• Applied Chemistry for Engineering
• /
• v.22 no.4
• /
• pp.429-432
• /
• 2011

The feasibility of applications of the char obtained from a gasification process of municipal-waste refuse derived fuel (RDF) as an auxiliary fuel was evaluated by combustion experiments. The higher heating value of the RDF char was 3000~4000 kcal/kg and its chlorine content was below the standard requirement demonstrating its potential as an auxiliary fuel. In the combustion exhaust gas, the maximum $NO_x$ and $SO_2$ concentrations were 240 ppm and 223 ppm, respectively. If an aftertreatment is applied, it is possible to control their concentrations low enough to meet the air pollutant emission standard. The HCl concentration was relatively high indicating that a care should be taken for HCl emission from the combustion of RDF. Based on the temperature distribution within the reactor, the concentration change of $O_2$ and $CO_2$, and the amount and the loss on ignition of solid residue, it was inferred that the combustion reaction was the most reliable when the excess air ratio of 1.3 was used.

• Resources Recycling
• /
• v.30 no.1
• /
• pp.53-59
• /
• 2021

Waste vinyl generated from household waste has been used as a solid refuse fuel (SRF) due to the presence of impurities such as soil, metal, and glass; however, the amount of SRF used has been decreasing owing to recent environmental problems, thereby necessitating the need for recycling. In this study, the mixed recycled raw material produced from household waste vinyl and polyethylene (PE) single recycled raw material produced from agricultural waste vinyl were examined. Raw material analysis revealed that waste vinyl was mainly composed of polyethylene, and approximately 2% of ash remained in the mixed recycled raw material, whereas no ash was found in the PE single recycled raw material. In addition, the analysis of tensile strength according to the mixing ratio of the two recycled raw materials revealed that the highest tensile strength was approximately 16 MPa under the heat treatment temperature of 200 ℃, compression pressure of 30 MPa, and a mixing ratio of 3:7 (mixed:PE single). In addition, the highest bending strength was approximately 39 MPa under the heat treatment temperature of 200 ℃, compression pressure of 30 MPa, and a mixing ratio of 3:7 (mixed:PE single). Therefore, the possibility of recycling waste vinyl was suggested by investigating the change in strength characteristics according to the mixing ratio of the recycled raw materials.

• Transactions of the Korean hydrogen and new energy society
• /
• v.31 no.2
• /
• pp.169-176
• /
• 2020

There is a growing interest in hydrogen energy utilization since an alternative energy development has been demanded due to the depletion of fossil fuels. Hydrogen is produced by the reforming reaction of natural gas and biogas, and the electrolysis of water. An solid oxide electrolyte cell (SOEC) is reversible system that generates hydrogen by electrolyzing the superheated steam or producing the electricity from a fuel cell by hydrogen. If the water can be converted into steam by waste heat from other processes it is more efficient for high-temperature electrolysis to convert steam directly. The reasons are based upon the more favorable thermodynamic and electrochemical kinetic conditions for the reaction. In the present study, steam at over 180℃ and 3.4 bars generated from a boiler were converted into superheated steam at over 700℃ and 3 bars using a cylindrical steam superheater as well as the waste heat of the exhaust gas at 900℃ from a solid refuse fuel combustor. Superheated steam at over 700℃ was then supplied to a high-temperature SOEC to increase the hydrogen production efficiency of water electrolysis. Computational fluid dynamics (CFD) analysis was conducted on the effects of the number of 90° elbow connector for piping, insulation types and insulation layers of pipe on the exit temperature using a commercial Fluent simulator. For two pre-heater injection method of steam inlet and ceramic wool insulation of 100 mm thickness, the highest inlet temperature of SOEC was 744℃ at 5.9 bar.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.31 no.2
• /
• pp.45-52
• /
• 2023

As of 2020, 139,753 tons/day of livestock manure is generated. Most of the livestock manure is made of compost(75.3%) and Liquor(11.7%) and is spread on farmland. The compost and Liquor of these livestock manure are the main causes of water pollution. Therefore, it is necessary to convert livestock manure into energy. For this reason, hydrothermal carbonization technology was applied to evaluate the physical and chemical properties. Among livestock manure, cow manure was used. Through hydrothermal carbonization, it was confirmed that the HHV (Kcal/kg) of 3,101 kcal/kg of raw material rises to more than about 3,800 kcal/kg at 220℃ or higher. This result was judged to be influenced by carbonization through a clear trend of decrease in O/C and H/C ratios. As a result, the value of Bio-SRF was evaluated through hydrothermal carbonization of cow manure, and All other items except for chlorine showed satisfactory results.

• 한국신재생에너지학회:학술대회논문집
• /
• 2010.06a
• /
• pp.207.2-207.2
• /
• 2010

자원자원의 절약과 재활용 촉진에 관한 법률에 폐기물 고형연료에 관한 조항 등 폐기물 고형연료에 관한 제반 규정이 도임된 2006년 이후 폐기물 고형연료 에너지화에 대한 관심이 크게 대두되고 정부 및 산업계의 사업추진이 활발하게 진행되어 오고 있다. 본 연구는 국내에서 최초로 RDF를 전용으로 연소하는 pilot plant급 순환유동층 보일러를 제작 건설하고 RDF 연료를 연소하여 성능특성과 운전특성을 연구 분석한 것이다. 연구 과정에서 8ton/h급 순환유동층 보일러를 독자적으로 설계하고 건설하였으며, 건설 전 과정을 연구진이 감리하고 관리하였다. 보일러의 스팀사양은 $450^{\circ}C$와 38ata로 하였다. 또한 시운전 및 정상운전을 위한 운전체계를 자체적으로 수립하였다. 설치된 보일러는 장시간의 운전과 반복 실험을 통해 상용 규모 보일러의 설계 자료를 확보하였다. 운전특성을 파악하기 위하여 국내에서 생산되는 RPF와 RDF 각 일종을 입수하여 연소실험을 수행하고 그 특성 자료를 비교하였다. 폐기물 고형연료는 순환유동층 보일러에서 뛰어난 연소 특성을 나타내었으며 배연특성도 양호하였다. 성형된 RDF는 장기간의 운전에서도 안정적인 연소특성을 나타내었다. 다만 HCl의 배출 특성은 환경 규제치를 넘어 섰으며 별도의 배가스 처리기술을 적용하여 환경기준을 맞출 수 있었다. 본 연구 결과를 토대로 60ton/h급 상용규모 RDF 전용 순환유동층 보일러를 설계하였다. 보일러의 용량은 10MWe 발전과 12ton/h 증기 공급에 적합한 규모로 산업체나 지역난방용 열병합 보일러에 적합한 사양이다.

• Journal of Korean Society for Atmospheric Environment
• /
• v.33 no.5
• /
• pp.473-479
• /
• 2017

This study was designed to understand characteristics of oxy-combustion of coal, dried sewage sludge and solid refuse fuel (SRF). Thermogravimetric analysis was conducted by burning the fuels with air, 21% oxygen ($O_2$)/79% carbon dioxide ($CO_2$) and 30% $O_2/70%$ $CO_2$. Heating rates were varied as 5, 10, 25, 40 and $100^{\circ}C/min$. Complete coal combustion was found at the heating rates of 5, 10, 25 and $40^{\circ}C/min$, and different combustion behavior was found with the gas composition at the heating rates of 10, 25, 40 and $100^{\circ}C/min$. Coal combustion with 30% $O_2/70%$ $CO_2$ showed the highest while coal combustion with 21% $O_2/79%$ $CO_2$ showed the lowest combustion rate. On the other hand, the combustion of dried sewage sludge and SRF showed similar combustion behavior with respect to the combustion gas composition. This suggests that oxy-combustion of dried sewage sludge and SRF which contain a large amount of volatile matter may show similar combustion behavior to their air combustion.

• Journal of Korea Society of Waste Management
• /
• v.35 no.7
• /
• pp.647-652
• /
• 2018

The emission of nitrogen oxides has a great environmental impact. It leads to Los Angeles type smog, and it recently has attracted attention as a source of ultrafine dust. The main sources of nitrogen oxides are internal combustion engines and industrial boilers. These emission sources are processes that are essential for human industrial activities, so the regulation of original use is impossible. Therefore, special control methods should be applied to reduce NOx emissions into the atmosphere. In this study, we investigated how the supply of ER and urea influences the removal of nitrogen oxides from SRF combustion boilers. Experimental results show that the removal efficiency of nitrogen oxides can be up to 80% under the conditions of ER 2.0 and a urea feed of 0.5 LPM.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.12 no.10
• /
• pp.4679-4688
• /
• 2011

This study was performed to the municipal waste generation amounts and characteristics for B city in Gangwon province, predicted the methane gas generation rate emitted from landfill, and analyzed the possibility of energy recovery to RDF(Refuse Derived Fuel) using combustible waste. The study results showed that the average bulk density of municipal waste for B city was 144.0 kg/$m^3$, and the average ratios of combustible waste were 36.0 % of paper, 21.6 % of vinyl, and 19.7 % of food waste. respectively. In the experiment for heating value, high and low heating value(moisture) was measured to 3,471 $kca{\ell}$/kg and 2,941 $kca{\ell}$/kg, respectively. After the prohibition of burying of food waste in landfill, the heating value of municipal waste was dramatically increased due to increase of the ratio of paper, vinyl, and plastic waste. The prediction results of methane gas generation rate emitted from landfill showed that the gas generation rate is increasing to 2,505.7 CH4 ton/year in 2021. After then, the rate is decreasing gradually. When the RDF facility is installed, the rate is decreasing after peaking at 1,956.9 CH4 ton/year in 2013. The generation rate of LFG emitted from waste landfill of B city was analyzed to 9.92 $m^3$/min, similar to 10.11 $m^3$/min for other city.

• Fire Science and Engineering
• /
• v.22 no.1
• /
• pp.99-104
• /
• 2008

It is important to understand thermal characteristic as a method to estimate the new materials, because spontaneous ignition characterized by causing combustion in the low temperature without ignition source. If can not find out the thermal characteristics of materials, it is frequent that causes of fires could not be found. The danger level of spontaneous ignition material should be estimated and by closely studying its thermal characteristic. However, RPF(Refuse Paper & Plastic Fuel) is a solid matter and getting increasesa year by year because it is an economy profit as alternative energy for limited fossil fuels. Some time RPF occur a fire in the cases of its production process and conservation. Therefore study for thermal stability and critical ignition temperature of RPF was so imperative that the experiment by means of Bombe Calorimeter, TG-DTA, MS80, SIT-II, and Wire Basket Test was implemented. As a result, RPF had a caloric value 26.4-28.3 MJ/kg, and its initial pyrolysis temperature was $192^{\circ}C$ at heating rate 2 K/min. With the result of analysis by MS 80 which is an instrument measuring microscopic calory, pure RPF not containing water has higher caloric value than RPF containing 20% water. Also, SIT-II which is an instrument of insulated auto-ignition was ignited by $118.5^{\circ}C$. This temperature is lower than that of Wire Basket Test. The critical ignition temperature was calculated by Frank-Kamenetskii equation can cause ignition at $80^{\circ}C$ when conserved in the height of 10 m by the standard of infinity slab.

• Journal of the Korea Organic Resources Recycling Association
• /
• v.16 no.3
• /
• pp.65-74
• /
• 2008

In this study, the composition and physico-chemical characteristics of municipal solid waste (MWS) which was treated in four different area were investigated. It is necessary to measure the characteristics of MSW to build a waste treatment and Refuse Derived Fuel (RDF) facility, the data-base and total managing of the landfill. It was found that the average density of solid wastes is in the range of $78.15-199.8kg/m^3$. This MSW was composed of 8.87% of food wastes, 38.8% of papers, 34.12% of plastics & vinyls, 7.16% of textiles, 0.96% of wood, 1.3% of rubber & leathers and others, respectively. Most of MSW are composed of food, paper and plastic waste and more than 94% was combustible waste. For three components, moisture is 17.38%, combustible component is 69.03% and ash is 6.24%. The chemical element has the high order of carbon, oxygen, hydrogen on the dry basis of wastes. And the low heating value of the MSW which is measured by calorimeter is calculated as 2973.8 kcal/kg and high heating value of the MSW is calculated as 5209.94 kcal/kg.