• Title/Summary/Keyword: Solid waste form

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Bio-dissolution of waste of lithium battery industries using mixed acidophilic microorganisms isolated from Dalsung mine (달성 광산(鑛山)에서 채취(採取)한 혼합(混合) 호산성 균주를 이용(利用)한 폐리튬 밧데리의 바이오 침출(浸出))

  • Mishra, Debaraj;Kim, Dong-Jin;Ahn, Jong-Gwan;Ralph, David E.
    • Resources Recycling
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    • v.17 no.2
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    • pp.30-35
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    • 2008
  • Mixed acidophilic bacteria were approached for leaching of cobalt and lithium from wastes of lithium ion battery industries. The growth substrates for the mixed mesophilic bacteria are elemental sulfur and ferrous ion. Bioleaching of the metal was due to the protonic action of sulfate ion on the metals present in the waste. It was investigated that bioleaching of cobalt was faster than lithium. Bacterial action could leach out about 80 % of cobalt and 20 % of lithium from the solid wastes within 12 days of the experimental period. Higher solid/liquid ratio was found to be detrimental for bacterial growth due to the toxic nature of the metals. At high elemental sulfur concentration, the sulfur powder was observed to be in undissolved form and hence the leaching rate also decreased with increase of sulfur amount.

Thermal Decomposition and Stabilization of the Lagoon Sludge Solid Waste after Dissolution with Water (라군 슬러지 물 용해 후 고체 패기물의 열분해 및 안정화)

  • Oh Jong-Hyeok;Hwang Doo-Seong;Lee Kue-Il;Choi Yun-Dong;Hwang Sung-Tae;Park Jin-Ho;Park So-Jin
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.3 no.3
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    • pp.249-256
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    • 2005
  • Thermal decomposition and stabilization characteristics of the solid cake after the dissolution of nitrate of the lagoon sludge was investigated. Most of the nitrates were dissolved in the water and removed to the filtrate, but small amount of nitrates, calcium carbonate and uranium were remained in the solid cake. The solid cake was thermally decomposed in the muffle furnace at $900^{\circ}C$ for 5 hours. Uranium, which is in the lagoon 1, was stabilized with $NaNO_3$ decomposition to $Na_{2}O{\cdot}2UO_3$ form. For the lagoon 2, it is confirmed that CaO, which was created by thermal decomposition of the $Ca(NO_3)_2$ and $CaCO_3$, was transferred to $Ca(OH)_2$ in the air with water. Because it is known that $Ca(OH)_2$ is stable material, further additives did not need to the stabilization of the thermal decomposition of the lagoons.

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Study on the Measurement of GHG Emissions and Error Analysis in Form the MSW Incineration Plant Equipment with the Recovery Heat System (2009~2013) (폐열회수시설이 설비된 생활폐기물 소각자원화시설 온실가스 배출량 산정 시 오차분석 (2009~2013))

  • Choi, Won-Geun;Seo, Ran-Sug;Park, Seung-Chul
    • Journal of Environmental Science International
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    • v.25 no.2
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    • pp.239-246
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    • 2016
  • This study aims to analyze region-specific trends in changing greenhouse gas emissions in incineration plants of local government where waste heat generated during incineration are reused for the recent five years (2009 to 2013). The greenhouse gas generated from the incineration plants is largely $CO_2$ with a small amount of $CH_4$ and $N_2O$. Most of the incineration plants operated by local government produce steam with waste heat generated from incineration to produce electricity or reuse it for hot water/heating and resident convenience. And steam in some industrial complexes is supplied to companies who require it for obtaining resources for local government or incineration plants. All incineration plants, research targets of this study, are using LNG or diesel fuel as auxiliary fuel for incinerating wastes and some of the facilities are using LFG(Landfill Gas). The calculation of greenhouse gas generated during waste incineration was according to the Local Government's Greenhouse Emissions Calculation Guideline. As a result of calculation, the total amount of greenhouse gas released from all incineration plants for five years was about $3,174,000tCO_2eq$. To look at it by year, the biggest amount was about $877,000tCO_2eq$ in 2013. To look at it by region, Gyeonggido showed the biggest amount (about $163,000tCO_2eq$ annually) and the greenhouse gas emissions per capita was the highest in Ulsan Metropolitan City(about $154kCO_2eq$ annually). As a result of greenhouse gas emissions calculation, some incineration plants showed more emissions by heat recovery than by incineration, which rather reduced the total amount of greenhouse gas emissions. For more accurate calculation of greenhouse gas emissions in the future, input data management system needs to be improved.

Solidification/stabilization of simulated cadmium-contaminated wastes with magnesium potassium phosphate cement

  • Su, Ying;Yang, Jianming;Liu, Debin;Zhen, Shucong;Lin, Naixi;Zhou, Yongxin
    • Environmental Engineering Research
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    • v.21 no.1
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    • pp.15-21
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    • 2016
  • Magnesium potassium phosphate cement (MKPC) is an effective agent for solidification/stabilization (S/S) technology. To further explore the mechanism of the S/S by MKPC, two kinds of Cd including $Cd(NO_3)_2$ solution (L-Cd) and municipal solid waste incineration fly ash (MSWI FA) adsorbed Cd (S-Cd), were used to compare the effects of the form of heavy metal on S/S. The results showed that all the MKPC pastes had a high unconfined compressive strength (UCS) above 11 MPa. For L-Cd pastes, Cd leaching concentration increased with the increase of Cd content, and decreased with the increase of curing time. With the percentage of MSWI FA below 20%, S-Cd pastes exhibited similar Cd leaching concentrations as those of L-Cd pastes, while when the content of MSWI FA come up to 30%, the Cd leaching concentration increased significantly. To meet the standard GB5085.3-2007, the highest addition of S-Cd was 30% MSWI FA (6% Cd contained), with the Cd leaching concentration of 0.817 mg/L. The S/S of L-Cd is mainly due to chemical fixation, and the hydration compound of Cd was $NaCdPO_4$, while the S/S of S-Cd is due to physical encapsulation, which is dependent on the pore/crack size and porosity of the MKPC pastes.

Sensitivity Analysis of Thermal Parameters Affecting the Peak Cladding Temperature of Fuel Assembly

  • Ju-Chan Lee;Doyun Kim;Seung-Hwan Yu;Sungho Ko
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.21 no.3
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    • pp.359-370
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    • 2023
  • The thermal integrity of spent nuclear fuels has to be maintained during their long-term dry storage. The detailed temperature distributions of spent fuel assemblies are essential for evaluating the integrity of their dry storage systems. In this study, a subchannel analysis model was developed for a canister of a single fuel assembly using the COBRA-SFS code. The thermal parameters affecting the peak cladding temperature (PCT) of the spent fuel assembly were identified, and sensitivity analyses were performed based on these parameters. The subchannel analysis results indicated the presence of a recirculation flow, based on natural convection, between the fuel assembly and downcomer region. The sensitivity analysis of the thermal parameters indicated that the PCT was affected by the emissivity of the fuel cladding and basket, convective heat transfer coefficient, and thermal conductivity of the fluid. However, the effects of the wall friction factor of the canister, form loss coefficient of the grid spacers, and thermal conductivities of the solid materials, on the PCT were predominantly ignored.

Dry friction losses in axially loaded cables

  • Huang, Xiaolun;Vinogradov, Oleg G.
    • Structural Engineering and Mechanics
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    • v.4 no.3
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    • pp.330-344
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    • 1996
  • A model of a cable comprising interacting wires with dry friction forces at the interfaces is subjected to a quasi-static cyclic loading. The first cycle of this process, comprising of axial loading, unloading and reloading is investigated analytically. Explicit load-elongation relationships are obtained for all of the above phases of the cycle. An expression for the hysteretic losses is also obtained in an explicit form. It is shown that losses are proportional to the third power of the amplitude of the oscillating axial force, and are in inverse proportion to the interwire friction forces. The results obtained are used to introduce a model of a cable as a solid rod with an equivalent stiffness and damping properties of the rod material. It is shown that the stiffness of the equivalent rod is weakly nonlinear, whereas the viscous damping coefficient is proportional to the amplitude of the oscillation. Some numerical results illustrating the effect of cable parameters on the losses are given.

Review of Recent Trends and Technology for Additive Manufacturing (적층제조기술 응용사례 및 최신기술동향)

  • Lee, Jaehyang;Park, Sung-Jun
    • Journal of Institute of Convergence Technology
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    • v.6 no.1
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    • pp.1-5
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    • 2016
  • Additive manufacturing is converting a digitally designed object into a tangible three dimensional solid using an additive process where materials are applied in successive layers with no or very limited material waste. It can be distinguished form traditional manufacturing which begins with a fixed amount of raw material and removes excess to arrive at the final product. Generally there are five stages to the additive manufacturing supply chain, namely materials, systems, software, application design and production. In this paper, recent market trends and technology about additive manufacturing based on supply chain are analyzed and reviewed.

Conditions for Rapid Processing of Modified Fish Sauce using Enzymatic Hydrolysis and Improvement of Product Quality 2. Fish Sauce from Sardine Waste and Its Quality (효소분해법에 의한 개량어장유의 속성제조 및 품질에 관한 연구 2. 정어리 폐기물을 이용한 어장유의 속성제조 및 품질)

  • BAE Tae-Jin;HAN Bong-Ho;CHO Hyun-Duk;KIM Jong-Chul;KIM Byeong-Sam;CHOI Soo-Il
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.23 no.2
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    • pp.125-136
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    • 1990
  • To develope a rapid processing method for fish sauce, processing conditions of fish sauce from sardine waste was investigated. The chopped waste was homogenized and hydrolyzed by commercial proteolytic enzymes such as Complex enzyme-2000($2.18\cdot10^4$ U/g solid) and Alcalase($1.94\cdot10^4$ U/g solid) in a cylindrical vessel with 4 baffles and 6-bladed turbine impeller. Optimal temperature for the case of hydrolysis with Complex enzyme-2000 was 50 and that with Alcalase was $55^{\circ}C$. In both cases, the reasonable pH, amount of water for homo-genization, enzyme concentration and hydrolyzing time were 8.0, $40\%$ (W/W), $3\%$ and 100 min, respectively. Heating of the filtrated hydrolysate for 2 hours at $90^{\circ}C$ with $6\%$ of invert sugar was suitable for pasteurization of the hydrolysate and inactivation of enzymes. Flavor, taste and color of the hydrolysate was improved during the thermal treatment in which the browning reaction products might participate and result in antioxidative and bactericidal effects. Combined use of $0.005\%$ of Caryophylli flos with invert sugar was also effective for the improvement of taste. Yield of the fish sauce based on the total nitrogen in the raw sardine waste was $91.2\~92.3\%$ and $87.2\~87.8\%$ of the total nitrogen in the fish sauce was in the form of amino nitrogen. The pH, salinity and histamine content of the fish sauce prepared with $15\%$ of table salt were $6.1\~6.2$, $14.2\~14.4\%$ and less than $10mg\%$, respectively. The fish sauce was stable during the storage of 60 days at $26\pm3^{\circ}C$ on bacterial growth and its quality was also maintained.

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Development of Sulfated Oyster Shell-Based Solidifying Agent for Flowable Backfill Material (황산처리 굴패각을 이용한 유동성 뒷채움용 고화재 개발)

  • Wang, Xue;Kim, Sung Bae;Kim, Chang-Joon
    • Clean Technology
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    • v.24 no.4
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    • pp.315-322
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    • 2018
  • Industrial use of waste oyster shells is limited because of requiring excessive energy for converting natural oyster shells in the form of calcium carbonate ($CaCO_3$) into calcium oxide (CaO) for this purpose. This study aimed to develop energy-saving process for producing solidifying agent using waste oyster shells for backfill materials. It was suggested that oyster shells were converted to calcium sulfates which were mixed with sodium hydroxide solution and red clay, forming solid specimen. The optimal concentrations of sulfuric acid for sulfation of oyster shell and sodium hydroxide to generate calcium hydroxide ($Ca(OH)_2$), were determined. Unconfined compressive strength of solid specimen increased with increasing the content of solidifying agent while it increased also with increasing ratio of natural oyster shells to coal ash. The result clearly demonstrates that solidifying agent consisting of sulfuric acid-treated oyster shell, coal ash, and sodium hydroxide solution, can be effectively utilized for preparing backfill materials using natural oyster shell and coal ash. Sulfuric acid-treated oyster shell-based solidifying agent has not been previously developed and will contribute to broaden industrial application of waste oyster shells.

Removal of Cs by Adsorption with IE911 (Crystalline Silicotitanate) from High-Radioactive Seawater Waste (IE911 (crystalline silicotitanate) 의한 고방사성해수폐액으로부터 Cs의 흡착 제거)

  • Lee, Eil-Hee;Lee, Keun-Young;Kim, Kwang-Wook;Kim, Ik-Soo;Chung, Dong-Yong;Moon, Jei-Kwon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.13 no.3
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    • pp.171-180
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    • 2015
  • This study was performed on the removal of Cs, one of the main high- radioactive nuclides contained in the high-radioactive seawater waste (HSW), by adsorption with IE911 (crystalline silicotitanate type). For the effective removal of Cs and the minimization of secondary solid waste generation, adsorption of Cs by IE911 (hereafter denoted as IE911-Cs) was effective to carry out in the m/V (ratio of absorbent weight to solution volume) ratio of 2.5 g/L, and the adsorption time of 1 hour. In these conditions, Cs and Sr were adsorbed about 99% and less than 5%, respectively. IE911-Cs could be also expressed as a Langmuir isotherm and a pseudo-second order rate equation. The adsorption rate constants (k2) were decreased with increasing initial Cs concentrations and particle sizes, and increased with increasing ratios of m/V, solution temperatures and agitation speeds. The activation energy of IE911-Cs was about 79.9 kJ/mol. It was suggested that IE911-Cs was dominated by a chemical adsorption having a strong bonding form. From the negative values of Gibbs free energy and enthalpy, it was indicated that the reaction of IE911-Cs was a forward, exothermic and relatively active at lower temperatures. Additionally, the negative entropy values were seen that the adsorbed Cs was evenly distributed on the IE911.