• Journal of Soil and Groundwater Environment
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• v.26 no.1
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• pp.1-7
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• 2021

Air-water interfacial area is of great importance for the analysis of contaminant mass transfer processes occurring in the soil systems. Capillary bundle model has been proposed to estimate the specific air-water interfacial areas in unsaturated soils. In this study, the measured air-water interfacial areas of a soil (loam) using the gaseous interfacial tracer technique were compared to those from capillary bundle model. The measured values converged to the specific solid surface area (7.6×104 ㎠/㎤) of the soil. However, the simulated air-water interfacial areas based on the capillary bundle model deviated significantly from those measured. The simulated values were substantially over-estimated at low end of the water content range, whereas the model under-estimated the air-water interfacial area for the most of the water content range. This under-estimation is considered to be caused by the nature of the capillary bundle model that replaces the soil pores with a bundle of glass capillaries and thus no surface roughness at the inner surface of the capillaries is taken into account for the estimation of the air-water interfacial area with the capillary bundle model. Subsequently, appropriate correction is necessary for the capillary bundle model to estimate the air-water interfacial area in soils. Since the soil-moisture release curve data is the basis of the capillary bundle model, the model can be of use due to its simplicity, while the gaseous tracer technique requires complicated experimental equipment followed by moment analysis of the breakthrough curves. The size distribution profile of the pores filled with gas estimated by the water retention curve was found to be similar to that of particle size at different size range. The shifted distribution of gas-filled pores toward smaller size side compared to the particle size distribution was also found.

• Journal of Soil and Groundwater Environment
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• v.19 no.5
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• pp.45-52
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• 2014

Torrefaction and hydrothermal carbonization (HTC) are productive methods to reclaim energy from lignocellulosic biomass. The hydrophobic, homogenized, energy dense and carbon rich solid fuel can be obtain from torrefaction and hydrothermal carbonization. Dead leaves were carbonized in a stainless steel reactor of volume 200 ml with torrefaction ($250-270^{\circ}C$) for 120 minutes and hydrothermal carbonization ($200-250^{\circ}C$) for 30 minutes, with mass yield solid fuel ranging from 57-70% and energy content from 16.81MJ/kg to 22.01 MJ/kg compare to the biomass. The char produced from torrefaction process possess high energy content than hydrothermal carbonization. The highest energy yield of 89.96% was obtained by torrefaction at $250^{\circ}C$. The energy densification ratio fluctuated in between 1.15 to 1.30. On the basis of pore size distribution of the chars, the definition of the International Union of Pure and Applied Chemistry (IUPAC) was used as a classification standard. The pore diameter was ranging within 11.09-19 nm which play important role in water holding capacity in soil. Larger pores can hold water and provide passage for small pores. Therefore, it can be concluded that high pore size char can be obtained my HTC process and high energy content char of 22.01 MJ/Kg with 34.04% increase in energy can be obtain by torrefaction process.

• Proceedings of the Korean Geotechical Society Conference
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• 2006.10a
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• pp.481-489
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• 2006

Two dimensional diffusion model test was conducted to investigate the sedimentation properties and consolidation process of reclaimed ground using dredging coarse soil which is composed of passing amount 20 percentage and 45 percentage of #200 sieve size respectively. The passing amount of #200 sieve size affected on sedimentation properties. The coarse soil which is passing amount of 20 percent showed that the sedimentation structure was layered type and passing amount of 45 percentage was wall-partition type according diffusion distance. Furthermore, the water content of surface and section, and distribution of fine soil were changed according to diffusion distance. and the change amount of pore water pressure and strength property when soil is diffused, segregated and accumulated can be applied efficiently in design of dredging and reclamation.

• Journal of the Korean Society of Environmental Restoration Technology
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• v.7 no.6
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• pp.39-48
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• 2004

The purpose of this paper was to confirm the application of the equation of the soil-water characteristic curve on an unsaturated soil. To this ends, a series of suction test was conducted on the selected 4 kinds of soil which is located in Korea, using the modified pressure extractor apparatus. And it was carried out to analyze the experimental parameters which can describe the soil-water characteristics, were determined by using the data obtained from the experiment. From the results, it was found that the matric suction was varied according to the grain size distribution, amount of fine grain particle and void ratio. Also it was found that the residual volumetric water content was decreased with the void ratio, but the index related air entry value, the soil parameter related water content and the parameter with residual water content were increased with the void ratio. And the application of equation of the soil-water characteristic curve was confirmed for the various conditions and the various state by the comparison between the volumetric water content measured by the experiment and the predicted values.

• Korean Journal of Soil Science and Fertilizer
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• v.40 no.3
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• pp.189-195
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• 2007

Using fractal dimensionality theory proposed by Riew and Sposito (1991), we attempted to analyze quantitatively the characteristics of porous distribution for built-in soils in the mini-lysimeter and artificial seed-bed media. The 2" stainless core soil samples were taken from lysimeter soils. Artificial seed-bed media were compacted in the acrylic core filled with raw materials consisted of cocopeat, zeolite and perlite. N (Constant number of partitioned group size smaller media volumes) and r (Self-similarity ratio) parameters consisting of fractal dimension D=log(N)/log(1/r) were obtained by Excel Programme using the Riew and Sposito's fractal model. The pore distribution of tested media was screened in pore size and its occurring frequency. The results reveal that the distribution range of pores is wider in the lysimeter soils than in the seed-bed media, while average size of pores in the media is smaller in lysimeter core soils than in seed-bed media.

• Nuclear Engineering and Technology
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• v.42 no.5
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• pp.562-567
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• 2010

A One-Dimensional Water Flow and Contaminant Transport in Unsaturated Zone (FTUNS) code has been developed in order to interpret radionuclide migration in an unsaturated zone. The pore-size distribution index (n) and the inverse of the air-entry value ($\alpha$) for an unsaturated zone were measured by KS M ISO 11275 method. The hydraulic parameters of the unsaturated soil are investigated by using soil from around a nuclear facility in Korea. The effect of hydraulic parameters on radionuclide migration in an unsaturated zone has been analyzed. The higher the value of the n-factor, the more the cobalt concentration was condensed. The larger the value of $\alpha$-factor, the faster the migration of cobalt was and the more aggregative the cobalt concentration was. Also, it was found that an effect on contaminant migration due to the pore-size distribution index (n) and the inverse of the air-entry value ($\alpha$) was minute. Meanwhile, migrations of cobalt and cesium are in inverse proportion to the Freundich isotherm coefficient. That is to say, the migration velocity of cobalt was about 8.35 times that of cesium. It was conclusively demonstrated that the Freundich isotherm coefficient was the most important factor for contaminant migration.

• Geomechanics and Engineering
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• v.18 no.1
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• pp.49-58
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• 2019

The effect of microstructure on the permeability of two saturated marine clays was studied through a series of falling head permeability tests and mercury intrusion porosimetry (MIP) tests. The key findings from this experimental study include the following results: (1) The permeability of undisturbed specimens is larger than that of reconstituted specimens at the same void ratio due to different soil fabrics, i.e., the pore size distributions (PSDs), even though they have the similar variation law in the permeability versus void ratio. (2) Different permeabilities of undisturbed and reconstituted specimens at the same void ratio are mainly caused by the difference in void ratio of macro-pores based on the MIP test results. (3) A high relevant relation between $C_k$ ($C_k$ is the permeability change index) and $e*_{10}$, can be found by normalizing the measured data both on undisturbed or reconstituted specimens. Hence, the reference void ratio $e*_{10}$, can be used as a reasonable parameter to identify the effect of soil fabric on the permeability of saturated soft clays.

• Journal of Soil and Groundwater Environment
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• v.7 no.3
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• pp.103-114
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• 2002

Knowledge of soil water retention characteristic is essential for many problems involving water flow and organic solute transport in unsaturated soils. A physico-empirical approach based on the translation of the particle-size distribution (PSD) into a corresponding water retention curve has been accomplished by others using the concept that the pore-size distribution is directly related to PSD. This approach implies that details of a PSD curve may affect the estimation of water retention characteristic (WRC). To determine whether the WRC estimation using the Arya-Paris model could be affected by the selection of a PSD model, four PSD models with one to four fitting parameters were used. The Jaky model with only one fitting parameter had greater WRC estimation ability than other models with greater number of fitting parameters. The better performance of the Jaky model may be explained by the effect of soil structure in field soils.

• Journal of Soil and Groundwater Environment
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• v.11 no.2
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• pp.13-21
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• 2006

Polycyclic aromatic hydrocarbons (PAHs) are widespread soil contaminants and major environmental concerns. PAHs have extremely low water solubility and are strongly sorbed to soil. A potential technology for remediation of PAHcontaminated soils is a soil washing with surfactant solutions. While the use of surfactants significantly enhances the performance of soil remediation, operation costs are increased. Selective adsorption of PAHs by activated carbons is proposed to reuse the surfactants in the soil-washing process. The adsorption isotherms of pure chemicals (Triton X-100 and phenanthrene) onto three granular activated carbons were obtained. The selective adsorption of phenanthrene in mixed solution was examined at various concentrations of phenanthrene and Triton X-100. The selectivity results were discussed with pore size distribution of activated carbons and molecular sizes of phenanthrene and the Triton X-100 monomer. The selectivity for phenanthrene was much larger than 1 regardless of the particle size of activated carbons. The selective adsorption using activated carbons with proper pore size distribution would greatly reduce the material cost for the soil washing process by the reuse of the surfactants.

• Journal of Ocean Engineering and Technology
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• v.20 no.4 s.71
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• pp.43-49
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• 2006

Detailed investigations were carried out on the stability of the dredged soil bed against wave actions, aimedat establishing the design method of artificial tidal flats using dredged soil. The soil was dredged at Nagoya port, Japan, and has a mean grain size of 0.013mm. Basic features of artificial dredged soil bed against wave actions were explained from a series of model experiments in a wave flume. The two types of section shapes were employed; one is a horizontal bed and the other is a sloped one. Changes of the bed profile, shear strength, grain size distribution and water content, according to the wave actions, were measured in detail. The cumulative effect of the wave actions, over about one week, was investigated. A dredged soil bed moves withthe wave actions with relatively small wave height. It should be especially. noted that the clay component is dissolved and flown out, away from the surface layer, and consequently the surface layer hardens, as if it is covered with sand. Wren the wave height is gradually increased, the bed is not liquefied and the shear strength of the dredged bed is increased by a wave-induced dissipation of pore pressures in the bed and a decrease of clay component by the wave-induced leakage.