• 한국주조공학회지
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• 제23권5호
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• pp.276-285
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• 2003

In the undercooled melt of $Pd_{40}Cu_{30}Ni_{10}P_{20}$ alloy, the solidification behavior including nucleation and growth of crystals at the micrometer level has been observed in-situ by use of a confocal scanning laser microscope combined with an infrared image furnace. The $Pd_{40}Cu_{30}Ni_{10}P_{20}$ alloy specimens were cooled from the liquid state to glass transition temperature. 575 K, at various cooling late under a helium gas flow. According to the cooling rate, the morphologies of the solidification front are changed among various types, irregular jog like front, columnar dendritic front, cellular grain, star like shape jog and fine grain, etc. The velocities of the solid-liquid interface are measured to be $10^{-5}{\sim}10^{-8}$ m/s which are at least two orders higher than the theoretical crystal growth rates. Combining the morphologies observed in terms of cooling rates and their solidification behaviors, we conclude that phase separation takes place in the undercooled molten $Pd_{40}Cu_{30}Ni_{10}P_{20}$ alloy. The continuous cooling transformation (CCT) diagram was constructed from solidification onset time at various linear cooling conditions with different rate. The CCT diagram suggests that the critical cooling rate for glassy solidification is about 1.5 K/s, which is in agreement with the previous calorimetric findings.

• 한국세라믹학회지
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• 제39권12호
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• pp.1133-1137
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• 2002

폐콘크리트 미분말과 고로 슬래그를 사용하여 유해 산업폐기물 고화용 시멘트를 제조한 후 수화성상과 압축강도를 평가하고 이 시멘트를 COREX 슬러지에 첨가하여 고화처리 하였다. 폐콘크리트 미분말과 슬래그 미분말을 1:1로 하고 여기에 포틀랜드 시멘트와 반수석고를 각각 10% 첨가하여 만든 고화용 시멘트로 사용 가능한 강도를 발현하고 있었다. 이 시멘트로 COREX 슬러지를 고화한 경우에 7일에서 140 kgf/$cm^2$을 상회하는 강도를 보여 폐슬러지를 고화시켜 안정화하는데 응용할 수 있음을 확인하였다.

• 한국주조공학회지
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• 제17권6호
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• pp.608-614
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• 1997

The effect of mold preheating temperature on the microstructure such as grain size, eutectic silicon morphology was investigated for the Al-7wt%Si-0.3wt%Mg alloy. Microstructural variations have been characterized as a function of Sr addition and cooling rate during solidification. Microstructures were correlated with cooling rate, local solidification time and eutectic nucleation temperature, etc. In this study, Sr addition caused increase of local solidification time, undercooling and reduction of eutectic plateau temperature. In logarithmic scale, local solidification time was in inverse proportion to cooling rate. Eutectic nucleation temperature was in inverse proportion to cooling rate of logarithmic scale. Increasing the cooling rate refined dendrite arm spacing and eutectic silicon. Dendrite arm spacing was logarithmically in inverse proportion to cooling rate. Without modifier addition, eutectic silicon was modified at cooling rate of $7^{\circ}C/s$ or higher.

• 한국주조공학회지
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• 제11권1호
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• pp.54-62
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• 1991

A computer program which consists of pre-processor, main solidification simulator and post-processor has been developed for three dimensional solidification analysis of steel castings. The pre-processor is used for mesh generation in a small personal computing system. The modified finite difference method is adopted for the main solidification simulation algorithm. The post -processor graphically presents the simulation results and shows the formation of shrinkage defects. Several experiments on large steel castings in sand mold were carried out. The temperature variations in casting and mold with time are measured experimentally, and the results are compared with calculation results. Several numerical examples for the prediction of shrinkage cavity in large steel casting of SC42 and SCNCrM2 alloys are compared with experimental results. The effect of sleeve and chills on solidification patterns are also studied. Formation of shrinkage defects for the three cases of experimental castings are relatively well predicted by present model.

• 상하수도학회지
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• 제9권3호
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• pp.108-115
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• 1995

The feasibility study of using converter slag as a solidifying agent of digested sewage sludge cake has been performed. The availability of converter slag as solidifying agent has been investigated by several trial tests. Based on the trial test results, the optimum mixing ratios of sludge cake and solidification additive are estabilished. Finally the solidification characters of sludge cake are elucidated by SEM and EDS. It is ascertained that converter slag with a small amount of quicklime enhences the solidification. From the result of pH test, overall pH of specimens tends to decrease slowly with curing time. After solidifying specimens had been cured for 7 days, these are water-cured for 24 hours. The weight and strength of all the specimens are nearly the same regardless of the mixed ratios of solidifying agent. The result of leaching tests for four heavy metal ions, Cd, $Cr^{6+}$, Pb and Cu show that the leaching strength becomes below the decision criteria of the specific wastes, respectively. The SEM observation of the delicate structure shows that needlelike crystals appear after solidification which are not observed before. From the EDS analysis, it is found that the main ingredients of needlelike crystals are Ca, Si, Al and O.

• Korean Chemical Engineering Research
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• 제52권2호
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• pp.199-204
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• 2014

2성분 응고계에서 다공성 mush 층에서의 조성 대류는 생성되는 제품의 질에 영향을 준다. 본 연구에서는 일정한 속도로 응고되는 mush 층을 고려하였다. 선형 안정성 이론을 사용하여 mush 층에 대한 교란방정식을 유도하였고, 기본상태 온도장과 mush 층에서 기공률의 분포를 수치해법으로 조사하였다. 과열량이 클 때 mush 층의 두께는 열경계층의 두께에 비해 상대적으로 작았다. 과열량이 감소함에 따라 mush 층의 두께를 기준으로 한 Rayleigh 수는 증가하였고, mush 층은 조성 대류에 대해 안정해졌다. mush 층의 윗면에 등온조건을 적용한 경우보다 온도 및 열속의 연속조건을 액체-mush 계면에 적용한 경우에 임계 Rayleigh 수가 더 작게 얻어졌다.

• 대한기계학회논문집
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• 제18권7호
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• pp.1818-1832
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• 1994

Transport process during solidification of an AI-CU alloy in a vertical annular mold of which inner wall is cooled is numerically simulated. A model which can take account of local density dependence on the solute concentration is established and incorperated in the analysis. Results show that thermally and solutally induced convections are developed in sequence, so that there is little interaction between them. Thermal convection effectively removes the initial superheat from the melt and vanishes as solidification proceeds from the cooling wall. On the other hand, solutal convection which is developed later over the meshy and the pure liquid regions leads to large-scale redistribution of the consituents. The degree of the initial superheating hardly affects overall solidification behavior except the early stage of the process, when the cooling rate is kept constant. Macrosegregation is reduced remarkably with increasing cooling rate, because not only the liquidus interface advances so quickly that time available for the solute transport is not enough, but also the interdendritic flow is strongly damped by rapid crystal growth within the mushy region.

• 한국주조공학회지
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• 제18권3호
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• pp.283-288
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• 1998

Interest in rapid solidification of magnesium alloys stems from the fact that conventional ingot metallurgy alloys exhibit poor strength, ductility, and corrosion resistance. Such properties can be improved by microstructural refinement via rapid solidification processing. In this study, Mg-Zn alloys have been produced as continuous strips by melt overflow technique. In order to evaluate the influence of additional elements on the grain refinement and mechanical properties, Th and Zr were added in rapidly solidified Mg-5wt%Zn alloy. Then the microstructual observations were undertaken with the objective of evaluating the grain refinement as function of the cooling rate and the additional elements. The tremendous increase in hardness of Mg-Zn base alloys was mainly due to the refinement of the grain structure by the effect of rapid solidification and alloying elements. The formation of intermetallic phases on the grain boundaries may have a positive effect on the corroion resistance. Therefore, despite competition from many other developments, the rapid solidification processing of magnesium alloys emerges as a valuable method to develop superior and commercially acceptable magnesium alloys.

• 한국주조공학회지
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• 제13권3호
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• pp.268-275
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• 1993

In gravity die casting, die cooling systems are frequently employed with water cooling to remove the heat of the solidifying metal. Thermal modeling is an important technique in mold design for improving the productivity of the process. Computer simulation system which consists of pre-processor, main solidification simulator and post-processor has been developed for three dimensional solidification analysis of cyclic gravity die casting. The pre-processor is used for mesh generation in a PC system. The modified finite difference method is adopted for the main solidification simulation algorithm during all the casting cycles. The post-processor graphically presents the simulation results. Several experiments in automotive cast piston were carried out. The temperature variations in casting and mold with time are measured experimentally, and the results are compared with calculation results. The effects of cycle number on solidification pattern are also studied. Several experimental results for the prediction of shrinkage defects are compared with calculated results.

• 동력기계공학회지
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• 제19권3호
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• pp.69-74
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• 2015

Check valves used in vessels include shock-release function on piping system, aside from basic back flow prevention. However, proper and enough protection of system is not obtainable due to use of high-pressure and bulk fluids, resulting from enlargement of vessels. In this study, casting analysis of check valves protecting systems in flow path from water hammering or back flow is conducted, using Z-CAST program. Also, molten metal filling, flow analysis, solidification analysis and shrinkage cavity analysis are conducted. The main results are as following. Regarding filling of each risering, molten metal showed stable supply condition without being isolated. It was identified that the final solidification exists on risering, but shrinkage cavity possibly might happens at the point of isolation solidification.