• 제목/요약/키워드: Solid surface

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Enhanced Production of Epothilone by Immobilized Sorangium cellulosum in Porous Ceramics

  • Gong, Guo-Li;Huang, Yu-Ying;Liu, Li-Li;Chen, Xue-Feng;Liu, Huan
    • Journal of Microbiology and Biotechnology
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    • v.25 no.10
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    • pp.1653-1659
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    • 2015
  • Epothilone, which is produced by the myxobacterium Sorangium cellulosum, contributes significant value in medicinal development. However, under submerged culture conditions, S. cellulosum will accumulate to form bacterial clumps, which hinder nutrient and metabolite transportation. Therefore, the production of epothilone by liquid fermentation is limited. In this study, diatomite-based porous ceramics were made from diatomite, paraffin, and poremaking agent (saw dust). Appropriate methods to modify the porous ceramics were also identified. After optimizing the preparation and modification conditions, we determined the optimal prescription to prepare high-performance porous ceramics. The structure of porous ceramics can provide a solid surface area where S. cellulosum can grow and metabolize to prevent the formation of bacterial clumps. S. cellulosum cells that do not form clumps will change their erratic metabolic behavior under submerged culture conditions. As a result, the unstable production of epothilone by this strain can be changed in the fermentation process, and the purpose of increasing epothilone production can be achieved. After 8 days of fermentation under optimized conditions, the epothilone yield reached 90.2 mg/l, which was increased four times compared with the fermentation without porous ceramics.

Study on synthesis of Schiff base and its basic characteristics (Schiff base의 합성과 그의 기초적 물성에 관한 연구)

  • Shin, Dong-Gyu;Kwon, Oh-Kwan;Lim, Sung-Taek;Kim, Young-Kwan;Nam, Ki-Dae;Sohn, Byoung-Chung
    • Journal of the Korean Applied Science and Technology
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    • v.15 no.4
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    • pp.57-62
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    • 1998
  • In this study, a new conducting materials, namely, a Schiff base (polymeric azomethine) was synthesized from 2,6-diamino-N-docosyl pyridinium bromide and terephthalaldehyde to obtain a soluble and fusible conducting polymer. The synthesized Schiff base structure was analyzed by using UV/vis absorption spectrophotometer, FT-IR spectrometer and $^1H$-NMR spectrometer. It was found that the Schiff base was successfully synthesized and soluble in carbon tetrachloride$(CC^{14})$, its Langmuir-Blodgett film was easily fabricated, and its surface pressure was determined to be 30mN/m for solid state by measuring ${\pi}$-A isotherm.

Possibility of Dyeing Wastewater Treatment using Chitin (Chitin을 이용한 염색폐수 처리가능성 연구)

  • Hwang, Sung-Kwy;Lee, Han-Seab;Hwang, Yong-Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.15 no.4
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    • pp.87-93
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    • 1998
  • In spite of various applications of chitin derivatives from waste marine sources, commercial use of chitin has been limited due to resistance to chemicals and the absense of proper solvents. We prepared chitin through decalcification, bleaching and deproteination from protunus trituberculatus shells by the application of Hackman's method. Structural and chemical properties of chitin were investigated to have proper specific surface area and particle size by IR, BET and PSA. The amount of absorbed water of chitin reached equilibrium by stirring about 15 minutes. The amount of absored water of the prepared chitin were large than the commercial chitin. When prepared chitin tested on dyeing wastewater, they showed better treatment efficiency in COD, suspended solid, and color tests than the commercial chitin. The adsorption capacity increased with decreasing particle size for the prepared chitin. Treatment efficiency for color was increased as the sitirring rate increased. Results show the possibility of the prepared chitin from waste marine sources as a treatment system for dyeing wastewater.

Properties and Classification of Patterns of Air Discharges (기중방전의 방전원별 특성분석 및 패턴분류)

  • Park, Yeong-Guk;Lee, Gwang-U;Jang, Dong-Uk;Gang, Seong-Hwa;Jeong, Gwang-Ho;Kim, Wan-Su;Lee, Yong-Hui;Im, Gi-Jo
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.1
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    • pp.19-23
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    • 2000
  • Partial discharges(PD)in air insulated electric power apparatus often lead to deterioration of solid insulation by electron bombardments and electrochemical reaction. The PD caused to reduce the life time of power apparatus and to increase power losses. Thus understanding and classification of PD patterns in air are very important to discern sources of PD. In this paper, PD in air by using statistical methods was investigated. We classified air discharges, corona, surface discharges and cavity discharges by Kohonen network. For classification of PD patterns, we used statistical operators and parameters such as skewness$(S^+,\; S^-),\; kurtosis(K^+, K^-),\; mean phase(AP^+, AP^-)$, cross-correlation factor(CC) and asymmetry derived from the mean pulse-height phase distribution$(H_{avg}(\phi))$, the max pulse-height phase distribution $(H_{qmax}(\phi))$, the pulse count phase distribution $(H_n(\phi))$ and the pulse height vs. Repetition rate $(H_q(n))$.

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A New Measurement Method of Dielectric Constants Applied the Principles of Cross Capacitance (Cross Capacitance 원리를 작용한 새로운 유전상수 측정방법 제안)

  • Kim, Han-Jun;Lee, Rae-Duk;Kang, Jeon-Hong;Yu, Kwang-Min;Han, Sang-Ok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.1084-1087
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    • 2002
  • The guard-ring type 3-terminal parallel plate electrodes proposed by ASTM D 150-81 and IEC 250 have been widely used for measurement of dielectric constants of solid dielectrics. However the method using this electrodes causes many uncertainty associated with the measurement errors of the diameter of the guarded electrode. the gap between guarded and guard-ring electrode. the distance of two active electrodes(the thickness of specimen), the roughness and contamination of surface of electrode and specimen. close adherence grade of electrode and specimen. In this paper. a new electrode system of cross capacitance type based on Thompson-Lampard theorem is designed and is employed for the measurement of dielectric constant. The results of simulation of guard-ring electrode and cross capacitance electrode using FEM program show that distance measurement between two electrodes in guard-ring electrode produces large uncertainty. on the other hand this effect in cross capacitance electrode is negligible. Furthermore. the air gap effects in the cross capacitance electrode is 5.6 times less sensitive than that in guard-ring electrode by assuming air gap of $50{\mu}m$.

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Characteristics of poly-Si TFTs using Excimer Laser Annealing Crystallization and high-k Gate Dielectrics (Excimer Laser Annealing 결정화 방법 및 고유전 게이트 절연막을 사용한 poly-Si TFT의 특성)

  • Lee, Woo-Hyun;Cho, Won-Ju
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.1
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    • pp.1-4
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    • 2008
  • The electrical characteristics of polycrystalline silicon (poly-Si) thin film transistor (TFT) crystallized by excimer laser annealing (ELA) method were evaluated, The polycrystalline silicon thin-film transistor (poly-Si TFT) has higher electric field-effect-mobility and larger drivability than the amorphous silicon TFT. However, to poly-Si TFT's using conventional processes, the temperature must be very high. For this reason, an amorphous silicon film on a buried oxide was crystallized by annealing with a KrF excimer laser (248 nm)to fabricate a poly-Si film at low temperature. Then, High permittivity $HfO_2$ of 20 nm as the gate-insulator was deposited by atomic layer deposition (ALD) to low temperature process. In addition, the solid phase crystallization (SPC) was compared to the ELA method as a crystallization technique of amorphous-silicon film. As a result, the crystallinity and surface roughness of poly-Si crystallized by ELA method was superior to the SPC method. Also, we obtained excellent device characteristics from the Poly-Si TFT fabricated by the ELA crystallization method.

An experimental study for prediction of the fluctuating pressure induced by a cavitating propeller (캐비티가 발생한 프로펠러의 변동압력 추정을 위한 실험적 연구)

  • K.S. Kim;I.S. Moon;K.Y. Kim;I.H. Song;J.T. Lee
    • Journal of the Society of Naval Architects of Korea
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    • v.36 no.1
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    • pp.47-52
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    • 1999
  • The influence of propeller revolution on measurement of fluctuating pressure is almost minimized in the KRISO cavitation tunnel and the measurement accuracy of fluctuating pressure acting on a flat plate due to a cavitating propeller is improved. The measurement data for Sydney Excess propeller is compared with the measurement results of other research institutes loading to the conclusion that KRISO data is so stable and reasonable. The fluctuating pressure data measured on a model ship and the prototype ship is compared with the data measured on the flat plate. The solid boundary factor, derived from a calculation based on a lifting surface theory, is applied to predict full scale pressure level from the experimental data on the flat plate, showing quite reasonable agreement with full scale data.

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Analysis of Energy Concentration Characteristics of Heliostat used in 200kW Tower Type Solar Thermal Power Plant (200kW 탑형 태양열발전시스템에서 사용되는 Heliostat의 집열특성 분석)

  • Park, Young-Chil
    • Journal of the Korean Solar Energy Society
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    • v.31 no.3
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    • pp.80-88
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    • 2011
  • Heliostat in the tower type solar thermal power plant is a sun tracking mirror system to reflect the solar energy to the receiver and the optical performance of it affects to the efficiency of whole power plant most significantly. Thus a solid understanding of heliostat's energy concentration characteristics is the most important step in designing of the heliostat field and the whole power plant. The work presented here is the analysis of energy concentration characteristics of heliostat used in 200kW solar thermal power plant, where the receiver located at 43m high in tower has $2{\times}2$m rectangular shape. The heliostat reflective surface is formed by 4 of $1{\times}1$m flat plate mirror facet and the mirror facet is mounted on the spherical frame. The direct normal incident radiation models in vernal equinox, summer solstice, autumnal equinox and winter solstice are first derived from the actually measured data. Then the intercept ratio, heat flux distribution and total energy collected at the receiver for the heliostats located in the various places of the heliostat field are investigated. Finally the effect of mirror facet installation error on the optical performance of the heliostat is analyzed.

Oligothiophene-based Semi-Conducting Nanostructures: from Solution to Solid-State Aggregates

  • Leclere, Ph.;Surin, M.;Lazzaroni, R.;Feast, W.J.;Schenning, A.P.H.J.;Meijer, E.W.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.304-304
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    • 2006
  • The possibility to develop optoelectronic devices with improved properties by controlling the degree of organization at the molecular level of organic materials has been driving the design of new ${\pi}-conjugated$ systems. In particular, the organization by self-assembling processes (${\tilde{\Box}}{\d{\Box}}}$ interactions, hydrogen bonding) of well-defined oligomeric systems such as disubstituted oligothiophene derivatives has been demonstrated as a promising approach to conjugated materials with a high degree of structural order of the constituent building blocks. The self-organization of conjugated building blocks in solution or on surfaces, leading to the construction of nanoscopic and mesoscopic architectures, represents a starting point for the construction of molecular electronics or even circuits, through surface patterning with nanometer-sized objects.

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Mechanical Properties and Microstructures in WC-12%Co/Low Carbon Steel Metal Matrix Composites(MMC) Welding Overlay

  • 임희식;김태형;박경채
    • Journal of Welding and Joining
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    • v.21 no.2
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    • pp.50-56
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    • 2003
  • Metal matrix composites(MMC) consist of metal matrix into which is distributed a second solid phase. The normal intension is to develop a material with superior mechanical properties (for example increased toughness, stiffness and wear resistance) compared to those inherent in the matrix component. In this study, WC-12%Co/low carbon steel MMC overlays have been prepared by Gas Metal Arc Welding(GMAW) according to feeding rate of WC-12%Co grit. The macro and microstructures were examined using optical microscopy (OM) and scanning electron microscopy(SEM) each other. The characteristics of hardness and wear resistance have been investigated. WC-12%Co/low carbon steel MMC overlays which have been taken good beads without porosity and cracks were manufactured by method of GMAW. Matrix of overlayed surface was seen as fish bone and faceted dendrite structures. It was known that structures were iron tungsten carbides, Fe$_{6}$W$_{6}$C which have been occurred by melting of WC-12%Co grits. After MMC had been tested by block-roll wear test it was known that WC-12%Co/low carbon steel MMC has a excellent wear resistance by exiting Fe6w6c and WC-12%Co grit. The consequence was that region of overlay with Fe$_{6}$W$_{6}$C phase has been showed a model of adhesive wear, but region of overlay with WC-12%Co grit was restrained as a result of mechanism that wear of WC-12%Co grit is not adhesive but fracture.racture.