.

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동결온도가 진공포장 동결육의 품질에 미치는 영향 (Effects of Freezing Temperature on Quality of Vacuum Packaging Freezed Beef)

  • 정인철;김도완;문귀임;강세주;김기영;문윤희
    • 한국식품영양학회지
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    • 제11권4호
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    • pp.409-415
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    • 1998
  • This study was carried out to investigate the effects of freezing temperature on quality of vacuum packaging freezed beef. In case of thaw drip loss, the freezing of -3$^{\circ}C$ and -20$^{\circ}C$ were 5.23% and 5.17% to 60 days respectively, were increased significantly during freezing. The cooking loss of water bath and pan were increased significantly during freezing than the beginning of freezing, but were no different between -3$^{\circ}C$ and -20$^{\circ}C$. The salt soluble protein extractability was decreased during freezing, the -20$^{\circ}C$ freezing was higher than -3$^{\circ}C$freezing. The water soluble protein extractability was increased during freezing higher than during freezing. The myoglobin denatured percentage of the -3$^{\circ}C$ freezing was higher than -20$^{\circ}C$ freezing, the 15 days storage of -3$^{\circ}C$ freezing was highest to 96%. The shear force value was not change during freezing, the myofibrillar fragmentation index during freezing was higher than the beginning of freezing, but was not change during freezing. The pH was decreased to freezing 45 days, after that increased.

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크롬환원제와 인산염으로 처리된 6가 크롬 오염토양의 장기용출 특성 (Long-term teaching Characteristics of Hexavalent Chromium Contaminated Soils Treated with Phosphate and Chromium Reducing Agent)

  • 이의상
    • 한국산학기술학회논문지
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    • 제7권3호
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    • pp.448-452
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    • 2006
  • 본 연구는 크롬환원제와 액상인산염으로 고정화 처리된 6가 크롬 오염토양이 일반 자연조건에서 얼마나 안정한 상태를 유지하는지 알아보고자하는 장기용출실험을 실시하였다. 크롬환원제와 액상인산염으로 고정화 처리한 토양의 110일간의 장기용출 실험결과, 6가 크롬의 경우 고정화제와 반응하여 불용성 크롬인산염 화합물을 형성한 반응 토양에서 미반응토양과 대조적으로 중금속이 용출되지 않아 수계에 영향을 미치지 않는 것으로 나타났다. 또한 고정화제로 투입된 잔류인이 0.1 mg/L 이하로 측정되어 지하수로의 2차오염을 유발하지 않는 것으로 보여진다. 이와 같은 실험결과를 미루어볼 때 이 고정화기술의 장기적인 안정성을 기대해도 좋은 것으로 사료된다.

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Functional and Film-forming Properties of Fractionated Barley Proteins

  • Cho, Seung-Yong;Rhee, Chul
    • Food Science and Biotechnology
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    • 제18권4호
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    • pp.889-894
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    • 2009
  • Barley proteins are expected to have unique functional properties due to their high content of alcohol soluble protein, hordein. Since the barley proteins obtained by conventional isoelectric precipitation method cannot represent hordein fraction, barley proteins were fractionated to albumin, globulin, glutelin, and hordein with respect to extraction solvents. Functional properties and film-forming properties of solubility-fractionated barley proteins were investigated to explore their potential for human food ingredient and industrial usage. The 100 g of total barley protein comprised 5 g albumin, 23 g globulin, 45 g glutelin, and 27 g hordein. Water-binding capacities of barley protein isolates ranged from 140-183 mL water/100 g solid. Hordein showed the highest oil absorption capacity (136 mL oil/100 g), and glutelin showed the highest gelation property among the fractionated proteins. In general, the barley protein fractions formed brittle and weak films as indicated by low tensile strength (TS) and percent elongation at break (E) values. The salt-soluble globulin fraction produced film with the lowest TS value. Although films made from glutelin and hordein were dark-colored and had lower E values, they could be used as excellent barriers against water transmission.