• Title/Summary/Keyword: Solidification of Alloy

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Solidification Process of an Al-Cu Alloy in a Vertical Annular Mold and Effects of Cooling Rate on Macrosegregation (수직환상주형내 Al-Cu합금의 응고과정 및 냉각속도의 조대편석에 대한 영향)

  • 유호선
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.7
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    • pp.1818-1832
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    • 1994
  • Transport process during solidification of an AI-CU alloy in a vertical annular mold of which inner wall is cooled is numerically simulated. A model which can take account of local density dependence on the solute concentration is established and incorperated in the analysis. Results show that thermally and solutally induced convections are developed in sequence, so that there is little interaction between them. Thermal convection effectively removes the initial superheat from the melt and vanishes as solidification proceeds from the cooling wall. On the other hand, solutal convection which is developed later over the meshy and the pure liquid regions leads to large-scale redistribution of the consituents. The degree of the initial superheating hardly affects overall solidification behavior except the early stage of the process, when the cooling rate is kept constant. Macrosegregation is reduced remarkably with increasing cooling rate, because not only the liquidus interface advances so quickly that time available for the solute transport is not enough, but also the interdendritic flow is strongly damped by rapid crystal growth within the mushy region.

Change of Secondary Dendrite Arm Spacing of Hypoeutectic Al-Si Alloys according to Si Content and Cooling Rate (아공정 Al-Si 합금에서 Si 함량과 냉각속도에 따른 제이차수지상간격의 변화)

  • Park, Kyeong-Seob;Kim, Hee-Soo
    • Journal of Korea Foundry Society
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    • v.37 no.4
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    • pp.108-114
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    • 2017
  • In this study, we investigated the effect of the Si content on the secondary dendrite arm spacing (SDAS) of hypoeutectic Al-Si binary alloys in the range of 4~10 wt% Si. Cooling curves were measured during the solidification of the alloy cast in a step-wise mold. We compared two kinds of solidification time: the first is the total solidification time for both dendritic and eutectic growth, and the second is the solidification time for only dendritic growth. The proportional constant in the relationship between SDAS and cooling rate was estimated, as this constant represents the stability of the cast microstructure. The proportional constant decreased with the Si contents from 4 wt% to 8 wt%, and it remains relatively uniform with up to 10 wt% of Si.

The Effect of Misch Metal on the Microstructure of Rapidly solidified Ag-Sn-In Alloys (급속응고한 Ag-Sn-In 합금의 미세조직에 미치는 Misch Metal의 영향)

  • Chang, Dae-Jung;Nam, Tae-Woon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.6
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    • pp.561-565
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    • 2007
  • Because of a good wear resistance and a stable contact resistance, Ag-CdO is widely used as electrical contact material. But, the Cd-oxide mainly exists as a coarse particle and adversely affected to environment. As a reason, $Ag-SnO_2$ alloy has been developed. The Sn-oxide maintains stable and fine particle even at high temperature. In order to investigate the effect of Misch metal (Mm) additional that affects the formation of the oxide and the formation of fine matrix Ag, we studied the microstructures and properties of Ag-Sn-In(-Mm) material fabricated by rapid solidification process. The experimental procedure were melting using high frequency induction, melt spinning, and internal oxidation. The Mm addition makes Ag matrix more fine than no Mm addition. The reason is that the addition of Misch metal decreased a latent heat of fusion of alloy, as a result the rapid solidification effect of alloy is increased. The maximum hardness shows at 0.3 wt%Mm. after that the hardness is decreased until 0.4 wt% Mm, but still larger than no Mm addition alloy. At 0.5 wt% Mm alloy, the precipitation of Misch metal causes a decrease of hardness than no Mm addition alloy.

Mechanical Characteristics and Microstructures of Hypereutectic Al-17Si-5Fe Extruded Alloys Prepared by Rapid Solidification Process (급속응고법으로 제조한 과공정 Al-17Si-5Fe 합금 압출재의 미세조직 및 기계적 특성)

  • KIM, Tae-Jun;LEE, Se-dong;BECK, Ah-Ruem;KIM, Duck-Hyun;LIM, Su-Gun
    • Journal of Korea Foundry Society
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    • v.39 no.2
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    • pp.26-31
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    • 2019
  • In this study, the mechanical characteristics and microstructure of hypereutectic Al-17Si-5Fe extruded alloys prepared by a rapid solidification process (RSP) were investigated. The hypereutectic Al alloy was fabricated by means of RSP and permanent casting. For RSP, the Al alloy melted at $920^{\circ}C$, cooling the specimens at a rate of $10^6^{\circ}C/s$ when the RSP was used, thus allowing the refining of primary Si particles more than when using permanent casting, at a rate of about 91%. We tested an extrusion RSP billet and a permanent-cast billet. Before the hot-extrusion process, heating to $450^{\circ}C$ took place for one hour. The samples were then hotextruded with a condition of extrusion ratio of 27 and a ram speed of 0.5 mm/s. Microstructural analyses of the extruded RSP method and the permanent casting method were carried out with OM and SEM-EDS mapping. The mechanical properties in both cases were evaluated by Vickers micro-hardness, wear resistance and tensile tests. It was found that when hypereutectic Al-17Si-5Fe alloys were fabricated by a rapid solidification method, it becomes possible to refine Si and intermetallic compounds. During the preparation of the hypereutectic Al-17Si-5Fe alloy by the rapid solidification method, the pressure of the melting crucible was low, and at faster drum speeds, smaller grain alloy flakes could be produced. Hot extrusion of the hypereutectic Al-17Si-5Fe alloy during the rapid solidification method required higher pressure levels than hot extrusion of the permanent mold-casted alloy. However, it was possible to produce an extruded material with a better surface than that of the hot extruded material processed by permanent mold casting.

Real-time Observation and Analysis of Solidification Sequence of Fe-Rich Al-Si-Cu Casting Alloy by Synchrotron X-ray Radiography (가속 방사광을 활용한 Fe함유 Al-Si-Cu 주조용 합금의 응고과정 실시간 관찰 및 분석)

  • Kim, Bong-Hwan;Lee, Sang-Hwan;Yasuda, Hideyuki;Lee, Sang-Mok
    • Journal of Korea Foundry Society
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    • v.30 no.3
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    • pp.100-110
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    • 2010
  • The solidification sequence and formation of intermetallic phase of Fe-rich Al-Si-Cu alloy were investigated by using real-time imaging of synchrotron X-ray radiation. Effects of cooling rate during uni-directional solidification on the resultant solidification behavior was also studied in a specially constructed vacuum chamber in the SPring-8 facility. The series of radiographic images were complementarily analyzed with conventional analysis of OM and SEM/EDX for phase identification. Detailed solidification sequence and formation mechanisms of various phases were discussed based on real-time image analysis. The growth rates of $\alpha$-AlFeMnSi and ${\beta}-Al_5FeSi$ were measured in order to understand the growth behavior of each phase. It is suggested that real-time imaging technique can be a powerful tool for the precise understanding of solidification behavior of various industrial materials.

Effect of Electromagnetic Stirring on Microstructure Evolution in Solidification of a Near-Eutectic Al-Si Alloy

  • Guo, Qing-Tao;Sim, Jae-Gi;Jang, Young-Soo;Choi, Byoung-Hee;Lee, Moon-Hyoung;Hong, Chun-Pyo
    • Journal of Korea Foundry Society
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    • v.28 no.5
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    • pp.226-230
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    • 2008
  • 본 논문에서는 공정조성 부근의 Al-Si 합금의 미세구조에 미치는 전자기교반(EMS)의 영향에 대하여 연구하였다. 초정 a 상의 형상에 미치는 전자기교반의 세기의 영향을 조사하기 위하여 각각 교반장치에 60, 80,및 120V의 전압을 가하여 미세조직을 관찰하였다. 60V 이하의 전압이 인가되었을 때 전자기교반의 효과가 나타나지 않은 반면에, 80V 이상의 전압으로 5초 이상 인가되었을 때 구상화된 초정 a 상을 얻을 수 있었다. 인가된 전압이 120V일 때 초정 a 상은 보다 균일한 분포를 가지며 구상화 되었다. 전자기교반의 세기와 함께 교반시간의 영향을 확인하기 위하여 교반시간을 증가시키면서 미세조직을 관찰하였다. 또한 초정 a 상의 형상에 미치는 주조변수의 영향에 대해서도 실험하였다.

An analysis on the solidification process of alloy casting with a contact resistance (접촉 열저항을 고려한 합금주조의 응고과정 해석)

  • Kim, W.S.;Lee, K.S.;Im, I.T.;Kim, K.S.
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.21 no.1
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    • pp.57-67
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    • 1997
  • The solidification process of Al 4.5%Cu alloy is numerically studied in the presence of contact resistance between mold and cast. Natural convection is considered in the liquid and mushy regions. The porosity approach is applied to the mushy zone modeling and linear variation of the solid fraction on the temperature is assumed. Results show that the mushy region is wider in the case with a contact resistance compared to the perfect contact condition. The temperature of the cast with a temporal variation in the contact heat transfer coefficient changes very rapidly in the early stage of the casting process compared to that with constant contact heat transfer coefficient.

The structures and mechanical properties of unidirectionally solidified Al-Fe-Ni alloy (일방향응고시킨 Al-Fe-Ni 합금의 조직과 기계적 성질)

  • 김여원;신민교
    • Journal of Advanced Marine Engineering and Technology
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    • v.7 no.1
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    • pp.79-90
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    • 1983
  • The examination for the changes of structures and mechanical properties in directionally solidified Al-Fe-Ni alloys containing the small amount of Fe and Ni was carried out by the varying the composition and solidification rate R of alloy, provided that the temperature gradient was 80 .deg.C/cm. The result were obtained as follows. A) In proportion to the increase of the solidification rate (R), the crystallized phase of this alloy was changed from the Ribbon-type structure to the Rod-type structure. B) The strength was rapidly increased in the changing process of composite shape from the Ribbon-type to the Rod-type with the solidification rate (R) increasing. C) The fiber stress (${\sigma}^f$) and Young's modulus ($E_f$) calculated for the Rod-type structure were 220 kg/$mm^2$ and 11, 800 kg/$mm^2$ respectively, which were in good accord with the rule of Mixtures.

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Strengthening of Rapidly Solidified and Extruded Mg Alloy Powders (압출공정을 이용한 급속응고 Mg 합금분말의 고강도화)

  • Kim, Taek-Soo
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.10a
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    • pp.35-37
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    • 2008
  • The light Mg alloys bearing the remarkably high strength, corrosion resistance and elevated temperature stability stand on the center of interest. The accomplishment so far is, however, only by alloy modification without any consideration on the rapid solidification effect. This work is to report not only the effect of rapid solidification of $MgZn_{4.3}Y_{0.7}$ alloy powders, but the extrusion behavior on the materials properties. The average grain size of the atomized powders was about $3-4{\mu}m$. The extrusion was carried out with the area reduction ratio of 10:1 to 15:1. As the ratio increased, homogeneous microstructure was obtained, and the mechanical properties such as tensile strength and elongation were simultaneously increased.

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Mechanical Properties of Rapidly Solidified Mg-Zn Base Alloys (급냉응고된 Mg-Zn계 합금의 기계적 성질)

  • Kim, Yeon-Wook
    • Journal of Korea Foundry Society
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    • v.18 no.5
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    • pp.462-466
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    • 1998
  • Interest in rapid solidification of magnesium alloys stems from the fact that conventional ingot metallurgy alloys exhibit poor strength, ductility, and corrosion resistance. Such properties can be improved by microstructural refinement via rapid solidification processing. Mg-5wt%Zn alloys have been produced as continuous strips by melt overflow technique and the strips were consolidated by hot extrusion. The yield stress, tensile strengh and ductility obtained in asextruded Mg-5wt%Zn alloy were ${\sigma}_{0.2}=152\;MPa$, ${\sigma}_{T.S{\cdot}}=263\;MPa$ and ${\varepsilon}=21.8%$. In order to evaluate the influence of additional elements on mechanical properties, Th and Zr were added in rapidly solidified Mg-5wt%Zn alloy. An 130% increase in yield stress of as-extruded Mg-5wt%Zn-3wt%Th-1wt%Zr alloy was attributed to grain refinement by rapid solidification and elemental addition.

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