• 한국주조공학회지
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• 제39권2호
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• pp.26-31
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• 2019

In this study, the mechanical characteristics and microstructure of hypereutectic Al-17Si-5Fe extruded alloys prepared by a rapid solidification process (RSP) were investigated. The hypereutectic Al alloy was fabricated by means of RSP and permanent casting. For RSP, the Al alloy melted at $920^{\circ}C$, cooling the specimens at a rate of $10^6^{\circ}C/s$ when the RSP was used, thus allowing the refining of primary Si particles more than when using permanent casting, at a rate of about 91%. We tested an extrusion RSP billet and a permanent-cast billet. Before the hot-extrusion process, heating to $450^{\circ}C$ took place for one hour. The samples were then hotextruded with a condition of extrusion ratio of 27 and a ram speed of 0.5 mm/s. Microstructural analyses of the extruded RSP method and the permanent casting method were carried out with OM and SEM-EDS mapping. The mechanical properties in both cases were evaluated by Vickers micro-hardness, wear resistance and tensile tests. It was found that when hypereutectic Al-17Si-5Fe alloys were fabricated by a rapid solidification method, it becomes possible to refine Si and intermetallic compounds. During the preparation of the hypereutectic Al-17Si-5Fe alloy by the rapid solidification method, the pressure of the melting crucible was low, and at faster drum speeds, smaller grain alloy flakes could be produced. Hot extrusion of the hypereutectic Al-17Si-5Fe alloy during the rapid solidification method required higher pressure levels than hot extrusion of the permanent mold-casted alloy. However, it was possible to produce an extruded material with a better surface than that of the hot extruded material processed by permanent mold casting.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2003년도 추계학술대회논문집
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• pp.60-63
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• 2003

Semi-solid forming is the process of stirring alloy during solidification, making the mixture of liquid and solid, solidifying it, reheating it to the solid-liquid coexistent temperature, and then injecting this semi solid slurry into dies. In the semi-solid die casting process, it is very important to find out the correlation of injection condition, microstructure and mechanical properties. Especially, an improper injection condition is the main cause of liquid segregation and non-homogeneous mechanical properties due to the difference of solid fraction according to the position of the products. To ensure the database requisite to the semi-solid die casting product, it is essential to acquire the mechanical properties considering liquid segregation to the injection condition. In this study, the effect of injection condition on liquid segregation, formability, microstructure and mechanical properties in a thin product was investigated.

• 한국주조공학회지
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• 제32권6호
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• pp.276-283
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• 2012

This study presents the results on the changes of crucible thermal conductivity and inflow of Ar, and constructed the mathematical model about heat transfer into furnace. As process variables, simulation model was designated thermal conductivity of crucible to $0.5W{\cdot}m^{-1}{\cdot}K^{-1}$, $1W{\cdot}m^{-1}{\cdot}K^{-1}$, $2W{\cdot}m^{-1}{\cdot}K^{-1}$, $4W{\cdot}m^{-1}{\cdot}K^{-1}$, and inflow rate of Ar to 15 L/min, 30 L/min, 60 L/min. Initial condition and boundary condition were set respectively in two terms of process. Each initial conditions were set up by the preceding simulation of heat and fluid flow. The primary goal is the application of unidirectional growth of Si ingot using the result. In the result of the change of heat conductivity of crucible, the higher thermal conductivity of crucible shows the shorter solidification time and the bigger temperature difference. And the flow patterns are changed with the inflow rate of Ar. Finally, we found that the lower crucible's thermal conductivity, the better crucible is at polycrystalline Si ingot growth. But in case of Ar inflow, it is hard to say about good condition. This data will be evaluated as useful reference used in allied study or process variable control of production facilities.

• 한국산학기술학회논문지
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• 제21권6호
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• pp.482-489
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• 2020

본 연구의 목적은 소비자 및 현장의 니즈에 부합하면서 다이캐스팅으로 생산할 수 있는 커플링 부품을 개발하고자 하였으며, 유동 및 응고해석을 기반으로 다이캐스팅 금형 설계, 제작, 및 사출조건 최적화 도출을 실시하였고 사출된 제품의 측정 및 평가를 수행하였다. 유동해석을 통하여 캐비티 내부가 100 % 충진되기 위한 적정한 사출조건은 용탕의 온도 670 ℃, 사출속도 1.164 m/s, 충진압력 6.324~18.77 MPa로 분석되었다. 또한, 응고율이 69.47 %일 때 4개의 캐비티 모두에서 100 %에 근접하는 응고가 발생됨을 알 수 있었으며, 이를 기초로 시사출 조건설정 등에 응용하였으며 그 결과 사이클 타임은 약 6.5초로 도출되었다. 다이캐스팅으로 시사출된 제품의 표면 및 내부의 품질 검사를 수행한 결과 성형불량 및 기공 등의 결함은 전혀 발견되지 않았으며, 주요 개소의 치수를 측정한 결과 모든 항목에서 허용하는 공차 이내의 값을 보였다. 또한, 게이트로부터 약 45 mm 이격된 곳의 평균 경도값은 97.7(Hv)로 나타나는 등 전체적으로 양호한 치수 및 품질의 부품을 제작할 수 있었다.

• 한국주조공학회지
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• 제41권4호
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• pp.349-356
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• 2021

우수한 기계적 성질과 가격경쟁력을 갖는 구상흑연주철 합금 개발을 위해 Cu와 Sn을 소량 첨가한 고 Mn 구상흑연주철의 응고 후 냉각조건에 따른 미세조직과 기계적 특성을 분석하였다. 첨가원소인 Cu와 Sn의 경우 펄라이트 형성 촉진을 통한 인장특성 향상을 위해 선택하였다. 또한 물성에 미치는 냉각속도의 영향을 확인하기 위해, Mg 처리된 다양한 조성의 합금을 블록시편에 주입한 후 주형 내 냉각과 800℃에서 주형 해체 후 공랭의 두 가지 냉각 조건을 비교분석하였다. 주형 내 냉각 시편의 경우, 펄라이트 분율은 27-44%, 인장강도와 연신율은 각각 513-568N/mm²와 10.4-14.3%로 나타났다. 반면, 이른 형해체 공랭 시편의 경우에는 펄라이트 분율은 77~85%, 인장강도와 연신율은 각각 728~758N/mm²와 3.2~6.0% 이었다. 결론적으로, 소량의 Cu 및 Sn 함유 Mn 구상흑연주철의 공랭 시 괄목할만한 인장강도와 연신율의 증가를 확인할 수 있었다.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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• pp.58-59
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• 2006

In Spray Forming, specific enthalpy is a key parameter in the deposition process as it influences the thermal condition of the impinging droplets as well as that of the deposit surface. An empirical model for the distribution of specific enthalpy in the spray cone was developed as an easy to handle alternative to numerical models with which the descriptive partial differential equations are solved numerically. The model results were compared with the experimental data to validate its applicability.

• 한국지반환경공학회 논문집
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• 제3권4호
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• pp.37-49
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• 2002

본 연구에서는 고강도 고내구성 및 환경에 대한 안정성이 높은 주입재료를 주입재 형태별로 즉 현탁액형, 용액형 주입재에 배합설계를 실시하여 주입압, 지반조건에 따른 주입효과와 환경적 유해성을 분석 검토하고자 한다. 주입재 특성 및 주입효과에 대한 연구결과, 현탁액형 주입재에서는 초미립자시멘트가 보통시멘트에 비하여 상당히 높은 침투성 및 고결율을 나타냄을 알 수 있었고 용액형 주입재에 사용된 인산과 탄산수소나트륨의 경우 초미립자시멘트와 유사한 경향을 나타내었다. 주입된 고결체의 압축강도 시험결과, 현탁액형 주입재의 초미립자시멘트가 상당한 고강도를 나타났으나 용액형 주입재의 경우 현탁액형 주입재에 비하여 매우 낮은 강도를 나타내었다. 또한 주입재가 가지고 있는 환경적 유해성 여부를 평가하기 위해 대상시료를 주입재의 원재료 및 주입재의 고결시편의 양생일수에 따라 중금속 용출시험을 실시한 결과, 선정한 약액조합 및 고결체의 중금속 함량은 규제기준을 만족하였다.

• 한국환경보건학회지
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• 제19권2호
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• pp.46-54
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• 1993

This study was carried out on the stabilized/solidified treatment for the reducing leachability of hazardous heavy metals copper, lead, chromium and cadmium in the hazardous sludge which treated to be unleached heavy metals by sodium diethyl dithiocarbamate. Cement matrix was analyzed for the leachability of 24 hrs and dynamic leaching test, structure and the optimum condition for the stabilization and solidification of the hazardous sludge. In 28 days of curing time the unconfined compressive strength was 21.5 kg/cm$^2$ at the ratio of portland cement (0.5)+fly ash (0.25) and 23.5 kg/cmz at the ratio of portland cement (0.5)+fly ash (0.25) + cake (0.25). High concentration of Pb, Cr and Cd in the sea water and Cu in the distilled water were leached at the dynamic leaching test. The concentration of leaching heavy metals for specimens which were tested 24 hrs were found low leachability with decreasing pH of leachant. According to dynamic leaching test, the low level of copper, lead, cadmium and chromium were leached in the cement matrix with sodium diethyl dithiocarbamate. But the effective diffusion coefficient of unleached cement matrix which was treated sodium diethyl dithiocarbamate was decreased above 2 times than that of cement matrix. The relation of leachant renewal period (Y) and cumulative fraction ion leached (X) was the following regression equations. Solidification with unleached agent. Y$_{Cu}$ = 1413752X + 247, Y$_{Pb}$ = 223501IX + 214, Y$_{Cr}$ = 8310601X - 472, Y$_{Cd}$ = 168787X + 1061 The structure of' solidified matrix with X-ray diffraction analysis was composed more Ca(OH)$_2$, Si, Mg(OH)$_2$ and Al in the unleached cement matrix than those in cement matrix.

• 한국자동차공학회논문집
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• 제22권4호
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• pp.152-159
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• 2014

Urea solution as a reductant of SCR has been widely used to reduce NOx emissions from diesel engine. But it has lots of problems which are freezing at low temperature due to liquid state, deposition of solid formation in the exhaust, dosing device, and complex package such as mixers for uniform concentration of ammonia. In order to overcome these obstacle, ammonium carbonate which is one of solid ammonium materials to produce ammonia gas directly by sublimation process is considered. Simple reactor with visible widow was designed to predict equilibrium temperature and pressure of ammonium carbonate. To simulate real operation conditions under automobile environment, several cycles of heating and cooling condition were settled, two different re-solidification materials were extracted from the reactor and visible window. Analytical study is performed to characterize these unknown materials by XRD(X-Ray Diffraction), FT-IR(Fourier Transform Infrared Spectroscopy), and EA(Elemental Analyzer). From analytical results, re-solidification materials from heating and cooling cycles are very similar to original material of ammonium carbonate.

• 한국건축시공학회지
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• 제1권2호
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• pp.146-153
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• 2001

Radical development has been made in the every field of our society for the past scores of year. Radical development of industry and lining environment has mass-produced various toxic wastes . Which comes to the fore as a serious environmental problem. The purpose of this is to suggest the optima mix design by studying the utility of a toxic waste, plated sludge as a building material and deciding the standards of quality and use of cement and evaluating the properties of mortar and concrete in which plated sludge mixed. From an experiment, compressive strength required high early strength cement or special cement. Watertightness proved to be excellent. Heavy metals, such as Cd, Pb, Cu came out below an environmental standard. Cr+6 exceeded an environmental standard under a steam curing, but came out below an environmental under a standard curing. The higher replacement rate was, the lower frost, fusion and resistance were. Thus, got better results above the goal by condition. It was possible that plated sludge was replaced and solidified to aggregate. Therefore, it is necessary to define the standards of quality on strength, replacement rate of wastes, water permeability, endurance in other to solidify plated sludge to concrete products.