• 제목/요약/키워드: Solid Oxide

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셀 입구 예열방법에 따른 고체산화물 연료전지/가스터빈 하이브리드 시스템의 성능해석 (Performance Analysis of Solid Oxide Fuel Cell/Gas Turbine Hybrid Systems for Different Cell Inlet Preheating Methods)

  • 양원준;김동섭;김재환
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 추계학술대회
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    • pp.1664-1669
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    • 2004
  • Design analysis of the solid oxide fuel cell and gas turbine combined power system is performed considering different methods for preheating cell inlet air. The purpose of air preheating is to keep the temperature difference between cell inlet and outlet within a practical design range. Three different methods are considered such as a burner in front of the cell, a preheater in front of the cell and recirculation of the cathode exit gas. Analyses are carried out for two maximum cell temperature differences. The greater temperature difference ensures higher efficiency. The cathode exit gas recirculation exhibits better performance than other methods.

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고체 산화물 연료전지 음극에서 개질 가스의 경쟁적 전기화학 반응 (Competitive electrochemical oxidation of reformate gas in SOFCs)

  • 김용민;배중면;배규종;김정현;이창보
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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    • pp.5-8
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    • 2008
  • SOFC (Solid oxide fuel cell) has an advantage in the term of fuel flexibility, comparing with other kinds of fuel cells. In SOFC and fuel reformer cooperation system, the reformate gas with the various $H_2$/CO ratios is delivered into the anode of SOFC. In this situation, electrochemical oxidation reactions of the reformate gas in the anode are complex and competitive. In this paper, the effects of the composition of $H_2$ and CO on the overall electrochemical oxidation at Ni-YSZ anode are studied by testing the open circuit voltage (OCV) and current-voltage characteristics of single cells.

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연료극 지지체식 Flat Tube 고체산화물 연료전지 제조 및 특성 (Fabrication and Characteristics of Anode Supported Flat Tube Solid Oxide Fuel Cell)

  • 김종희;손희정;이길용;유승호;신동원;송락현;현상훈
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2003년도 춘계학술발표강연 및 논문개요집
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    • pp.76-76
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    • 2003
  • 제 3세대로 불리우는 차세대 발전시스템인 고체산화물 연료전지(Solid Oxide Fuel Cell, SOFC)는 연료전지 가운데 발전효율이 가장 높고, NOx와 SOx의 발생이 없는 무공해 청정에너지 발전 시스템으로 많은 연구가 진행되고 있다. 이중 원통형 구조는 전력밀도가 평판형 구조에 비해 다소 떨어지나 반응기체의 밀봉이 쉽고, 기계적 강도가 높으며, 열응력에 대한 저항성이 높아 스텍제작이 비교적 용이하며 장기 운전이 가능하다는 장점이 있으며, 평판형 구조의 경우는 전류의 흐름이 구성요소의 면에 수직방향으로 흐르므로 전력밀도가 높은 장점이 있으나 가스의 밀봉이 어렵고, 기계적 강도나 열응력에 대한 저항성이 높은 단점을 갖고 있다. 본 연구에서는 원통형 구조와 평판형 구조의 상호 장점을 보완하여 기존의 원통형의 구조를 최적화하여 개선한 연료극 지지체식 Flat-Tube형 고체산화물 연료전지의 제조와 특성에 대한 연구를 발표하고자 한다.

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기상증착법을 이용한 산화아연 나노로드의 성장 (Growth of ZnO nanorods by vapor-solid method)

  • 김나리;김재수;변동진;노대호;진정근;양재웅
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2003년도 추계학술발표강연 및 논문개요집
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    • pp.122-122
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    • 2003
  • In recent years, there has been increasing interest in quasi one-dimensional nanostructural systems, because of their numerous potential applications in various areas, such as materials sciences, electronics, optics, magnetism and energy storage. Specifically, zinc oxide (ZnO) is recognized as one of the most promising oxide semiconductor materials, because of its good optical, electrical, and piezoelectrical properties. The ZnO nanorods were synthesized using vapor-solid (VS) mechanism on soda lime glass substrate without the presence of metal catalyst. ZnO nanorods were prepared thermal evaporation of a Zn powder at 500. As-fabricated ZnO nanorods had an average diameter and length of 40nm and 3$\mu\textrm{m}$. Transmission electron microscopy revealed that the ZnO nanorods were single crystalline with the growth direction perpendicular to the (101) lattice plane. The influences of reaction time on the formation of the ZnO nanorods were investigated. The Photoluminescence measurements showed that the ZnO nanorods had a strong ultraviolet emission at around 380nm and a green emission at around 500nm.

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50W 고체 산화물 연료전지 시스템 구축 (Development of 50W Solid Oxide Fuel Cell system)

  • 지영석;나세윤;조구영;차석원
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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    • pp.311-314
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    • 2009
  • Recently by the development of the electronic engineering technology various mobile devices are developed. But their operation time need to be extended although capacity of the batteries are limited. We focused our attention to the portable SOFC system. Because SOFC has the high efficiency and a lot of strongness in comparison with other kinds of fuel cells, We evaluated hydrogen fed SOFC 50W system theoretically and got the results about the operating condition range from the comparison of the power efficiency, exhaust gas temperature, required heat for maintaining the operation temperature and operation time.

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산화물에서의 산소추적자확산계수를 결정하는 새로운 방법의 개발 II - 라만분광법에 의한 고체시료 중의 시간에 따른 $^{18}O$ 농도변화 측정 - (Development of Novel Techniques for Determining the Oxygen Tracer Diffusion Coefficients in Oxides II - Measurements of the Depth Profiles of $^{18}O$ Concentration in the solid Samples by Raman Spectroscopy)

  • 김병국;마하구찌히로오;박순자
    • 한국세라믹학회지
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    • 제31권12호
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    • pp.1459-1466
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    • 1994
  • A novel technique for determining the oxygen tracer diffusion coefficients in oxides was developed. After the 16O-18O solid-gas exchange reactions between 16O in the oxides and 18O in the ambient gas, Raman spectra of the cross sections of oxide samples were measured in a spatial resolution of 5 ${\mu}{\textrm}{m}$. From thus obtained Raman spectra, depth profiles of 18O concentration in the oxide samples were calculated. The oxygen tracer diffusion coefficients and the surface exchange coefficients were determined under the assumptions that samples are semi-infinite slab and that the surface exchange reactionsare not negligible. The oxygen tracer diffusion coefficient of 2.8 mol% Y2O3-containing tetragonal ZrO2 polycrystals, 8 mol% Y2O3-containing ZrO2 polycrystals, and 10 mol% Y2O3-containing cubic ZrO2 single crystals (along the a axis) are as follows.

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가스터빈과 고체산화물 연료전지를 결합한 가압형 하이브리드 시스템의 설계변수 해석 (Parametric Design Analysis of a Pressurized Hybrid System Combining Gas Turbine and Solid Oxide Fuel Cell)

  • 정영현;김동섭;김재환
    • 대한기계학회논문집B
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    • 제26권11호
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    • pp.1605-1612
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    • 2002
  • Thermodynamic performance analysis has been carried out for a hybrid electric power generation system combining a gas turbine and a solid oxide fuel cell and operating at over-atmospheric pressure. Performance characteristics with respect to main design parameters such as maximum temperature and pressure ratio are examined in detail. Effects of other important design parameters are investigated including fuel cell internal parameters such as fuel utilization factor, steam/carbon ratio and current density, and system parameters such as recuperator efficiency and compressor inlet temperature.

선박동력용 SOFC/GT 하이브리드시스템의 성능 및 안전성 해석 (터빈 냉각 및 TIT 일정 조건을 중심으로) (Performance and Safety Analysis of Marine Solid Oxide Fuel Cell and Gas Turbine Hybrid Power System (under Conditions of Turbine Cooling and Constant TIT))

  • 김명환
    • Journal of Advanced Marine Engineering and Technology
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    • 제33권4호
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    • pp.484-496
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    • 2009
  • The strengthened regulations for atmospheric emissions from ships like MARPOL Annex VI have caused a necessity of new, alternative power system in ships for the low pollutant emissions and the high energy efficiency. This paper attempts to investigate the configuration of SOFC/GT hybrid power system for LNG tanker taking into account the safety and to analyze the influence of design parameters on the system performance. The simulation results provide the basic data for the design and efficiency improvement of SOFC/GT hybrid system and indicate the guidelines for the safe system operation.

평판형 고체산화물 연료전지 제조 및 특성 연구 (Fabrication and Chacterization of Planar Solid Oxide Fuel Cell)

  • 송락현;이병록;김창수;신동열
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1996년도 하계학술대회 논문집 C
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    • pp.1700-1702
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    • 1996
  • Solid oxide fuel cell(SOFC) is an electrochemical energy device which converts the free energy of fuel gas directly to electric energy. SOFC has several diratinct advantages over other types of fuel cells: no use of noble metals, no requirement of a reformer, no problem of liquid electrolyte management, and no problem of corrosion by liquid electrolyte. In this study, we have investigated the cell components and the single cell of the planar SOFC fabricated by composite plate process, in which green films of electrolyte, anode and cathode were co-fired. The planar SOFCs were tested and the cell performance characteristics wag evaluated by using electrochemical methods.

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Effect of silver oxide additions on YBCO thick film properties

  • Soh, Dea-Wha;Li, Ying-Mei;Cho, Yong-Joon;Korobova, N.
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 추계학술대회 논문집 Vol.14 No.1
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    • pp.81-84
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    • 2001
  • The effect of silver oxide (14 wt.%) addition to YBCO compounds and electrophoretic deposition of composite particles prepared by solid phase reaction have been investigated. The results were compared with those for as-processed samples with YBCO films on Ag wire substrate. Our experiments show that the adhesion, microstructure changes, superconducting properties of these films is sensitive to the silver content and sintering conditions. Adding a small amount of PEG tends to remove cracks in the YBCO and (YBCO + Ag) films, which develop during the heating process. An attempt has been made to explain the experimental observations regarding variation of critical current density with the YBCO and (YBCO + Ag) films.

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