• Bulletin of the Korean Chemical Society
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• 제34권3호
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• pp.831-836
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• 2013

Platinized counter electrode is common in most of the dye sensitized solar cell (DSSC) researches because of its high catalytic activity and corrosion stability against iodine in the electrolyte. Platinum (Pt) film coating on fluorine doped tin oxide (FTO) glass surface by using alcoholic solution of hexachloroplatinic acid ($H_2PtCl_6$), paste containing Pt precursors or sputtering are widely used techniques. This paper presents a novel application of Pt ink containing nanoparticles for making platinized counter electrode for DSSC. The characteristics of Pt films coated on FTO glass surface by different chemical methods were compared along with the performance parameters of the DSSCs made by using the films as counter electrodes. The samples coated with Pt inks were sintered at $300^{\circ}C$ for 30 minutes whereas Pt-film and Pt-paste were sintered at $400^{\circ}C$ for 30 minutes. The Pt ink diluted in n-hexane was found to a promising candidate for the preparation of platinized counter electrode. The ink may also be applicable for DSSC on flexible substrates after optimization its sintering temperature.

• 천문학논총
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• 제18권1호
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• pp.25-35
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• 2003

In this paper, we have re-examined the relative sunspot numbers from June 1987 to December 2002 observed at Korea Astronomy Observatory. For this we determined conversion factors (K) for each year data to derive the relative sunspot numbers. The estimated conversion factor ranges from 0.57 to 1.09 and has a trend to decrease with time, which seem to depend on the several effects such as observational system, observation methods, and experience of an observer. Our analysis shows that the newly-determined relative sunspot numbers are in much better agreements with the international sunspot numbers than the previously-determined ones in which the conversion factors were determined only four times. This result implies that we should determine the conversion factor for each year data. From these investigations, we also identified one and half solar cycles form our relative sunspot number.

• 천문학회보
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• 제36권2호
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• pp.93.2-93.2
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• 2011

Japan Aerospace Exploration Agency (JAXA) has measured space environment and its effects on spacecraft and astronaut since 1987. At present, we have operated space environment monitors onboard one GEO spacecraft, one QZO spacecraft, and two LEO spacecrafts. The obtained space environment data has been gathered into the Space Environment and Effects System database (SEES, http://sees.tksc.jaxa.jp/). In this presentation, measurement result of space environment in low earth orbit obtained by the Daichi satellite from 2006 through 2011 is reported as well as recent activities in space environment engineerings in JAXA. The Technical Data Acquisition Equipment (TEDA) on board the Daichi satellite (Advanced Land Observing Satellite: ALOS) had been operated in low earth orbit at 700 km altitude with 98 degree inclination from February 2006 until April 2011. The TEDA consists of the Light Particle Telescope and the Heavy Ion Telescope. The operation period of the Daichi satellite was through the solar-activity minimum period. The space radiation environment around the Daichi satellite had been almost stable. However, large solar flares followed by CMEs sometimes disturbed the space radiation environment in the orbit of the Daichi satellite. In addition, high speed solar wind often flowed and modulated the electron flux in the horn region. On the other hand, a little variation was seen in the SAA region.

• 천문학회보
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• 제39권1호
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• pp.75.2-75.2
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• 2014

We have developed a set of daily solar flare peak flux forecast models using the multiple linear regression (MLR), the auto regression (AR), and artificial neural network (ANN) methods. We consider input parameters as solar activity data from January 1996 to December 2013 such as sunspot area, X-ray flare peak flux, weighted total flux $T_F=1{\times}F_C+10{\times}F_M+100{\times}F_X$ of previous day, mean flare rates of a given McIntosh sunspot group (Zpc), and a Mount Wilson magnetic classification. We compute the hitting rate that is defined as the fraction of the events whose absolute differences between the observed and predicted flare fluxes in a logarithm scale are ${\leq}$ 0.5. The best three parameters related to the observed flare peak flux are as follows: weighted total flare flux of previous day (r=0.5), Mount Wilson magnetic classification (r=0.33), and McIntosh sunspot group (r=0.3). The hitting rates of flares stronger than the M5 class, which is regarded to be significant for space weather forecast, are as follows: 30% for the auto regression method and 69% for the neural network method.

• Advances in environmental research
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• 제5권1호
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• pp.61-77
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• 2016

$NanoTiO_2$ was synthesized by ultrasonication assisted sol-gel process and subjected to iron doping and carbon-iron codoping. The synthesized catalysts were characterized by XRD, HR-SEM, EDX, UV-Vis absorption spectroscopy and BET specific surface area analysis. The average crystallite size of pure $TiO_2$ was in the range of 30 - 33 nm, and that of Fe-$TiO_2$ and C-Fe $TiO_2$ was in the range of 7 - 13 nm respectively. The specific surface area of the iron doped and carbon-iron codoped nanoparticles was around $105m^2/g$ and $91m^2/g$ respectively. The coupled semiconductor photo-Fenton's activity of the synthesized catalysts was evaluated by the degradation of a cationic dye (C.I. Basic blue 9) and an anionic dye (C.I. Acid orange 52) with concurrent investigation on the operating variables such as pH, catalyst dosage, oxidant concentration and initial pollutant concentration. The most efficient C-Fe codoped catalyst was found to effectively destruct synthetic dyes and potentially treat real textile effluent achieving 93.4% of COD removal under minimal solar intensity (35-40 kiloLUX). This reveals the practical applicability of the process for the treatment of real wastewater in both high and low insolation regimes.

• 한국수소및신에너지학회논문집
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• 제34권6호
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• pp.785-791
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• 2023

Copper sulfide (Cu_xS) has been extensively utilized as a counter electrode (CE) material for quantum dot solar cells (QDSCs) due to its exceptional catalytic activity for polysulfide electrolytes. The typical fabrication method of Cu₂S CEs based on brass substrate is dangerous, involving the use of a highly concentrated hydrochloric acid solution in a relatively high temperature. In contrast, electroplating presents a safer alternative by employing a less acidic solution at a room temperature. In addition, the electroplating method increases the probability of obtaining CEs of consistent quality compared to the brass method. In this study, the optimized electroplating cycle for CuS CEs in QDSCs has been studied for the highly efficient photovoltaic performances. The QDSCs, featuring electroplated CuS CEs, achieved an impressive efficiency of 7.18%, surpassing the conventional method employing brass CEs, which yielded an efficiency of 6.62%.

• Journal of Astronomy and Space Sciences
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• 제24권2호
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• pp.125-134
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• 2007

이 연구에서는 태양 및 지자기 활동에 의해 발생한 우주환경변화가 우리나라 위성인 아리랑위성1호(KOMPSAT-1)의 궤도에 미치는 영향을 분석하였다. 인공위성의 궤도변화는 정상적인 상태에서도 자연적인 섭동에 의해 지속적으로 발생하지만, 거대한 태양폭발에 의한 지구 주변 우주환경이 급격히 변화할 때 고층대기의 밀도변화로 인해 크게 발생한다. 특히 이러한 현상은 아리랑위성 1호와 같이 저궤도 상에서 운영되는 위성에 직접적인 영향을 미친다. 이 때, 태양활동에 의한 지구 주변 우주환경의 변화는 크게 두 가지로 구분할 수 있다. 하나는 태양 플레어 (Flare)가 폭발했을 때 고에너지 복사(Radiation)로 인해 지구 고층대기가 가열되어 팽창하고 이런 결과로 고층대기에 있는 중성입자밀도가 급격히 증가하는 것이다. 다른 하나는 코로나 물질 방출(Coronal Mass Ejections) 등에 의해 발생한 지자기폭풍기간 동안 플라즈마 대류와 입자들의 하강으로 전기장이 강해져 상당량의 줄가열(Joule heating)과 하강입자가열(precipitating particle heating)이 발생하고 이로 인해 중성입자밀도가 증가하는 것이다. 두 가지 원인에 대한 영향을 구분하여 알아보기 위해, 우리는 태양 및 지자기 자료를 면밀히 분석하여 2001년에서 2002년 동안 5개의 기간을 선정하였다. 그 결과 위성의 대기저항가속도는 태양의 극자외선(Extreme Ultra-Violet)의 증가와 함께 약 하루 정도의 시간 지연을 가지고 유사하게 변화하고 있음을 확인하였다(R=0.92). 그리고 지자기폭풍이 발생한 기간동안 대기저항가속도는 지자기폭풍에 의한 Dst 변화와 상당히 유사하게 그리고 거의 동시에 급격히 변화하는 것을 확인하였다. 마지막으로 우리는 위성의 대기저항가속도의 변화는 전반적으로는 오랜 기간 동안 고에너지 복사에 의한 효과로 나타나고 있으나 짧은 기간(하루 미만) 동안 크게 발생하는 대기저항가속도의 변화는 지자기폭풍에 의한 효과로 보고 있다.

• 천문학회보
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• 제38권2호
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• pp.94.1-94.1
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• 2013

Whistler mode chorus waves, which are observed outside the plasmasphere of the Earth's magnetosphere, play a major role in accelerating and scattering energetic electrons in the radiation belts. In this study we developed a predicting scheme of the global distribution of chorus by using the Time History of Events and Macroscale Interactions during Substorms (THEMIS) satellite data. First, we determined global spatial distributions of chorus activity, and identified fit functions that best represent chorus intensities in specific L-MLT zones. Second, we determined the specific dependence of average chorus intensity on preceding solar wind conditions (e.g., solar wind speed, IMF Bz, energy coupling degree) as well as preceding geomagnetic states (as represented by AE, for example). Finally, we combined these two results to develop the predicting functions for the global distribution and intensity of chorus. Implementing these results in the radiation belt models should improve the local acceleration effect by chorus waves.

• 한국물환경학회지
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• 제26권4호
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• pp.707-712
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• 2010

Nitrogen-doped $TiO_2$ particles have been successfully prepared using titanium tetraisopropoxide as the Ti source and urea as the nitrogen source. As-prepared nitrogen-doped $TiO_2$ was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer-Emmett-Teller method (BET) and ultraviolet-visible light (UV-vis) absorption spectra techniques. Photocatalytic degradation of Methylene Blue (MB) has been carried out in both solar light (UV-vis) and the visible region (${\lambda}=420nm$). Nitrogen-doped $TiO_2$ exhibits higher activity than the commercial $TiO_2$ photocalyst, particularly under visible-light irradiation because bandgap of nitrogen-doped $TiO_2$ becomes remarkably decreased.

• Journal of Astronomy and Space Sciences
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• 제37권3호
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• pp.165-170
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• 2020

Muons and neutrons are representative secondary particles that are generated by interactions between primary cosmic ray particles (mostly protons) and the nuclei of atmospheric gas compounds. Previous studies reported that muons experience seasonal variations because of the meteorological effects of temperature. The intensity of neutrons has a typical modulation with various periods and reasons, such as diurnal and solar variation or transient events. This paper reports that cosmic ray particles, which were observed by neutron monitors, have seasonal variations using the daily data at the Oulu neutron monitor. To eliminate the effects of solar activity across time, the daily data were normalized by two different transformations: transformations with respect to the grand mean and yearly mean. The data after transformation with respect to the yearly mean showed more statistical stability and clear seasonal variations. On the other hand, it is difficult to determine if the seasonal variation results from terrestrial effects, such as meteorological factors, or extraterrestrial effects, such as the position of the Earth in its orbit of revolution.