• Applied Chemistry for Engineering
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• v.27 no.4
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• pp.397-401
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• 2016

A new solid oxidizer, pyridinium dinitramide (Py-DN) is a low toxic energetic material which can be utilized as a HPGP (high performance green propellant). In this work, Py-DN was synthesized using various starting materials including potassium sulfamate, pyridine hydrochloride, strong nitric acid and sulfuric acid. Physical and chemical properties of the Py-DN were characterized using UV-Vis, FT-IR and a thermal analyzer and their properties were compared to those of previously prepared salts including ammonium dinitramide[ADN, $NH_4N(NO_2)_2$] and guanidine dinitramide[GDN, $NH_2C(NH_2)NH_2N(NO_2)_2$] in our lab. Endothermic and exothermic decomposition temperatures of Py-DN were $77.4^{\circ}C$ and $144.7^{\circ}C$, respectively. The combustion caloric value was 1739 J/g, which is thermally more sensitive than that of conventional dinitramides. It may enable to lower the decomposition temperature, which can reduce preheating temperature required for satellite thruster applications.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.42 no.5
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• pp.430-436
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• 2014

The mission objective of STEP Cube Lab. (Cube Laboratory for Space Technology Experimental Project) classified as a pico-class satellite is to verify the technical effectiveness of payloads such as variable emittance radiator, SMA washer, oscillating heat pipe and MEMS based solid propellant thruster researched at domestic universities. In addition, the MEMS concentrating photovoltaic power system and the non-explosive holding and separation mechanism with the advantages of high constraint force and low shock level will be developed as the primary payloads for on-orbit verification. In this study, the feasibility of the mission actualization has been confirmed by the preliminary system design.