• Title/Summary/Keyword: Soil Washing

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The Removal of Mixed Soil of Protein and Fat by Protease (프로테아제를 응용한 단백질과 지질 혼합오구의 제거)

  • Seong, Hye Yeong;Lee, Jeong Suk
    • Textile Coloration and Finishing
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    • v.13 no.2
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    • pp.18-18
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    • 2001
  • This study has examined the removal of mixed soil of protein and fat by protease. Cotton and PET fabrics were soiled by spotting of hemoglobin and triolein, respectively. The soiling order and soil concentration were changed in this procedure. The soiled fabrics were aged at 130℃ for 20 minutes. Protease was added in the alcohol ethoxylate(AE) detergent solution. The removal effciency was evaluated by analysis of protein and/or fat on the fabrics before and after washing, respectively. The detergency of PET fabrics was higher than that of cotton fabrics. The removal efficiency of hemoglobin was improved by protease from cotton and PET fabrics. Especially the removal efficiency of hemoglobin was remarkably improved from cotton fabrics. With the increase of hemoglobin and triolein (1:1) mixed soil, the removal of mixed soil was increased in proportion to mixed soil content up to a certain point. but it began to decrease above the point from cotton fabrics, while it was generally increased from PET fabrics. The detergency of total mixed soil from cotton fabrics was higher in case of soiling order with triolein after hemoglobin than in case of soiling order with triolein before hemoglobin. But the soiling order was not greatly effected in the detergency of total mixed soil from PET fabrics.

The Removal of Mixed Soil of Protein and Fat by Protease (프로테아제를 응용한 단백질과 지질 혼합오구의 제거)

  • 성혜영;이정숙
    • Textile Coloration and Finishing
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    • v.13 no.2
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    • pp.104-113
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    • 2001
  • This study has examined the removal of mixed soil of protein and fat by protease. Cotton and PET fabrics were soiled by spotting of hemoglobin and triolein, respectively. The soiling order and soil concentration were changed in this procedure. The soiled fabrics were aged at $130^\circ{C}$ for 20 minutes. Protease was added in the alcohol ethoxylate(AE) detergent solution. The removal effciency was evaluated by analysis of protein and/or fat on the fabrics before and after washing, respectively. The detergency of PET fabrics was higher than that of cotton fabrics. The removal efficiency of hemoglobin was improved by protease from cotton and PET fabrics. Especially the removal efficiency of hemoglobin was remarkably improved from cotton fabrics. With the increase of hemoglobin and triolein (1:1) mixed soil, the removal of mixed soil was increased in proportion to mixed soil content up to a certain point. but it began to decrease above the point from cotton fabrics, while it was generally increased from PET fabrics. The detergency of total mixed soil from cotton fabrics was higher in case of soiling order with triolein after hemoglobin than in case of soiling order with triolein before hemoglobin. But the soiling order was not greatly effected in the detergency of total mixed soil from PET fabrics.

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Determination of Soil Washing Condition for Light Hydrocarbon Contaminated Soils (Light Hydrocarbon에 오염된 토양의 용매추출조건에 관한 연구)

  • Hwang, Keon-Joong;Atalay, Asmare
    • Journal of Environmental Health Sciences
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    • v.23 no.4
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    • pp.82-90
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    • 1997
  • This study was conducted to establish an ideal condition for obtaining maximum extraction efficiencies using an array of soil types and under a wide variety of conditions. Nine characteristic compounds were studied: benzene, toluene, ethylbenzene, o-xylene, m-xylene, p-xylene, n-propylbenzene, 1,2,4-trimethylbenzene, and n-butylbenzene which were found in gasoline. Increasing the moisture content resulted in decreased recovery, and recovery of hydrocarbons from wet soils was significantly lower than from dry soils. For the batch extraction process, 4 hours of extraction time was sufficient to give optimum recovery of the contaminants. With methanol as an extraction solvent, maximum recovery time appeared to be reached quicker for BTEX components than with 2-propanol. The 2 to 1 ratio of solvent/soil was chosen as a compromise to provide for the indicated minimum solvent use and high extraction efficiency. The 0.4 mg/g soil contamination was adequate to show quantitative recovery. The percent recovery of BTEX was concentration dependent more than the semivolatile compounds. Methanol and 2-propanol consistently gave higher efficiency than water. Methanol was superior to 2-propanol in removing contaminants from silty clay loam soil. Using the most efficient extraction procedure, the average recovery of the light hydrocarbons from the three soils was 66 percent. Recoveries were also dependent on soil type, solvent type, extraction time, solvent amount, contaminant concentration, and compounds volatility. This study provided a useful screening technique for procedures that can be used to remediate soils contaminated with light hydrocarbons.

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Tephrochronology: Washing, Separation and Identification of Volcanic Glass Shard (테프라 연대학: 화산유리의 세척, 분리 및 감정)

  • Kil, Young-Woo;Cheong, Chang-Sik;Park, Se-Jin;Park, Myong-Ho
    • The Korean Journal of Petroleum Geology
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    • v.12 no.1
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    • pp.9-13
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    • 2006
  • Volcanic glass shard, which shows relatively homogeneous chemical composition in volcanic eruption materials, is used to determine ages of tephra layers and then to correlate tephra layers each other for understanding of evolution of Quaternary geomorphology. For reducing processing errors in age determination and correlation of units, amorphous glass shard should be separated carefully from soil sample through laboratory procedures such as washing, separation, and identification. Introduction of these processes in detail could be reduced errors in tephrochronology by using volcanic glass shard.

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High-Performance Liquid Chromatographic Determination of Tricyclazole Residues in Rice Grain, Rice Straw, and Soil

  • Lee, Young-Deuk;Lee, Jung-Hun
    • Applied Biological Chemistry
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    • v.41 no.8
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    • pp.595-599
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    • 1998
  • An analytical method was developed to determine tricyclazole residues in rice grain, straw, and soil using high-performance liquid chromatography (HPLC) with ultraviolet absorption detection. Tricyclazole was extracted with methanol from moist rice grain, straw, and soil samples. n-Hexane washing was employed to remove nonpolar co-extractives during liquid-liquid partition. Tricyclazole was then extracted with dichloromethane from alkaline aqueous phase, while acidic interferences remained in the phase. Dichloromethane extract was further purified by silica gel column chromatography prior to HPLC determination. Reverse-phase HPLC using an octadecylsilyl column was successfully applied to separate and quantitate the tricyclazole residue in sample extracts monitored at ${\lambda}_{max}$ 225nm. Recoveries from fortified samples averaged $95.5{\pm}3.0%\;(n=6),\;87.5{\pm}20.%\;(n=6),\;and\;84.3{\pm}2.8%$ (n=12) for rice grain, straw, and soil, respectively. Detection limit of the method was 0.02 mg/kg for rice grain and soil samples while 0.05 mg/kg for rice straw samples. The proposed method was reproducible and sensitive enough to evaluate the safety of tricyclazole residues in rice grain, straw, and soil.

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A study on the removal of triglyceride from cotton fabric (면포에서 Triglyceride 단독 오염의 세척성에 관한 연구)

  • 곽혜원
    • Journal of the Korean Home Economics Association
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    • v.23 no.1
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    • pp.19-24
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    • 1985
  • The effect of temperature, washing time, mechanical agitation and concentration on the removal from cotton fabrics of tripalmitin labelled with C\sup 14\ were studied. In order to correlate the detergency with the removal mechanism, solubilization and suspending power of surfactants were observed. RESULTS : 1. The detergency from cotton fabric was increased with elevating temperature and over the temperature of maximum detergency, the rate of soil removal was rather decreased. 2. The effects of washing time and mechanical agitation on the removal of triplamitin were obvious at lower temperature. 3. The removal of tripalmitin was remarkably increased at higher concentration over cmc for all surfactants. The detergency of nonionic surfactant -NPPG- was best, this was resulted from its large solubilization and suspending power.

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STUDIES ON THE I LABELLING OF CASTOR OIL, AND THE DETERGENCY OF SODIUM DODECYL SULFATE

  • Heo, Yong-Cheol;Mun, Byeong-Yeol;Kim, Yeong-Guk
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.10 no.1
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    • pp.42-48
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    • 1984
  • The comparative detergency of Sodium dodecyl sulfate (SDS) solution near the first critical micelle concentration (CMC) was measured by means of a 131 I-labelled castor oil as a soil. More than 95% radiochemical purity of 131 I-labelled castor oil was obtained using potassium lidide as a carrier. Polyester test fabric was soiled with 131 I-labelled castor oil, and washed in a conventional washing apparatus mounted on appropriate devices. Fabric radioactivities were measured before and after washing by a scintilation counter. Near the first CMC, the detergency of SDS was increased with decreasing of surface tension of SDS. It was also shown that 131 I-labelled castor oil was useful for studying the detergency of SDS.

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A Study on Remediation Method of Diesel-Contaminated Railroad Soil using $TiO_2$-MMT ($TiO_2$-MMT를 이용한 디젤오염 철도토양의 개선방안에 관한 연구)

  • Yang, Young-Min;Huh, Hyun-Sue;Lee, Jae-Young;Lee, Cheul-Kyu;Jeon, Yu-Mi
    • Proceedings of the KSR Conference
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    • 2011.10a
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    • pp.2870-2874
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    • 2011
  • Soil pollution around railroad has been occurred mainly by diesel and lubricant oil, which is difficult to treat due to high carbon number. In this study, we investigated the feasibility of inorganic-inorganic nanohybrid photo-catalyst for the remediation of diesel-contaminated railroad soil. Generally, the $TiO_2$ nanoparticle easily removes organic pollutants due to photo and natural clay of layer structure. Also, montmorillonite (MMT) have an excellent absorption property with organic component. So, we prepared $TiO_2$ pillared MMT nanohybrid photo-catalyst as a chemical oxidant through the integration of theses advantage. As a result, the removal efficiency of diesel was more than 45% at a laboratory-scale test with diesel concentration and the amount of $TiO_2$-MMT. In future, we will improve the removal efficiency of diesel to optimize experimental parameters and apply the field soil The remediation method using photo-catalyst can be used to clean up the railroad soil polluted with high concentration instead of common methods such as soil washing, bioremediation, etc..

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Remediation for Hydrophobic Organic Compound Contaminated Soils by Surfactant Solution (계면활성제 용액을 이용한 소수성 유기화합물로 오염된 토양의 정화)

  • 윤현석;박민균;권오정;박준범
    • Proceedings of the Korean Geotechical Society Conference
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    • 1999.03a
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    • pp.543-550
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    • 1999
  • Hazardous substances produced from industrial sectors have caused serious contamination of soils and groundwater. The hydrophobic organic compounds in the subsurface are hard to be decomposed, and as they soil on the soil or last as a NAPL they might contaminate the groundwater for a long time. Although we recognize the danger of contaminated subsurface, very little was known about the effective remediation technique. This paper focuses on the remediation of the p-Cresol which contaminated subsurface by applying the surfactant-enhanced description technique. Sorption characteristics of soils and organic compounds are studied, and the applications of surfactant solution are studied for effective rededication. The results from this study could be used as some data for surfactant-enhanced rededication. The flexible-wall permeameter tests are performed in which in-situ remediation is simulated. Results show that triton X-100 at 2% solution disrobes p-Cresol 1.7 times as much as water description in the flexible-wall permeameter tests.

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Analysis of the Extracted Non-fibrous Matters from the Exhumed Textiles of Milchang-gun Burial of Mapo (마포 밀창군 묘 출토 복식유물의 섬유외 물질의 추출분석)

  • 안춘순
    • The Research Journal of the Costume Culture
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    • v.11 no.6
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    • pp.902-912
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    • 2003
  • The purpose of this research was two-folds; first, to investigate the type of soil contaminated in the Hunsang excavated from the Milchang-gun burial of Mapo for the purpose of proposing the adequate washing method, second, to utilize the chemical degradation result obtained from the previous research to identify the natural dye source used in the Hunsang textile. The application of KS K0251 test showed that the soil was more oleophilic than hydrophilic thus indicating that wet cleaning was more adequate that dry cleaning for the removal of Hunsang soil. The GC-MS result of the Hunsang extraction showed dimethyl phthalate and 2,4-di-tert-butylphenol as its degradation product and these coincided with the degradation products from the alizarin standard data of previous research. The comparison of the two suggested that it is likely that Hunsang was dyed with madder which has alizarin as its major chromophore.

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