• Title/Summary/Keyword: Solid surface

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A Study of Weather Resistance on Dancheong Ground Treatment of Tranditional Wooden Building in Korea (한국 목조건축물 단청 바탕처리에 대한 내후성 연구)

  • Kim, Young Kyun;Han, Kyeong Soon
    • Journal of Conservation Science
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    • v.35 no.5
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    • pp.480-493
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    • 2019
  • In this study, the method for processing glue and glue-alum sizing from the dancheong ground treatment was evaluated with respect to weather resistance, and its effect on the conservation of dancheong was analyzed. Viscosity and pH of the glue and glue-alum specimen were measured and classified into three categories(none layer, glue layer, and glue-alum layer), which were further classified according to low concentration(four times for 2%) and high concentration(once for 10%). The base layer formation was subsequently classified into three categories based on pigment adoption, namely, Noerok(celadonite), Seokganju(terra rossa), and Jangdan(red lead). The completed specimen was subjected to a changing-environment experiment for evaluating weather resistance and observing the surface. Color variations were analyzed before and after the experiment. The results indicate that glue-alum sizing comprising 5% alum or 7% alum has strong acidity that can affect the life of dancheong, and the high level of 7% alum makes it difficult to create a solid coating layer. After ultraviolet irradiation, the specimen with 7% alum changes its color to yellow. Furthermore, after moisture absorption and drying, cracks can be observed on the entire specimen surface that corroborate the physical change. Additionally, gas-based corrosion causes marginal surface changes. Hence, the formation of a stable coating layer can be achieved by incorporating a low concentration glue solution that is almost neutral, and the application of glue-alum sizing having 2% concentration can aid in the conservation of dancheong.

Enhancement of cyanoacrylate-developed marks using p-dimethylaminobenzaldehyde (DMAB) on semi-porous surfaces and analysis of the influence factors on fluorescence intensity (반다공성 재질에 유류된 지문의 CA 훈증 후 p-dimethylaminobenzealdehyde(DMAB) 형광시약 적용 시 표면적과 주변 온도, 기압이 형광착색에 미치는 효과에 관한 연구)

  • Yu, Je-Sul;Kim, Ju-Hah
    • Analytical Science and Technology
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    • v.27 no.4
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    • pp.187-195
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    • 2014
  • It is very important to minimize the damage of latent fingerprints at enhancing the contrast. This study proves the enhancement effects of cyanoacrylate-fumed latent fingerprints using p-dimethylaminobenzealdehyde (DMAB) on semi-porous surfaces and the influence factors. The latent fingerprints in experiment were developed for cyanoacrylate treatment in a vacuum chamber and used after drying at room temperature for 24 hours. For fluorescence staining, the cyanoacrylate-developed marks using DMAB were sublimated during 48 hours under the different conditions of surface area, temperature, atmospheric pressure. First experiment showed how surface area effects on the sublimation rate and fluorescence intensity by DMAB of particle size and container size. In addition, the fluorescence staining using DMAB with solvent-free contact method had the greatest fluorescence intensity after 36 hours and a low fluorescence intensity over a certain size of surface area. Second experiment showed that the evaporation of DMAB solid crystals got a satisfying result in a temperature of $20^{\circ}C$ and reduced time to get the greatest fluorescence intensity. It took a long time to get a optimum level of fluorescence intensity at $30^{\circ}C$ or more and it was less effective in fluorescence intensity. Third experiment on the pressure indicated that the fluorescence intensity of vacuum was weaker than nonvacuum but it was inapplicable to very high variations in pressure.

The Estimation of Water Quality Changes in the Keum River Estuary by the Dyke Gate Operation Using Long-Term Data (장기관측자료에 의한 금강하구둑 수문조작에 따른 수질 변화 평가)

  • KWON Jung-No;KIM Jong-Gu;KO Tae-Seung
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.34 no.4
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    • pp.348-354
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    • 2001
  • This study was conducted to estimation of change characteristics for water quality by the dyke gate operation in the Keum River estuary. The estimation data made use of surveyed data in Keum River estuary by NERDI (National Fisheries Research and Development Institute) during $1990\~1999$. Shown to compare water quality changes at st. A and st. D in Figure 1, the concentrations of TSS, COD and nutrients at st. A were as high as about $2\~4$ times than those at st. D due to affection of fresh water discharge in the Keum River. The percentages of water quality change at surface water by dyke gate operation in the Keum River estuary were shown that TSS (Total Suspended Solid) was decrease to $56\%,\;47\%$ at st. A and D, and COD (Chemical Oxygen Demand) was increase to $68\%,\;71\%$ at st. A and D, respectively. The changes percentage of DIN (Dissolved Inorganic Nitrogen) by dyke gate operation in the Keum River estuary were increase high to $95\%$ at surface water and $7\sim30\%$ at bottom water, but those of DIP (Dissolved Inorganic Phosphorus) were increase to $2.8\sim8.6\%$ at surface water and $28\%$ at bottom water. The range of fluctuation for water quality at each station by dyke gate operation has shown that salinity and TSS are little better than before dyke gate operation, but COD show highly fluctuation. Also we studied estimation of characteristics of water quality change by the season, COD was increased except the summer, TSS was decreased to all season. DIN was increased to about $61\sim172.1\%$ for all season, but DIP was increased to the spring and decreased to the autumn, DIN enrichment in the estuary by dyke gate operation are interpreted to improvement of organic matter decomposition and nitrification by increasing the residence time and to increase nutrient flux in sediments due to decreasing dissolved oxygen and increasing a deposit matter.

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Spectroscopic Analysis of Silica Nanoparticles Modified with Silane Coupling Agent (실란 커플링제에 의해 표면이 개질된 실리카 나노입자의 분광학적 분석)

  • Song, Seong-Kyu;Kim, Jung-Hye;Hwang, Ki-Seob;Ha, Ki-Ryong
    • Korean Chemical Engineering Research
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    • v.49 no.2
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    • pp.181-186
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    • 2011
  • In this study, we used 3-(trimethoxysilyl)propylmethacrylate(MPS) silane coupling agent for surface modification of silica nanoparticles. We studied effects of reaction conditions such as solvent pH, MPS hydrolysis time, reaction time, and molar ratio of MPS to Si-OH groups on silica nanoparticle surfaces, on the surface modification reactions of silica nanoparticles. Fourier Transform Infrared Spectroscopy(FTIR), Elemental Analysis(EA) and solid state crosspolarization magic angle spinning(CP/MAS) Nuclear Magnetic Resonance Spectroscopy(NMR) techniques were used to determine the type and the degree of surface modification. We found MPS reacts preferentially with Si-OH groups of the silica nanoparticles as monomeric form at solvent pH = 4.5. But increasing hydrolysis time of MPS from 30 mins to 90 mins, and molar ratio of MPS to Si-OH groups on silica nanoparticle surfaces, we found that MPS reacts preferentially with Si-OH groups of the silica nanoparticles as oligomeric form.

Numerical analysis of solar heat gain on slim-type double-skin window systems - Heat transfer phenomena with opening of windows and vent slot in summer condition - (전산유체 해석을 통한 슬림형 이중외피 창호의 태양열 취득량 분석 - 높은 태양고도 및 하절기 냉방조건에서의 자연환기구 적용 및 창문 조절 방식별 비교 -)

  • Park, Ji-Ho;Oh, Eun-Joo;Cho, Dong-Woo;Cho, Kyung-Joo;Yu, Jung-Yeon
    • KIEAE Journal
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    • v.17 no.1
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    • pp.69-75
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    • 2017
  • Purpose: Heat transfer analysis of recently developed 'slim type double-skin system window' were presented. This window system is designed for curtain wall type façade that main energy loss factor of recent elegant buildings. And the double skin system is the dual window system integrated with inner shading component, enclosed gap space made by two windows when both windows were closed and shading component effectively reflect and terminate solar radiation from outdoor. Usually double-skin system requires much more space than normal window systems but this development has limited by 270mm, facilitated for curtain wall façade buildings. In this study, we estimated thermophysical phenomena of our double-skin curtain wall system window with solar load conditions at the summer season. Method: A fully 3-Dimentional analysis adopted for flow and convective and radiative heat transfer. The commercial CFD package were used to model the surface to surface radiation for opaque solid region of windows' frame, transparent glass, fluid region at inside of double-skin and indoor/outdoor environments. Result: Steep angle of solar incident occur at solar summer conditions. And this steep solar ray cause direct heat absorption from outside of frame surface rather than transmitted through the glass. Moreover, reflection effect of shading unit inside at the double-skin window system was nearly disappeared because of solar incident angle. With this circumstances, double-skin window system effectively cuts the heat transfer from outdoor to indoor due to separation of air space between outdoor and indoor with inner space of double-skin window system.

Tribological Properties of Pressureless-sinteed Silicon Carbide (상압소결 탄화규소 소결체의 마찰마모특성)

  • Baik, Yong-Hyuck;Choi, Woong;Seo, Young-Hean;Park, Yong-Kap
    • Journal of the Korean Ceramic Society
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    • v.35 no.7
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    • pp.721-725
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    • 1998
  • In this study solid-phase sintered silicon caribide samples composed of SiC powder having boron and car-bon black as additives were prepared by pressureless sintering at $1950^{\circ}C$. The bending strength the frac-ture toughness and the specific werar rate of the samples were examined and the micro structures of the broken and the worn surface were observed by SEM to understand the relationship between the tri-bological charcteristics and the micro structure. Additionally the relationship between the micro struc-tures and the tribological characteristics of the samples for the frictional opponents SiC and $Al_{2}O_{3}$ pins were investigated Conclusions are as follows ; 1. The specific were rate of the samples for the SiC pin was larger than that for the $Al_{2}O_{3}$ pin. HOwever the specific wear rate for the $Al_{2}O_{3}$ pin was increased about 6,45 times as that for the SiC pin under the load increasing. 2. The specific wear rate of the SiC pin was larger than that of the $Al_{2}O_{3}$ pin. owever the specific wear rate of the $Al_{2}O_{3}$ pin was increased about 4 times as that of the SiC pin under the load increasing 3. The micro stucture of the worn surface showed a flat face without cracks in the case that the frictional opponents has the low friction coefficient but in the case of without cracks in the case that the frictional opponents has the low friction coefficient but in the case of the high friction coefficient the micro structure of the worn surface showed an uneven face having spread-ed cracks. 4. The tribological characteristics of thesolid-phase sintered SiC samples was similar to that of li-quid-phase sintered ones when the pin having the high friction coefficient was used.

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The Preparation of $TiO_2$ Coated Activated Carbon Pellets Driven by LED and Removal Characteristics of VOCs (LED구동 $TiO_2$ 코팅 활성탄소 펠렛 제조 및 VOCs 제거 특성)

  • Kim, Yesol;Kim, Do Young;Jung, Min-Jung;Kim, Min Il;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.24 no.3
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    • pp.314-319
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    • 2013
  • In this study, nitrogen doped $TiO_2$ ($N-TiO_2$) coated on an activated carbon pellet (ACP) was prepared using sol-gel and the solid state heat treatment of urea to improve the removal property of volatile organic compounds (VOCs). To explore the visible light photocatalytic activity of the ACP under the light emitting diods (LED), the removal property of benzene gas was characterized by gas chromatography. The SEM and BET results show that the increment of titanium tetra isopropoxide contents leads to the increased $TiO_2$ coating amount of ACP surface and decreased specific surface area. From the results of benzene gas removal, the breakthrough time of ACP10 increased about 2 times compared to that of the ACP. The improved performance was attributed to the $N-TiO_2$ coating on ACP surface, which could be more effective to remove benzene gas under the condition of LED lamp.

Effect of the Tidal Sea Level Change on the Unconsolidated Sediment in Gwangyang Bay (광양만 조석 해수면 변동의 미고결 퇴적층에 대한 영향)

  • CHO Tae-Chin
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.24 no.1
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    • pp.9-20
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    • 1991
  • The characteristics of the unconsolidated sediment in Gwangyang bay was analyzed from the core samples. The porosity of the sediment showed irregular variation with respect to the sedimentation depth, which indicated that sediment weight-induced consolidation was not significant. Numerical analysis for the mechanical and hydraulic behavior of the unconsolidated sediment due to the tidal sea level change was processed. Because of the delayed excessive pore pressure change in the very low permeable mud medium, the magnitude of the excessive pore pressure for the duration of the minimum sea level exceeded the total stress from the sea water weight, which resulted in the negative (tensional) effective stress below the top surface. The in-situ effective stress, obtained by superposing the tensional effective stress on the solid weight-induced compressive stress, was remained to be tensile (quick-sand condition) near the top surface of the mud deposit. The occurrence of the quirk-sand condition provided a theoretical evidence for the insignificant consolidation and the irregular porosity variation of the sediment. When the sand is distributed on the top surface of the mud layer, the quick-sand condition occurred below the sandy mud layer and the downward movement of sand particles was facilitated.

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The Effects of Metal Plate loaded on TLD chip in 6 MV Photon and 6 MeV Electron Beams (6 MV 광자선과 6 MeV 전자선 하에서 TLD 기판 위에 얹힌 금속 박막의 효과)

  • Kim, Sookil;Byungnim Min
    • Progress in Medical Physics
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    • v.10 no.1
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    • pp.41-46
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    • 1999
  • There is necessity for making a smaller and more sensitive detector in small field sizes. This report assesses the suitability of metal-loaded thermoluminescent dosimeters for this purpose. Measurements were performed in the 6 MV photon and 6 MeV electron beams of a medical linear accelerator with LiF thermoluminescence dosimeters (TLD-100) embedded in solid water phantom. TLD-100 chips(surface area 3.2 $\times$ 3.2 $\textrm{mm}^2$) loaded with a metal plate(Tin or gold respectively) were used to enhance dose readings to TLD-100. Surface dose was measured for field size 10 $\times$ 10 $\textrm{cm}^2$ and 100 em SSD. Measurements have been made of the enhanced signal intensity and good linearity for absorbed dose with each metal. Using a 1 mm each metal on TLD-l00 in the beam increased the surface dose to 14% and 56% respectively for 6MV photon. In the case of 6 MeV electron, gold plate enhanced the TL response to 13%, but there is no difference for tin plate. The specific dose response of TLD-100 with thin metal plate increases with electron concentration of metal film, this is most likely due to increased electron scattered from the additional material with electron density higher than TLD-100. This emphasizes the role of TL dosimeters with metal as amplified dosimeters for therapeutic high energy x-ray beams. Due to the enhanced dose reading of TLD-100 with metal plate, it could be possible to develop smaller TL dosimeter with high sensitivity.

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Development of a Sustainable First Flush Management System for Urban Stream Water Quality Management (도시 하천 수질 관리를 위한 지속가능 초기 강우 오염 관리 시스템의 개발)

  • Seo, Dongil;Lee, Tongeun;Kim, Jaeyoung;Koo, Youngmin
    • Ecology and Resilient Infrastructure
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    • v.3 no.4
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    • pp.247-255
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    • 2016
  • Non-point pollutants from surface runoff during rainfall exert adverse effects on urban river water quality management. In particular, the first flush effect during the initial phase of rainfall can deliver significant amounts of pollutant loads to surface waters with extremely high concentrations. In this study, a sustainable first flush effect management system was developed by using settling and filtration that require no additional power or chemicals. A pilot scale experiment has shown that the removal of total suspended solid (TSS), total nitrogen (TN) and total phosphorus (TP) are in ranges of 84 - 95%, 31 - 46%, and 42 - 86%, respectively. An Integrated Stormwater Runoff Management System (ISTORMS) was also developed to efficiently manage the developed system by linking weather forecast, flow rate and water quality modeling of surface runoff and automatic monitoring systems in fields and in the system. This study can provide effective solutions for the management of urban river in terms of both quantity and quality.