• Title/Summary/Keyword: Solid state

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Synthesis and Hydration Property of 3CaO.${3Al_2}{O_3}$.$CaSO_4$ Clinker by Solid State Reaction (고상반응에 의한 3CaO.${3Al_2}{O_3}$.$CaSO_4$ 클링커의 제조 및 수화)

  • 전준영;김형철;조진상;송종택
    • Journal of the Korean Ceramic Society
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    • v.37 no.5
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    • pp.459-465
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    • 2000
  • 3CaO.3Al2O3.CaSO4(C4A3)clinker was prepared by solid state reaction and then its hydration property was investigated. C4A3 clinker was fired at various temperatures in the range of 700~135$0^{\circ}C$. The hydration of it was studied by XRD, DSC, Solid-state 27Al MAS NMR and SEM. According to the results, the Ca4A3 clinker was produced by reacting calcium aluminates with CaSO4 and Al2O3 and C4A3 was formed as a main phase after calcining at 120$0^{\circ}C$. The hydration products were mainly calcium monosulfoaluminate hydrate and Al(OH)3, and they were produced after 2hrs of hydration. However the hydration rate was about 74% at 3days.

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Nonlinear Dynamics of Orthogonally Polarized Dual-mode Solid-state lasers (서로 수직으로 편광된 이중 모드 고체레이저에 대한 동력학)

  • Park, Jong-Dae;Cho, Chang-Ho
    • The Journal of Natural Sciences
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    • v.17 no.1
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    • pp.39-50
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    • 2006
  • There are two relaxation frequencies in orthogonally polarized dual-mode solid-state lasers. Complex dynamic behaviors such as chaos can be observed by modulating orthogonally polarized dual-mode solid-state lasers. In this paper, we derived Maxwell-Bloch equations by considering anisotropy explicitly in laser-atom interactions and explained the complex nonlinear dynamical behaviors.

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Polymorphic Characterization of Pharmaceutical Solids, Donepezil Hydrochloride, by 13C CP/MAS Solid-State Nuclear Magnetic Resonance Spectroscopy

  • Park, Tae-Joon;Ko, Dong-Hyun;Kim, Young-Ju;Kim, Yon-Gae
    • Bulletin of the Korean Chemical Society
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    • v.30 no.9
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    • pp.2007-2010
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    • 2009
  • Donepezil hydrochloride is a reversible acetylcholinesterase inhibitor that is used in the treatment of Alzheimer’s disease to improve the cognitive performance. It shows different crystalline forms including hydrates. Therefore, it is very important to confirm the polymorphic forms in the formulations of pharmaceutical materials because polymorphs of the same drug often exhibit significant differences in solubility, bioavailability, processability and physical/chemical stability. In this paper, four different forms of donepezil hydrochloride were prepared and characterized using X-ray powder diffraction, Fourier transform infrared, and solid-state nuclear magnetic resonance (NMR) spectroscopy. This study showed that solid-state NMR spectroscopy is a powerful technique for obtaining structural information and the polymorphology of pharmaceutical solids.

Structural Studies of Hydrotalcite Compounds Calcined with Different Temperatures by $^{27}Al$ Solid-state NMR Spectroscopy

  • Park, Tae-Joon;Kim, Yong-Ae
    • Journal of the Korean Magnetic Resonance Society
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    • v.11 no.1
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    • pp.42-47
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    • 2007
  • Several hydrotalcite compounds calcined with different temperature for applications in a chlorine resistant textile were prepared, and its structural changes in dependence on the temperature were studied by using $^{27}Al$ solid-state nuclear magnetic resonance(NMR) spectroscopy. We found that the Al coordination was partly lowered from octahedral to tetrahedral site as the calcined temperature goes up. And we also investigated the hydrotalcite-treated textile for chlorine resistance by using $^{27}Al$ solid-state NMR spectroscopy.

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A Novel DC Solid-State Circuit Breaker for DC Grid (DC Grid를 위한 새로운 구조의 DC Solid-State Circuit Breaker)

  • Kim, Jin-Young;Kim, In-Dong;Nho, Eui-Cheol
    • The Transactions of the Korean Institute of Power Electronics
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    • v.17 no.4
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    • pp.368-376
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    • 2012
  • According to developed distributed generators, Solid State Circuit Breaker(SSCB) is essential for high power quality of DC Grid. In this paper, a simple and new structure of DC SSCB with a fast circuit breaker and fault current limiter is proposed. It can help to choice low specification of elements because of the limiting of fault current and achieve economic efficiency for minimizing auxiliary SCRs. Also all of SCRs have little switching loss because they operate under ZVS and ZCS. Through simulations and experiments of short-circuit fault, the performance characteristic of proposed circuit is verified and a guideline is so suggested that the DC SSCB is applied for a different DC grid using formulas.

Automation of Solid-state Bioreactor for Oyster Mushroom Composting

  • Lee, Ho-Yong;Kim, Won-Rok;Min, Bong-Hee
    • Mycobiology
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    • v.30 no.4
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    • pp.228-232
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    • 2002
  • This study focused on the production of high quality compost for the growth of aero-thermophilic fungi, which has a promoting effect on the growth rate and production of oyster mushrooms. The automated solid-state bioreactor system was designed on the basis of a Three-Phase-One system, which controls the serial steps of prewetting, pasteurization and fermentation processes. High numbers of thermophilic fungi and bacteria were recovered from the mushroom composts prepared by this solid-state bioreactor. The rates of composting process were depended on physical as well as chemical factors. Among these factors, the parameters of moisture content and temperature were found to be particularly important. In our automated system, constant levels of moisture content, temperature and ventilation via mixing were provided by a centralized control apparatus including PLC, water tank and water jacket systems. These features induced higher microbiological activity of aero-thermophiles.

Solid State NMR Studies of Proton Conducting Polymer, Poly(vinyl phosphonic) acid

  • Lee, Young-Joo;Bingol Bahar;Murakhtina Tatiana;Sebastiani Daniel;Ok, Jong-Hwa;Meyer Wolfgang H.;Wegner Gerhard;Spiess Hans Wolfgang
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.347-347
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    • 2006
  • Polymers containing poly(vinyl phosphonic) acid segments are promising candidates to be used as proton conducting membranes. Solid state NMR spectroscopy represents an ideal probe of proton motion on the molecular level, because it allows us to selectively detect the nuclei of interest. In this paper, we apply solid state NMR methods to poly(vinyl phosphonic) acid in order to demonstrate that the proton conduction of poly(vinyl phosphonic acid) results from P-OH proton through hydrogen bonding and that the condensation of phosphonic acid leads to decrease in proton conductivity. $^{1}H\;and\;^{31}P$ solid state NMR experiments are supported by quantum chemical computation of NMR parameters.

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A Study on the Needed Function of Low Voltage Solid State Meter Considering Electricity Tariff Policy (요금정책을 고려한 저압용 전자식 전력량계의 필요기능에 관한 연구)

  • Kim, Jae-Sung;Lee, Tae-Hyung;Kim, Jae-Chul
    • Proceedings of the KIEE Conference
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    • 1999.07b
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    • pp.800-802
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    • 1999
  • The meters for low voltage customer presently being used in Korea are all mechanical type and there is strict limitation on applying various customized tariff structure. Recently low voltage solid state meter is under development by several makers of the watt hour meter in Korea. Also, KEPCO has a plan to use the solid state meter for low voltage customer to reduce peak power. So, this paper suggests the needed function of low voltage solid state meter considering electricity tariff policy.

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$\alpha$-halo formation in semi-solid state processed hypereutectic Al-Si alloy (반고상 가공과 공정 Al-Si 합금에서 $\alpha$-halo의 형성)

  • 김인준;김도향
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 1997.06a
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    • pp.183-195
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    • 1997
  • The micorstructural characteristics, particularly $\alpha$-halo formation, in semi-solid state processed hypereutectic Al-Si alloy was investigated. The microstructural changes during reheating of wedge type mold cast ingot, hot-rolled sheet, and Si particulate reinforced Al composite was compared with those occurred during stirring of semi-solid state hypereutectic alloy. In the case of semi-solid state reheating of wedge type ingot and hot-rolled sheet, fine particles of Si as well as $\alpha$-halo formed after heat treatment. Although there seemed to be no coarsening with variations of holding time, the region of $\alpha$-halo decreased due to homogenization. Nucleation and recrystallization was accelerated with the addition of alloying elements during hot rolling resulting in primary Si particle size decrease and $\alpha$-halo formation. In the case of extruded specimens, very little morphological change of reinforcing Si particles was observed. Almost no $\alpha$-halo formed during reheating because of the oxide film formed on the reinforcing Si particles which acted as a diffusion barrier between the matrix and the primary Si particles.

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Fatigue Life Estimation of Solid-state Drive due to the Effect of Dummy Solder Ball under Forced Vibration (Solid-state drive 강제진동시 dummy solder ball 효과에 의한 피로수명 예측)

  • Lee, Juyub;Jang, Gunhee;Jang, Jinwoo
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2014.10a
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    • pp.978-983
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    • 2014
  • This research proposes a method to estimate the fatigue life of solid-state drive(SSD) due to the effect of dummy solder ball under forced vibration. Mechanical jig is developed to describe the SSD in laptop computer. The jig with SSD is mounted on a shaker, and excited by a sinusoidal sweep vibration within the narrow frequency band around the first resonant frequency until the SSD fails. A finite element model of SSD is also developed to simulate the forced vibration. It shows that the solder joints at the corners of controller package are most vulnerable components and that placing dummy solder balls at those area is effective method to increase fatigue life of SSD.

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