• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.04a
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• pp.77-82
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• 2004

Quantifying rates of microbial processes under subsurface conditions is difficult, and is most commonly approximated by laboratory studies using aquifer materials. In this study a single-well, 'push-pull' test method is adapted for the in situ determination of denitrification rates in groundwater aquifers. The rates of stepwise reduction of nitrate to nitrite, nitrous oxide, and molecular nitrogen were determined by performing a series of push-pull tests at an experimental well field of Korea University. A single Transport Test, one Biostimulation Test, and four Activity Tests were conducted for this study. Transport tests are conducted to evaluate the mobility of solutes used in subsequent tests. These included bromide (a conservative tracer), fumarate (a carbon and/or source), and nitrate (an electron acceptor). At this site, extraction phase breakthrough curves for all solutes were similar, indicating apparent conservative transport of the solutes prior to biostimulation. Biostimulation tests were conducted to stimulate the activity of indigenous heterotrophic denitrifyinc microorganisms. Biostimulation was detected by the simultaneous production of carbon dioxide and nitrite after each injection. Activity tests were conducted to quantify rates of nitrate, nitrite, and nitrous oxide reduction. Estimated zero-order degradation rates decreased in the order nitrate '||'&'||'gt; nitrite '||'&'||'gt; nitrous oxide. The series of push-pull tests developed and field tested in this study should prove useful for conducting rapid, low-cost feasibi1ity assessments for in situ denitrification in nitrate-contaminated aquifers.

• Journal of Soil and Groundwater Environment
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• v.18 no.3
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• pp.109-118
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• 2013

Characteristics of the transport of zero-valent iron nanoparticles (nZVI) in an aquifer were investigated to evaluate an application of nZVI-based reactive zone technology. Main flow direction of groundwater was north. Preferential flow paths of the groundwater identified by natural gradient tracer test were shown northeast and northwest. The highest groundwater velocity was $4.86{\times}10^{-5}$ m/s toward northwest. When the breakthrough curves obtained from the gravity injection of nZVI were compared with the tracer curves, the transport of nZVI was retarded and retardation factors were 1.17 and 1.34 at monitoring wells located on the northeast and northwest, respectively. The ratios of the amount of nZVI delivered to the amount of tracer delivered at the two wells mentioned above were 24 and 28 times greater than that of the well on the main flow direction, respectively. Attachment efficiency based on a filtration theory was $4.08{\times}10^{-2}$ along the northwest direction that was the main migration route of nZVI. Our results, compared to attachment efficiencies obtained in other studies, demonstrate that the mobility of nZVI was higher than that of results reported in previous studies, regardless of large iron particle sizes of the current study. Based on distribution of nZVI estimated by the attachment efficiency, it was found that nZVI present within 1.05 m from injection well could remove 99% of TCE within 6 months.

• Journal of Soil and Groundwater Environment
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• v.8 no.4
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• pp.12-20
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• 2003

This study presents a mathematical model for simulating the fate and transport of a reactive organic contaminant, TCE, degraded by cometabolism in dual-porosity soils during the installation of in situ biobarrier. To investigate the effect of dual-porosity on transport and biodegradation of organic hydrocarbons, a bimodal approach was incorporated into the model. Modified Monod kinetics and a microcolony concept were employed to represent the effects of biodegrading microbes on the transport and biodegradation of an organic contaminant. The effect of permeability reduction in biobarrier due to biomass accumulation on the flow field were examined in the simulation of a hypothetical field-scale in situ bioaugmentation. Simulation results indicate that the presence of the immobile region can decrease the bioavailability of biodegradable contaminants and that the placement of microbes and nutrients injection wells should be considered for an effective installation of biobarrier during in situ bioaugmentation scheme.

• Korean Journal of Soil Science and Fertilizer
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• v.45 no.6
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• pp.867-876
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• 2012

The concentration of veterinary antibiotics in aqueous and sediment matrices was measured in agricultural irrigation ditches bordering several animal-feeding operations (AFOs) and then compared to its concentration in the watershed. Analytical determination in aqueous samples was based on solid phase extraction (SPE) and appropriate buffer solutions were used to extract residuals in sediment samples. Separation and detection of extracted veterinary antibiotics were performed with high performance liquid chromatograph tandem mass spectrometry (HPLC/MS/MS). In general, higher concentrations of antibiotic were observed in the aqueous phase of irrigation ditches, with the highest concentration of erythromycin hydrochloride (ETM-$H_2O$) of $0.53{\mu}g\;L^{-1}$, than in aqueous watershed samples. In contrast, higher concentrations were measured in river sediment than in irrigation ditch sediment with the highest concentration of oxytetracycline of $110.9{\mu}g\;kg^{-1}$. There was a high calculated correlation ( > 0.95) between precipitation and measured concentration in aqueous samples from the irrigation ditches for five of the ten targeted veterinary antibiotics, indicating that surface runoff could be an important transport mechanism of veterinary antibiotics from field to environment. Further, environmental loading calculation based on measured concentrations in aqueous samples and flow information clearly showed that irrigation ditches were 18 times greater than river. This result suggests the likelihood that veterinary antibiotics can be transported via irrigation ditches to the watershed. The transport via surface runoff and likely environmental loading via irrigation ditches examined in this study helps identify the pathway of veterinary antibiotics residuals in the environment.

• Geotechnical Engineering
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• v.13 no.5
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• pp.155-168
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• 1997

The phenomena of detachment and movement of One particles are one of the important mechanisms both in geotechnical and geoenvironmental engineering. In geoenvironmental engineering, in particular, movement of fine particles may facilitate the transport of contaminants since the particle surfaces absorb contaminants before movement. Weathered granitic residual soils, which are the most abundant in Korea. contain large quantities of fine particles up to 50%. The characteristics of fine particle movement of weathered granitic residual soils are investigated in this paper. Samples are obtained from Poiiong, Shinnaedong in Seoul and Andong in Kyungpook : each of the samples represents typical residual soil types in Korea. Laboratory experiments for the three adopted soil types are performed. It is found that effluent concentration of the samples is influenced by porosity, fine particle percentage and particle size distribution. The critical velocity decreases as the fine particle percentage increases and the rate of change of erosion rate increases as the porosity increases. And well-graded samples showed less effluent concentrations compared to poorly-graded samples. The governing equation on the physical mechanism of fine particle movement and its nomerical solution scheme are suggested on the basis of the test results.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.04a
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• pp.188-191
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• 2003

Sing]e-well-push-pull tests were developed for use in assessing the feasibility of in-situ aerobic cometabolism of chlorinated aliphatic hydrocarbons (CAHs). The series includes Transport tests, Biostimulation tests, and Activity tests. Transport tests are conducted to evaluate the mobility of solutes used in subsequent tests. These included bromide or chloride (conservative tracers), propane (growth substrate), ethylene, propylene (CAH surrogates), dissolved oxygen (electron acceptor) and nitrate (a minor nutrient). Tests were conducted at an experimental well field of Oregon State University. At this site, extraction phase breakthrough curves for all solutes were similar, indicating apparent conservative transport of the dissolved gases and nitrate prior to biostimulation. Biostimulation tests were conducted to stimulate propane-utilizing activity of indigenous microorganisms and consisted of sequential injections of site groundwater containing dissolved propane and oxygen. Biostimulation was detected by the increase in rates of propane and oxygen utilization after each injection. Activity tests were conducted to quantify rates of substrate utilization and to confirm that CAH-transforming activity had been stimulated. In particular, the transformation of injected CAH surrogates ethylene and propylene to the cometabolic byproducts ethylene oxide and propylene oxide provided evidence that activity of the monooxygenase enzyme system, responsible for aerobic cometabolic transformations of CAHs had been stimulated. Estimated zero-order transformation rates decreased in the order propane > ethylene > propylene. The series of push-pu3l tests developed and field tested in this study should prove useful for conducting rapid, low-cost feasibility assessments for in situ aerobic cometabolism of CAHs.

• Journal of the Korean Geotechnical Society
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• v.15 no.5
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• pp.3-18
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• 1999

The geotextile filter, which is installed between the ground and the lining and used as a tunnel drainage system, should have sufficient groundwater drainage capacity so that water pressure does not act on the lining. The clogging may have a serious effect on the long term behaviour of geotextile filters. Two typical weathered residual soils in Korea, Shinnae-dong soil and Poi-dong soil, were chosen to investigate the in-plane flow characteristics of the soils with varying degree of compressive stresses applied on the geotextiles and with various conditions of hydraulic gradient. The Shinnae-dong soil is a relatively coarse material classified as'SW-SM'; on the other hand, the Poi-dong soil is much finer and is classified as'SC'. Based on the comparison of the $O_{95}$ of geotextile to the $D_{15}$ of residual soils, existing clogging criteria were reviewed, and a tentative clogging criterion for the in-plane flow of the residual soil through filters was proposed. The Shinnae-dong soil showed noticeable clogging phenomenon, while the clogging of the Poi-dong soil was not so serious. The Poi-dong soil seemed to be hindered in particle transport by its cohesiveness.

• Journal of the Korean Geosynthetics Society
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• v.11 no.1
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• pp.65-75
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• 2012

Since the modem reinforced soil wall technology was introduced in domestic civil engineering society in the year 1980, the reinforced soil walls have been extensively used because these technologies have advantages such as economical efficiency, graceful appearance, and easy construction. This paper describes the application of reinforced soil wall, design criteria, and construction problems. Many cases of troubles, which include a severe deformation of facing, cracks of facing block, overall sliding failure and so on, have been reported. Inappropriate design and construction management mainly induce these problems. The technological level of design and quantity control for reinforced soil wall is not sufficiently supported to cope with the growth quantity of reinforced soil wall construction market and the increasing number of construction companies. The unified standard design and construction criteria of reinforced soil wall should be established with the detail consideration of overall performance and stability. The quality control of design and construction, and cost of construction must be seriously executed to construct a high quality of reinforced soil wall.

• Journal of The Korean Society of Agricultural Engineers
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• v.53 no.1
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• pp.71-81
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• 2011

Due to increased human activities and intensive rainfall events in a watershed, soil erosion and sediment transport have been hot issues in many areas of the world. To evaluate soil erosion problems spatially and temporarily, many computer models have been developed and evaluated over the years. However, it would not be reasonable to apply the model to a watershed if topography and environment are different to some degrees. Also, source codes of these models are not always public for modification. The ArcGIS model builder provides ease-of-use interface to develop model by linking several processes and input/output data together. In addition, it would be much easier to modify/enhance the model developed by others. Thus, simple model was developed to decide soil erosion hot spot areas using ArcGIS model builder tool in this study. This tool was applied to a watershed to evaluate model performance. It was found that sediment yield was estimated to be 13.7 ton/ha/yr at the most severe soil erosion hot spot area in the study watershed. As shown in this study, the ArcGIS model builder is an efficient tool to develop simple models without professional programming abilities. The model, developed in this study, is available at http://www.EnvSys.co.kr/~sateec/toolbox for free download. This tool can be easily modified for further enhancement with simple operations within ArcGIS model builder interface. Although very simple soil erosion and sediment yield were developed using model builder and applied to study watershed for soil erosion hot spot area in this study. The approaches shown in this study provides insights for model development and code sharing for the researchers in the related areas.

• Journal of Radiation Protection and Research
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• v.28 no.3
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• pp.155-163
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• 2003

The groundwater flow and contaminant transport numerical models have been established for analyzing the movements of pollutants in subsurface soil at Daeduk site. The groundwater flow and concentration of U-234 using the numerical models were simulated around Daeduk nuclear facilities. The computed groundwater flow was mainly advected toward the direction of east and southeast around HANARO in the site. The radioactive material entered into the subsurface soil was transported along the same direction with groundwater flow. The radioactive material deposited on the surface from the calculated concentration distributions was not affected by surrounding environment of the site.