• E2M - 전기 전자와 첨단 소재
• /
• 제10권2호
• /
• pp.141-149
• /
• 1997

L $a_{0.7}$S $r_{0.3}$Mn $O_{3}$ powders were prepared by both GNP(Glycine-Nitrate Process) and solid state reaction method in various of calcination temperature(800-1000.deg. C) and time in air. Also, L $a_{0.7}$S $r_{0.3}$Mn $O_{3}$ cathode contacts on YSZ(Yttria-Stabilized Zirconia) substrate were prepared by screen printing and sintering method as a function of sintering temperature(1100-1450.deg. C) in air. Sintering behaviors have been investigated by SEM(Scanning Electron Microscope) and porosity measurement. Compositional and structural characterization were carried out by X-ray diffractometer and ICP AES(Inductively Coupled Plasma-Atomic Emission Spectrometry) analysis. Electrical characterization was carried out by the electrical conductivity with linear 4 point probe method. As the calcination period increased in solid state reaction method, L $a_{0.7}$S $r_{0.3}$Mn $O_{3}$ phase increased. Although L $a_{0.7}$S $r_{0.3}$Mn $O_{3}$ single phase was obtained only for 48hrs at 1000.deg. C, in GNP method it was easy to get single and ultra-fine L $a_{0.7}$S $r_{0.3}$Mn $O_{3}$ powders with submicron particle size at 650.deg. C for 30min. The particle size and thickness of L $a_{0.7}$S $r_{0.3}$Mn $O_{3}$ cathode contact by solid state reaction method did not change during the heat treatment, while those by GNP method showed good sintering characteristics because initial powder size fabricated from GNP method is smaller than that fabricated from solid state reaction method. Based on enthalpy change from thermodynamic data and ICP-AES analysis, it was suggested to make cathode contact in composition of (L $a_{0.7}$S $r_{0.3}$)$_{0.91}$ Mn $O_{3}$ which have little second phase (L $a_{2}$Z $r_{2}$ $O_{7}$) for high efficient solid oxide fuel cells applications. As (L $a_{0.7}$S $r_{0.3}$)$_{0.91}$Mn $O_{3}$ cathode contact on YSZ substrate was sintering at 1250.deg. C the temperature that liquid phase sintering did not occur. It was possible to obtain proper cathode contacts with electrical conductivity of 150(S/cm) and porosity content of 30-40%.m) and porosity content of 30-40%.

• 대한기계학회논문집B
• /
• 제34권2호
• /
• pp.173-178
• /
• 2010

빙축열시스템은 저온잠열저장을 위해 물을 사용한다. 그러나 물은 액체에서 고체로 상변화를 하는 과정에서 물의 과냉각 현상에 의하여 냉동기의 냉동용량 증가와 COP감소의 원인이 되고 있다. 본 연구는 저온잠열축열물질로 적용 가능한 TMA(Tri-methyl-amine, $(CH_3)_3N$) 20~25 wt%를 포함하고 있는 TMA-물계 포접화합물(TMA-water clathrate compound)의 냉각특성에 대한 실험적 연구를 수행하였다. 실험적 연구 결과, TMA 질량농도가 높을수록 상변화온도는 증가하였고, 과냉각도와 비열은 감소하였다. 특히, TMA 25wt%를 포함하고 있는 포접화합물은 냉각과정동안 평균 상변화온도 $5.8^{\circ}C$와 과냉각도 $8.0^{\circ}C$, 액상유지시간 651sec 및 비열 3.499 kJ/kgK로서 다른 TMA 농도보다 양호한 냉각특성을 나타내었다. 이와 같이 저온잠열축열물질로서 TMA 25wt%-물계 포접화합물을 적용하는 것이 유리할 것으로 판단된다.

• 한국태양에너지학회:학술대회논문집
• /
• 한국태양에너지학회 2011년도 춘계학술발표대회 논문집
• /
• pp.162-167
• /
• 2011

Thermal storage plays an important role in building energy saving, which is greatly assisted by the incorporation of latent heat storage in building materials. A phase change material is a substance with a high heat of fusion which, melting and solidifying at a certain temperature, can be storing and releasing large amount of energy. Heat is stored or released when the material changes from solid to liquid. Integration of building materials incorporating PCMs into the building envelope can result in increased efficiency of the built environment. The aim of this research is to identify thermal performance of PCMs impregnated building materials which is applied to interior of building such as gypsum and red clay. In order to analyze thermal performance of phase change materials, test-cell experiments and simulation analysis were carried out. The results show that micro-encapsulated PCM has an effect to maintain a constant indoor temperature using latent heat through the test-cell experiments. PCM wallboard makes it possible to reduce the fluctuation of room temperature and heating and cooling load by using EnergyPlus simulation program. Phase change material can store solar energy directly in buildings. Increasing the heat capacity of a building is capable of improving human comfort by decreasing the frequency of indoor air temperature swings so that the interior air temperature is closer to the desired temperature for a long period of time.

• 반도체디스플레이기술학회지
• /
• 제19권3호
• /
• pp.23-29
• /
• 2020

Electrochromic (EC) device is an element whose transmittance is changed by electrical energy. Coloring and decoloring states can be easily controlled and thus used in buildings and automobiles for energy saving. There exist several types of EC devices; EC using electrolytes, polymer dispersed liquid crystal (PDLC), and suspended particle device (SPD) using polarized molecules. However, these devices involve solutions such as electrolytes and liquid crystals, limiting their applications in high temperature environments. In this study, we have studied all-solid-state EC device based on Tin(IV) oxide (SnO₂). A coloring phase is achieved when electrons are accumulated in the ultraviolet (UV)-treated SnO₂ layer, whereas a decoloring mode is obtained when electrons are empty there. The UV treatment of SnO₂ layer brings in a number of localized states in the bandgap, which traps electrons near the conduction band. The SnO₂-based EC device shows a transmittance of 70.7% in the decoloring mode and 41% in the coloring mode at a voltage of 2.5 V. We have achieved a transmittance change as large as 29.7% at the wavelength of 550 nm. It also exhibits fast and stable driving characteristics, which have been demonstrated by the cyclic experiments of coloration and decoloration. It has also showed the memory effects induced by the insulating layer of titanium dioxide (TiO₂) and silicone (Si).

• 대한기계학회논문집B
• /
• 제20권10호
• /
• pp.3322-3333
• /
• 1996

A numerical analysis has been conducted to investigate a modified floating-zone crystal growth process in which most of the melt surface is covered with a heated ring. The crystal rod is not only pulled downward but rotated around its axisymmetric line during crystal growth process in order to produce the flat interface of crystal growth and the single crystal growth of NaNO3 is considered in 6mm diameter. The present study is made from a full-equation-based analysis considering a pulling velocity in all of solid and liquid domains and both of solid-liquid interfaces are tracked simultaneously with a governing equation in each domain. Numerical results are mainly presented for the comparison of the surface shape of rotational crystal rod with that of no-rotational crystal rod and the effects of revolution speeds of the crystal rod. Results show that the rotation of crystal rod produces more its flat surface. In addition, the shape of crystal growth near the centerline is more concaved with the increase in the revolution speed of crystal rod. The flow pattern and temperature distribution is analyzed and presented in each case. As the pulling velocity of crystal rod is increasing, the free surface of the melt below the heated ring is enlarged due to the crystal interface migrating downward.

• 설비공학논문집
• /
• 제11권4호
• /
• pp.549-559
• /
• 1999

An experimental study was peformed to measure the viscosity of microencapsulated PCM slurries as the functions of its concentration and temperature, and also influence to its fluid dynamics. For the viscosity measurement, a rotary type viscometer, which was equipped with temperature control system, was adopted. The slurry was mixed with water and Sodium Lauryl Sulphate as a surfactant by which its suspended particles were dispersed well without the segregation of particles during the experiment. The viscosity was increased as the concentration of MicroPCM particle added. The surfactant increased 5% of the viscosity over the working fluid without particles. Experiments were proceeded by changing parameters such as PCM particles'concentration as well as the temperature of working fluid. As a result, a model to the functions of temperature for the working fluid and its particle concentration is proposed. The proposed model, for which its standard deviation shows 0.8068, is agreed well with the reference's data. The pressure drop was measured by U-tube manometer, and then the friction factor was obtained. It was noted that the pressure drop was not influenced by the state of PCM phase, that is solid or liquid in its core materials at their same concentration. On the other hand, it was described that the pressure drop of the slurry was much increased over the working fluid without particles. A friction factor was placed on a straight line in all working fluids of the laminar flow regardless of existing particles as we expected.

• 대한기계학회논문집
• /
• 제17권8호
• /
• pp.2079-2087
• /
• 1993

The effects of subcooling and natural convection are studied numerically on the melting process of an initially subcooled phase-change medium filled inside a horizontal circular cylinder. It is postulated that melting continues with the tube wall kept at a constant temperature and with the unmelted solid core fixed. Primary emphasis is placed on the evolution of interface morphology, the local/overall heat transfer rate at the tube wall and at the interface, and the structure of natural convection. The numerical results are mainly presented in terms of the Rayleigh and subcooling numbers. As the degree of subcooling intensifies, the melting rate and the movement of the interface are impeded but the interfaces are of similar shape with the passage of time. The heat transfer characteristics are found to be mostly governed by the formation pattern of natural convection in the liquid phase. Good agreement with available experimental data is found.

• 한국전산유체공학회:학술대회논문집
• /
• 한국전산유체공학회 2008년도 춘계학술대회논문집
• /
• pp.472-473
• /
• 2008

Flow boiling in parallel microchannels has received attention as an effective heat sink mechanism for power-densities encountered in microelectronic equipment. the bubble dynamics coupled with boiling heat transfer in microchannels is still not well understood due to the technological difficulties in obtaining detailed measurements of microscale two-phase flows. In this study, complete numerical simulation is performed to further clarify the dynamics of flow boiling in microchannels. The level set method for tracking the liquid-vapor interface is modified to include the effects of phase change and contact angle. The method is further extended to treat the no-slip and contact angle conditions on the immersed solid. Also, the reverse flow observed during flow boiling in parallel microchannels has been investigated. Based on the numerical results, the effects of channel shape and inlet area restriction on the bubble growth, reverse flow and heat transfer are quantified.

• 한국항공우주학회지
• /
• 제44권10호
• /
• pp.887-894
• /
• 2016

고상-액상 상변화물질(PCM, Phase Change Material)을 이용한 위성부품 열제어장치를 설계 및 제작하였으며 열환경시험을 수행함으로써 온도제어 성능을 분석하였다. 설계온도에 부합하는 n-Hexadecane을 PCM으로 채용하였고, 낮은 열전도도를 보완하기 위하여 내부에 전열휜이 장착된 용기를 Al6061로 제작하였다. 위성에 장착하였을 때와 동일한 작동조건을 확보하기 위하여, 부품과 방열판 사이를 열관으로 연결하였으며 열관의 단열부가 관통하도록 PCM 열제어장치를 설치하였다. 동일한 모양과 부피의 열적완충질량(TBM, Thermal Buffer Mass)도 제작하여, 주기적인 가열-냉각 실험을 수행하였다. 실험결과 상변화 잠열에 의한 PCM의 열제어 성능을 확인할 수 있었으며, TBM에 비하여 질량과 보온히터의 소모전력을 절감할 수 있음을 확인하였다.

• 한국항공우주학회지
• /
• 제44권4호
• /
• pp.373-379
• /
• 2016

주기적 단속적으로 작동하는 위성부품의 열제어를 위하여 고상-액상 상변화물질(PCM, Phase Change Material)과 열관을 병렬로 결합한 열제어장치를 제안하였으며, 이의 성능을 수치해석을 통하여 검증하였다. 상변화 중 큰 잠열과 일정하게 유지되는 온도에 의하여 작은 방열판 면적에서도 부품의 최고온도를 제어할 수 있으며, 냉각기에는 PCM에 축적된 에너지가 방출됨으로써 보온히터 소모전력을 절약할 수 있다. 동일한 형태의 Al TBM(Thermal Buffer Mass)을 사용하면 비슷한 효과를 기대할 수 있으나, 질량과 보온히터의 소모전력이 증가하므로 PCM에 비하여 비효율적이다. 설계된 PCM 열제어장치는 발열량과 작동시간에 따라 그 양을 최적화할 수 있다.