• Title/Summary/Keyword: Solid Solution

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A Study on the Development of Floor-Fixed Standpipe Sway Brace for Narrow Space (협소공간전용 바닥고정형 입상관 흔들림방지버팀대 개발에 관한 연구)

  • Jin, Se-Young;Choi, Su-Gil;Park, Sang-Min;Yeon, Tae-Young;Kim, Chang-Su;Kim, Si-Kuk
    • Fire Science and Engineering
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    • v.34 no.1
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    • pp.47-54
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    • 2020
  • This paper proposes a solution to the problems of constructing and installing sway braces for existing standpipes in narrow spaces and pits. The study develops a floor-fixed sway brace for a narrow space that can support the ground area under horizontal seismic loads (X-axis, Y-axis) as well as vertical seismic loads (Z-axis). The results of structural analysis using SolidWorks simulation showed that the eccentric load was generated in the first design according to the anchored position along the vertical direction, and the problem of exceeding the allowable stress of the material along the horizontal and vertical directions. In the second design model, deformation caused by the eccentric load along the vertical direction, similar to the first design model, did not occur. The maximum strain rate was 0.17%, which is approximately 12.84% less than the first design model (Maximum strain rate of 13.01%). It was confirmed that the structural stability and durability improved. Compressive and tensile load testing of the prototypes showed that all of them meet the performance criteria of the standard.

Study of the Electrical Conductivity of the $({\alpha}-Nb_2O_5)_{1-x^-}(PbO)_x$ Solid Solution ($({\alpha}-Nb_2O_5)_{1-x^-}(PbO)_x$ 고용체의 전기전도도)

  • Roh, Kwon-Sun;Ryu, Kwang-Sun;Jun, Jong-Ho;Lee, Sung-Ju;Yo, Chul-Hyun
    • Journal of the Korean Chemical Society
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    • v.35 no.6
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    • pp.625-629
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    • 1991
  • The electrical conductivity of the Niobium Oxide-Lead Oxide systems containing 2.5, 5.0, 7.5, and 10.0 mol% of Lead Oxide has been measured in a temperature range 700${\sim}$$1100^{\circ}C$ under oxygen partial pressure of 2.0 ${\times}$ $10^{-1}$${\sim}$1.0 ${\times}$ $10^{-5}$ atm. The electrical conductivities of the system decreased with increasing PbO mol% and varied from $10^{-5}$ to $10^{-1}$ $ohm^{-1}$ $cm^{-1}$. The activation energy for conductivity was about 1.70 eV. The oxygen pressure dependence of electrical conductivity revealed that the system was a mixed conductor between ionic and electronic conductivities at high oxygen pressures and a n-type electronic conductivity with oxygen pressure dependence of -1/4 order at low oxygen pressures. The defect structure and electrical conduction mechanism of the system have been discussed with the data obtained.

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Microwave Dielectric Characteristics of the $xMgTiO_3$(1-x) ($Na_{1/2}Ln_{1/2}$) $TiO_3$(Ln = La, Pr, Nd, Sm)Systems ($xMgTiO_3$(1-x) ($Na_{1/2}Ln_{1/2}$) $TiO_3$(Ln = La, Pr, Nd, Sm)의 초고주파 유전특성에 관한 연구)

  • Kim, Duck-Hwan;Lim, Sang-Kyu;An, Chul
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.35D no.10
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    • pp.51-59
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    • 1998
  • ($Na_{1/2}Ln_{1/2}$)$TiO_3$ceramics have a high relative dielectric constant and a positive temperature coefficient of resonant frequency ($\tau_f$)(where Ln represents a lanthanide: $La^{+3}$, $Pr^{+3}$, $Nd^{+3}$ and $Sm^{+3}$). On the other hand, $MgTiO_3$ ceramic has a high Qf value and a negative temperature coefficient. So We have investigated the microwave dielectric properties of $xMgTiO_3$-(1-x) ($Na_{1/2}Ln_{1/2}$)$TiO_3$. In these systems, there are no clues on solid-solution and secondary phase. There are mixed phases with $MgTiO_3$and ($Na_{1/2}Ln_{1/2}$)$TiO_3$ phases. Its dielectric characteristics (Qf, temperature coefficient and dielectric constant) are intermediate between ($Na_{1/2}Ln_{1/2}$)$TiO_3$ and $MgTiO_3$ and are predictable by the logarithmic mixing rule. The dielectric ceramic compositions temperature coefficient each approximates to zero at Ln=La, x=0.9, Ln=Pr, x=0.87, and Ln=Nd, x=0.84. At this time, there are Qf values in the range of 55,000 to 28,00GHz and relative dielectric constants in the range of 22 to 25.

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Use of East Deep Sea Water for the Increase of Functional Components of Ginseng (Panax ginseng C.A. Meyer) and Tomato (Lycopersicon eculentum L.) (인삼과 토마토의 기능성 성분 증진을 위한 동해 해양심층수의 이용)

  • Woo Cheon-Seok;Kang Won-Hee
    • Korean Journal of Plant Resources
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    • v.19 no.2
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    • pp.331-335
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    • 2006
  • This experiment was conducted to investigate the effect of deep sea water on fruit quality and yield of tomato. In the deep sea water treatments, fruit growth and weight were decreased as the concentration of deep sea water increased. Especially, the fresh weight of second truss was decreased significantly than first truss. Soluble solid content was increased significantly in higher concentration treatment especially at 30mM and 40mM treatment. That was increased more in the first than in the second truss fruits. Most of hexose in fruits were glucose and fructose. The reason of increased glucose and fructose contents was the decline of growth because of salinity stress by deep sea water treatment. however deep sea water treatment increased the lycopene content, especially in 20mM treatment. It is assumed that deep sea water treatment cause induction and promotion of ethylene. The higher concentration of deep sea water to the solution, the eater fruit quality improvement was noticed. However, proportional yield reduction accompanied concentration, 20mM deep sea water improved fruit quality without a significant yield reduction. The Re content was the highest among ginsenosides in all treatments. The contents total of ginsenosides in all treatments, except EC 8 treatment, was higher than those in the controlled treatment. The PT/PD value was 1.31 of the lowest in the EC 8 treatment and was 2.52 of the highest in the EC6 treatment. Rf contents in high increase was detected at all treated ginseng roots.

Effect of phosphorus application on appearance of algal water bloom and rice yield in rice-barley double cropping system

  • Hwang, Jae-Bok;Bae, Hee-Soo;Park, Tae-Seon;Choi, In-Bae
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2017.06a
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    • pp.233-233
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    • 2017
  • Algal communities are important to maintain the aquatic ecosystems function. Algae have short life cycles, they respond quickly to environmental change and their diversity and density can indicate and the quality of their habitat. The bloom forms before the rice seedings have emerged, it may present a physical barrier that prevents the seedlings from penetrating the floodwater. Wind may also move the algal bloom, pushing the young plants beneath the surface. Another harmful action develops when the water dries up and the algae form a layer at the bottom of the field. The layer envelops the seedlings, which are not yet deeply rooted, and drag them to the surface when the water is let in again. Soil utilization pattern can be the mail facter affecting soil physico-chemical properties, especially in soil phosphorus (P). Solid content of the algae culture solution increased with the increase in the nitrogen rather the phosphors concentration. Phosphoric acid was treated with conventional treatments (100-0%, before transplanting time-tillering stage), 50-50%, 0-100%, and un-treated. The herbicide was treated on the 7 DAT (day after transplanting). Green algae samples were collected 20 DAT. Total phosphoric acid was the highest at 0.06 in 50-50% treatment in 20 DAT. The amount of green algae was about twice (9.8 mg/20ml) that of un-treated. Total number of green algae was 54 species(Green algae 35 species, Euglena 9 species, Stone wheel 10 species). Among the phosphoric acid treatment methods, the number of occurrences of green algae were the highest with 39 species in 0-100%, followed by 50-50%, 28 species, conventional treatments, 22 species, non-treatment, 18 species, respectively. Rice Yield was not significantly different by phosphoric treatment time, but slightly higher than un-treated. The maximal algal biomass was observed about 2weeks or 1 month after transplanting; the subsequent decrease of the biomass was related to the consumption by grazers and to a deficient light under the rice canopy. Maximal algal growth was observed just before tillering. To estimate the suitable method of phosphorus application in puddled-soil drill seeding of rice, available phosphorus appearance of algal water bloom, and rice yield were investigated in paddy soil of rice-barley double cropping system.

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Selective Ni Recovery from Spent Ni-Mo-Based Catalysts (니켈-몰리브데늄 성분계 폐촉매로부터 니켈의 선택적 회수)

  • Lee, Tae Kyo;Han, Gi Bo;Yoon, Suk Hoon;Lee, Tae Jin;Park, No-Kuk;Chang, Won Chul
    • Applied Chemistry for Engineering
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    • v.19 no.6
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    • pp.668-673
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    • 2008
  • The objective of this study is to optimize the leaching conditions of sequential leaching and extracting processes for selective Ni recovery from spent Ni-Mo-based catalyst. The selective Ni recovery process consists of two processes of leaching and extracting process. In this 2-step process, Ni component is dissolved from solid spent Ni-Mo-based catalyst into leaching agent in leaching process and sequentially extracted to Ni complex with an extracting agent in the extracting process. The solutions of nitric acid ($HNO_3$), ammonium carbonate ($(NH_4)_2CO_3$) and sodium carbonate ($Na_2CO_3$) were used as a leaching agent in leaching process and oxalic acid was used as an extracting agent in extracting process. $HNO_3$ solution is the most efficient leaching agent among the various leaching agent. Also, the optimized leaching conditions for the efficient and selective Ni recovery were the leaching temperature of $90^{\circ}C,\;HNO_3$ concentration of 6.25 vol% and elapsed time of 3 h. As a result, Nickel oxalate having the highest yield of 88.7% and purity of 100% was obtained after sequentially leaching and extracting processes under the optimized leaching conditions.

Factors Influencing Protoplast Isolation and Culture in Three Capsicum Species (세 가지 고추속 식물의 원형질체 분리 및 배양에 미치는 요인)

  • 임학태;염옥희;전익조;조미애;양승균
    • Korean Journal of Plant Tissue Culture
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    • v.28 no.3
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    • pp.141-146
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    • 2001
  • Protoplasts were isolated from cotyledons, hypocotyls, and mesophyll tissues of three species of Capsicum species (C. anuumm, C. bacatuum, and C. chacoense). Combination of Cellulysin (1%) and Macero-zyme (0.25%) in 0.65 M sorbitol was found to be the most effective for the digestion of cell wall, regardless of the Capsicum species. Antioxidant MES (2-[N-Morpholino]ethanesulfonic acid) in the enzyme solution helped protoplasts overcome browning. After 5 days of initial culture, Cell division occurred in modified K8p medium containing 1~5 mg/L zeatin, 0.5 mg/L IAA, 0.1~0.5 mg/L TDZ, and 1 mg/L 2,4-D under continuous dark condition at $25^{\circ}C$. Semi-solid agarose culture method was more effective than liquid culture, and it also protected the cells from browning caused by polyphenolic compound released during protoplast culture. A total of 4000 calli were obtained from protoplast culture of different capsicum species. All of these calli were transferred to the 100 combinations of regeneration media using various plant growth regulators; TDZ, IAA, 2ip, BAP, NAA, and zeatin. These calli derived from protoplast of three species of capsicum were, however, not differentiated into shoots.

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Effects of pre-curing process on improvement of the compressive strength of IGCC-slag-based-geopolymer (IGCC 용융 슬래그로 제조된 지오폴리머의 강도증진에 Pre-curing이 미치는 영향)

  • Park, Soo-bin;Kim, Kang-duk;Kang, Seung-gu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.6
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    • pp.295-302
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    • 2017
  • In this study, the effect of pre-curing process on the enhancement of mechanical properties of IGCC-slag-based-geopolymer was studied. Pre-curing is a process in which the green geopolymer is left at room temperature for a certain period of time prior to the high-temperature curing, and it is known as increasing the strength of a specimen. Therefore, in this experiment, the compressive strength of the geopolymers was measured according to various pre-curing conditions, and microstructure and crystal phase changes were observed by SEM and XRD, respectively. The W/S ratio was determined to be 0.26, which can offer the maximum geopolymer strength with easy molding ability, and the concentration of the alkali solution was 15 M. Pre-curing was performed at room temperature for 0 to 27 days. Compressive strength of the geopolymer made with pre-curing process increased by 36~87 % compared with the specimens made with no pre-curing process. Those improved compressive strength for the pre-cured geopolymer was confirmed owing to promotion effect of pre-curing process on generation of C-S-H gel and zeolite phases, which were analyzed using by XRD and SEM measurement.

Formation and Color of the Spinel Solid Solution in CoO-ZnO-$Fe_2O_3$-$TiO_2$-$SnO_2$ System (CoO-ZnO-$Fe_2O_3$-$TiO_2$-$SnO_2$계 Spinel 고용체의 생성과 발색에 관한 연구)

  • 이응상;이진성
    • Journal of the Korean Ceramic Society
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    • v.28 no.11
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    • pp.897-907
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    • 1991
  • This study was conducted to research the formation and the color development of CoO-ZnO-Fe2O3-TiO2-SnO2 system for the purpose of synthesizing the spinel pigments which are stable at high temperature. After preparing CoO-ZnO-Fe2O3, in which CoO causes the color, as a basic composition, $\chi$CoO.(1-$\chi$)ZnO.Fe2O3 system, $\chi$CoO.(1-$\chi$)ZnO.TiO2 system and $\chi$CoO.(1-$\chi$)ZnO.SnO2 system were prepared with $\chi$=0, 0.2, 0.5, 0.7, 1.0 mole ratio respectively. The manufacturing was carried out at 128$0^{\circ}C$ for 90 minutes. These specimens were analyzed by the reflectance measurement and the X-ray diffraction analysis and the results were summarized as follows: 1. All of the specimens formed the spinel structure and were colored with stable yellow or blue. 2. As the content of CoO and Fe2O3 in the specimens being increased, the reflectance of each specimen was measured becoming lower and the colors were changed from yellow to greyish blue and from blue to dark blue. 3. As the substituting amount of Co2+ ion for Zn2+ ion in $\chi$CoO-ZnO-TiO2-SnO2 system being increased, the colors were changed from blue to greyish blue. The colors were changed from yellow to grayish green owing to the tetrahedral Co2+ ions being increased, the octahedral Co2+ ions being decreased with increasing the amount of Sn4+ ions. 4. CoO-ZnO-Fe2O3-TiO2-SnO2 system, in which Zn2+ was substituted with Co2+ and Fe3+ was substituted with Ti4+ and Sn4+, easily formed the spinel structure without regard to the amount of substitution or the ion owing to the selectivity of the coordination number: 4 of Zn2+, 4 of Co2+, 6 of Fe3+ or 6 of Ti4+ and Sn4+.

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A Study on Electrodeionization for Purification of Primary Coolant of a Nuclear Power Plant (원자력 발전소의 일차 냉각수 정화를 위한 전기탈이온법의 기초연구)

  • Yeon, Kyeong-Ho;Moon, Seung-Hyeon;Jeong, Cheorl-Young;Seo, One-Sun;Chong, Sung-Tai
    • Journal of Radiation Protection and Research
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    • v.24 no.2
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    • pp.73-86
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    • 1999
  • The ion-exchange method for the purification of primary coolant has been used broadly in PWR(pressurized water reactor)-type nuclear power plants due to its high decontamination efficiency, simple system, and easy operation. However, its non-selective removal of metal and non-radionuclides shortens its life, resulting in the generation of a large amount of waste ion-exchange resin. In this study, the feasibility of electrodeionization (EDI) was investigated for the purification of primary cooling water using synthetic solutions under various experimental conditions as an alternative method for the ion exchange. The results shows that as the feed flow-rate increased, the removal efficiency increased and the power consumption decreased. The removal rate was observed as a 1000 decontamination factor(DF) at a nearly constant level. For the synthetic solution of 3 ppm TDS (Total Dissolved Solid), the power consumption was 40.3 mWh/L at 2.0 L/min of feed flow rate. The higher removal rate of metal species and lower power consumption were obtained with greater resin volume per diluting compartment. However, the flow rate of the EDI process decreased with the elapsed time because of the hydrodynamic resistivity of resin itself and resin fouling by suspended solids. Thus, the ion-exchange resin was replaced by an ion-conducting spacer in order to overcome the drawback. The system equipped with the ion-conducting spacer resolved the problem of the decreasing flow rate but showed a lower efficiency in terms of the power consumption, the removal rate of metal species and current efficiency. In the repeated batch operation, it was found that the removal efficiency of metal species was stably maintained at DF 1000.

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