• Korean Chemical Engineering Research
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• 제44권6호
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• pp.614-622
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• 2006

질산망간수용액의 열분해에 의한 이산화망간 적용 $Ta/Ta_2O_5/MnO_2$ 커패시터의 특성 연구를 수행하였다. 질산망간수용액의 TG/DSC 분석을 통해 약 $230{\sim}250^{\circ}C$ 범위에서 단일상의 이산화망간이 생성되었다. 열분해 온도, 질산망간수용액의 농도, 열분해 회수를 이산화망간 고체 전해질 생성의 기초 변수로 선정하고 이에 따른 커패시터 특성을 평가하였다. 최적 조성을 기준으로 복사열분해 방식이 대류열분해 방식에 비하여 우수한 특성을 발휘하였다. 이는 복사열분해에 의해 상대적으로 구형의 작은 입자 상태의 이산화망간 입자들이 생성되고 이를 통해 미세 다공성 구조의 커패시터 소결체 내부에 균일하고 치밀한 이산화망간 고체전해질 층이 생성되는 것에서 기인하는 결과임을 확인하였다.

• 열처리공학회지
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• 제33권5호
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• pp.226-231
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• 2020

The Cu-Co-Si alloy shows high strength by forming precipitates by aging precipitation heat treatment of supersaturated solid solution treated with solution treatment such as Cu-Ni-Si alloy, and the Co₂Si precipitated phase is dispersed in the copper matrix. The effect of aging treatment on the microstructure, mechanical and electrical properties of Cu-Co-Si alloys for electronic devices was investigated. As a results of SEM/EDS analysis, it was found that Co₂Si precipitates of 30~300 nm size were distributed in grains. By performing the double aging treatment, it was possible to improve the strength and electrical conductivity by dispersing the fine precipitate evenly.

• 소성∙가공
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• 제10권3호
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• pp.223-234
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• 2001

The characteristics of thixoforming process can decrease liquid segregation because of the improvement in fluidity in a globular microstructure state and utilizes flow without an air entrapment. Therefore, in order to obtain the sound parts of metal matrix composites by using thixoforming process which has co-existing solidus-liquidus phase, it is very important to design a die shape property and to obtain the fabrication conditions which affect the unifomity of the solid fraction on unfilling state and various defects throughout the fabricated parts. The die designs and fabrication conditions to obtain the good piston part are proposed for thixoforging process of metal matrix composites. When reheated metal matrix composites billets were transferred to the closed die gate, thixoforging were carried out under the various pressure(60, 80, 100MPa) with controled forging speed. The mechanical properties such as hardness and tensile strength for thixoforged parts have been investigated after T6 heat treatment.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 1997년도 추계학술대회 논문집
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• pp.808-811
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• 1997

MMC has excellent mechanical properties in many ways in automotive industrial, and get into the spotlight as a light materials substituted for iron and steel. But the know-how about MMC research lack, MMC is expensive and difficult to apply the sound parts. Especially it is difficult to produce the hollow type parts composed with MMC. Therefore, hollow type parts of metal composites by using thixoforming process which as co-existing solidus-liquidus phase, it is very important to obtain forming condition. In this study, MMC billet producted by electro-magnetic stirring and mechanical stirring process is formed to hollow type parts of thixoforming process and inspected of suitability for application. It is optimized production condition, and applied to experiment. After variable materials were produced for thixoforming process, it were inspected of suitability for application by comparsion with mechanical properties. In this study, used materials were A357, A380 10%vol, and 20%vol SiCp, and the size of particultes were 14$\mu\textrm{m}$ and 5.5$\mu\textrm{m}$.

• 한국정밀공학회지
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• 제13권8호
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• pp.88-95
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• 1996

유리섬유가 강화된 열가소성 복합재료 판재의 성형성에 대한 이해를 돕기 위해 이론적 고찰과 실험적 고찰이 행해졌다. 성형시험에서 사용된 형상은 임의의 방향으로 위치한 유리섬유를 중량비로 30% 함유한 폴리프로필렌 재료가 사용되었고, 시험된 형상은 판재의 굽힘성이나 인장성을 측정하는데 널리 사용되는 스위프트컵(Swift flat-bottomed cup)모양이다. 성형시험과 재료시험은 플리프로필렌 Matrix의 유리성 천이온도(Glass transition temperature)와 용융온도 사이에서 행해졌다. 본 연구의 이론과 고찰을 위해서 재료의 평면 방향으로는 동질성을 그리고 그 직각 방향으로는 이질성을 가진 연속체 물질로 가정하여 유도하였다. 이러한 이론적 결과는 실험 결과와 비교되어졌고,이를 통해 시험된 재료의 최적의 성형조건을 제시하였다.

• 한국정밀공학회지
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• 제15권3호
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• pp.119-126
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• 1998

유리섬유 강화 열가소성 복합재료는 고상성형법에 의해 저렴한 가격으로 큰 부피의 제품의 제조에 널리 사용될 수 있어 아주 좋은 전망을 가지고 있다. 그러나 이러한 재료의 성형성이나 재료거동의 특성은 아직 잘 파악되지 않았다. 본 연구의 주안점은 이러한 재료의 단순 굽힘에서의 굽힘성형성을 연구하는데 두었다. 실험에 사용된 재료는 임의의 방향으로 위치한 유리섬유를 중량비로 20 %, 35 %, 40 % 함유한 폴리프로필렌이다 굽힘시험은 75 $^{\circ}C$에서 150 $^{\circ}C$ 사이의 온도에서 25 $^{\circ}C$ 씩 증가하면서 행했고, 편치속도는 2.54 mm/sec와 0.0254 mm/sec에서 행했다. 단순 굽힘시험에서 측정된 굽힘성형성은 해석적 모델로 예측한 결과와 비교하였다. 실험결과와 예측결과가 비교적 잘 일치함을 보였으며, 굽힘성 map으로써 성형 온도와 펀치반경의 좌굴에 대한 효과를 가시화 함은 물론 좋은 성형조건을 선정할 수 있는 좋은 도구로써 나타내었다.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 2003년도 가을 학술발표회 논문집
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• pp.197-198
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• 2003

Poly(butylene terephthalate)(P5T) has long history as an engineering thermoplastic. PBT was first introduced commercially to the market place as an injection molding resin about 1969 by Celanese Plastics in the U.S.A. It is still widely used as a molding resin. Processing or forming methods for solid-phase deformation, such as stretching, hydrostatic extrusion. roller stretching, rolling, and so on can improve the mechanical properties effectively. (omitted)

• 한국태양에너지학회 논문집
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• 제27권4호
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• pp.51-58
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• 2007

Gas hydrate is a special kind of inclusion compound that can be formed by capturing gas molecules to water lattice in high pressure and low temperature conditions. When referred to standard conditions, $1m^3$ solid hydrates contain up to $172Nm^3$ of methane gas, depending on the pressure and temperature of production. Such large volumes make natural gas hydrates can be used to store and transport natural gas. In this study, three-phase equilibrium conditions for forming methane hydrate were theoretically obtained in aqueous single electrolyte solution containing 3wt% NaCl. The results show that the predictions match the previous experimental values very well, and it was found that NaCl acts as an inhibitor.

• 소성∙가공
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• 제28권3호
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• pp.123-129
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• 2019

Hypereutectic Al-Si alloys have been widely utilized for wear-resistant components in the automotive industry. In order to expand the application of Hypereutectic Al-Si alloys, the addition of alloying elements forming a stable precipitate at high temperature is required. Thermally stable inter metallic compounds can be formed through the addition of transition elements such as Fe, Ni to Al alloys. However, the amount of transition element to be added to Al alloys is limited due to their low solid solubility. Also, hypereutectic Al-Si-Fe alloys form coarse primary Si phases and needle-shaped intermetallic compounds during solidification in the general casting processes. In this study, the effects of the destruction of Intermetallic compound and Si phase are investigated via hot extrusion. Both the microstructure and mechanical properties are discussed under different extrusion conditions.

• 한국분말재료학회지
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• 제9권6호
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• pp.394-408
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• 2002

Nanostructured high strength metastable Al-, Mg- and Ti-based alloys containing different amorphous, quasicrystalline and nanocrystalline phases are synthesized by non-equilibrium processing techniques. Such alloys can be prepared by quenching from the melt or by powder metallurgy techniques. This paper focuses on one hand on mechanically alloyed and ball milled powders containing different volume fractions of amorphous or nano-(quasi)crystalline phases, consolidated bulk specimens and, on the other hand. on cast specimens containing different constituent phases with different length-scale. As one example. $Mg_{55}Y_{15}Cu_{30}$- based metallic glass matrix composites are produced by mechanical alloying of elemental powder mixtures containing up to 30 vol.% $Y_2O_3$ particles. The comparison with the particle-free metallic glass reveals that the nanosized second phase oxide particles do not significantly affect the glass-forming ability upon mechanical alloying despite some limited particle dissolution. A supercooled liquid region with an extension of about 50 K can be maintained in the presence of the oxides. The distinct viscosity decrease in the supercooled liquid regime allows to consolidate the powders into bulk samples by uniaxial hot pressing. The $Y_2O_3$ additions increase the mechanical strength of the composites compared to the $Mg_{55}Y_{15}Cu_{30}$ metallic glass. The second example deals with Al-Mn-Ce and Al-Cu-Fe composites with quasicrystalline particles as reinforcements, which are prepared by quenching from the melt and by powder metallurgy. $Al_{98-x}Mn_xCe_2$ (x =5,6,7) melt-spun ribbons containing a major quasicrystalline phase coexisting with an Al-matrix on a nanometer scale are pulverized by ball milling. The powders are consolidated by hot extrusion. Grain growth during consolidation causes the formation of a micrometer-scale microstructure. Mechanical alloying of $Al_{63}Cu_{25}Fe_{12}$ leads to single-phase quasicrystalline powders. which are blended with different volume fractions of pure Al-powder and hot extruded forming $Al_{100-x}$$(Al_{0.63}Cu_{0.25}Fe_{0.12})_x$ (x = 40,50,60,80) micrometer-scale composites. Compression test data reveal a high yield strength of ${\sigma}_y{\geq}$700 MPa and a ductility of ${\varepsilon}_{pl}{\geq}$5% for than the Al-Mn-Ce bulk samples. The strength level of the Al-Cu-Fe alloys is ${\sigma}_y{\leq}$550 MPa significantly lower. By the addition of different amounts of aluminum, the mechanical properties can be tuned to a wide range. Finally, a bulk metallic glass-forming Ti-Cu-Ni-Sn alloy with in situ formed composite microstructure prepared by both centrifugal and injection casting presents more than 6% plastic strain under compressive stress at room temperature. The in situ formed composite contains dendritic hcp Ti solid solution precipitates and a few $Ti_3Sn,\;{\beta}$-(Cu, Sn) grains dispersed in a glassy matrix. The composite micro- structure can avoid the development of the highly localized shear bands typical for the room temperature defor-mation of monolithic glasses. Instead, widely developed shear bands with evident protuberance are observed. resulting in significant yielding and homogeneous plastic deformation over the entire sample.