• 제목/요약/키워드: Soil Chemical Concentrations

검색결과 509건 처리시간 0.025초

黃砂現象의 大氣汚染物質 動態에 關한 硏究 (Dynamics of Air Pollutants during the Yellow Sand Phenomena)

  • 李敏熙;黃奎浩;金恩植;平井英二;丁子哲治;宮崎元一
    • 한국대기환경학회지
    • /
    • 제6권2호
    • /
    • pp.183-191
    • /
    • 1990
  • To check the possible transportation of gaseous air pollutants with the particles of yellow sand in the movement of air masses during the Yellow Sand Phenomenon, the concentrations of such air pollutants as TSP, $SO_2, CO, NO_x, O_3 and N-CH_4$, and wind wpeed were measured during the Yellow Sand Phenomenon (April 8 $\sim 10, 1990) and they were compared with those during the normal times in Korea. Meanwhile dust color of the samples during the Yellow Sand Phenomenon was the color of sand, that during the normal times was dark-brown. The concentrations of dusts; water soluble components, and metallic components of soil-originated elements during the Yellow Sand Phenomenon were higher than those during the normal times. While the metallic components in the dusts during the Yellow Sand Phenomenon were from soil-originated elements, those during the normal times were of both soiloriginated and sea-originated elements. The change of hourly concentrations of air pollutants showed bi-modal distribution during the two periods. Generally, the concentration levels of air pollutants during the Yellow Sand Period were higher than those during the normal times. Although similarity was observed in the primary sources, differences were observed in the dynamics of the secondary sources due to chemical reactions of the air pollutants during the two periods.

  • PDF

Complexation of Cadmium(II) with Soil Fulvic Acid

  • Me Hae Lee;Se Young Choi;Hichung Moon
    • Bulletin of the Korean Chemical Society
    • /
    • 제14권4호
    • /
    • pp.453-457
    • /
    • 1993
  • Cadmium(II) complexation by a well characterized soil fulvic acid (FA) from the Okchun Metamorphic Belt were studied at pH of 6.0 in 0.1 M $NaClO_4$ using the ultrafiltration technique. The conditional stability constants thus obtained were log K= 3.90${\pm}$0.15 and 3.99${\pm}$0.12 $L{\cdot}mol^{-1}$ at fulvic acid concentrations of 101 and 226 mg${\cdot}L^{-1}$ respectively. When free cadmium ion concentration was measured directly using an ion selective electrode, log K of 4.12${\pm}$0.03 $L{\cdot}mol^{-1}$ was obtained. These results show that fulvic acid forms predominately 1 : 1 complex with $Cd^{2+}$ ions. The maximum binding ability of this polyelectrolyte material was 0.886 mmol Cd/g FA. The average gram formula weight of fulvic acid was estimated to be 1130 daltons.

Seasonal changes in soil acidity and related properties in ginseng artificial bed soils under a plastic shade

  • You, Jiangfeng;Liu, Xing;Zhang, Bo;Xie, Zhongkai;Hou, Zhiguang;Yang, Zhenming
    • Journal of Ginseng Research
    • /
    • 제39권1호
    • /
    • pp.81-88
    • /
    • 2015
  • Background: In Changbai Mountains, Panax ginseng (ginseng) was cultivated in a mixture of the humus and albic horizons of albic luvisol in a raised garden with plastic shade. This study aimed to evaluate the impact of ginseng planting on soil characteristics. Methods: The mixed-bed soils were seasonally collected at intervals of 0-5 cm, 5-10 cm, and 10-15 cm for different-aged ginsengs. Soil physico-chemical characteristics were studied using general methods. Aluminum was extracted from the soil solids with $NH_4Cl $(exchangeable Al) and Na-pyrophosphate (organic Al) and was measured with an atomic absorption spectrophotometer. Results: A remarkable decrease in the pH, concentrations of exchangeable calcium, $NH_4^+$, total organic carbon (TOC), and organic Al, as well as a pronounced increase in the bulk density were observed in the different-aged ginseng soils from one spring to the next. The decrease in pH in the ginseng soils was positively correlated with the $NH_4^+$ (r=0.463, p<0.01), exchangeable calcium (r=0.325, p<0.01) and TOC (r= 0.292, p < 0.05) concentrations. The $NO_3^-$ showed remarkable surface accumulation (0-5 cm) in the summer and even more in the autumn but declined considerably the next spring. The exchangeable Al fluctuated from $0.10mg\;g^{-1}$ to $0.50mg\;g^{-1}$ for dry soils, which was positively correlated with the $NO_3^-$ (r=0.401, p < 0.01) and negatively correlated with the TOC (r=-0.329, p < 0.05). The Al saturation varied from 10% to 41% and was higher in the summer and autumn, especially in the 0-5 cmand 5-10 cm layers. Conclusion: Taken together, our study revealed a seasonal shift in soil characteristics in ginseng beds with plastic shade.

Effect of 16 different (N, P combination) fertilizer treatments on the growth of Liriodendron tulipifera seedlings and soil chemical properties in the Nursery Station

  • Jung Won Park;Woo Bin Youn;Byung Bae Park;Min Seok Cho
    • 농업과학연구
    • /
    • 제50권2호
    • /
    • pp.181-192
    • /
    • 2023
  • Appropriate fertilization methods are required according to species to supply necessary nutrients to plants and prevent soil environmental contamination in nurseries. In this study, the effects of nitrogen and phosphorus fertilization on the growth of Liriodendron tulipifera and soil characteristics were investigated. After 16 fertilization treatments (4 levels of nitrogen × 4 levels of phosphorus) were applied to one-year-old L. tulipifera seedlings at the Yongmun Nursery Station of the Korea Forest Service, height, root collar diameter (RCD), biomass, leaf nutrients, and soil characteristics were investigated. The height increased as the amount of nitrogen and phosphorus fertilization increased, and the RCD was the highest in the ×2 treatment. Biomass growth was on average 40.0% higher for the treatment with high nitrogen fertilization compared to the low nitrogen treatment. The seedling quality index was the highest with nitrogen and phosphorus ×2 treatment. Leaf phosphorus and magnesium concentrations decreased when nitrogen fertilization was applied, and leaf potassium concentrations decreased as nitrogen fertilization increased. Soil pH and exchangeable potassium decreased as the amount of phosphorus application increased, and exchangeable magnesium decreased as the amount of nitrogen application increased and increased as the amount of phosphorus application increased. Considering the growth of L. tulipifera seedlings and changes in the soil characteristics at the nursery stage, twice the standard fertilization amount is the appropriate fertilization amount for nursery of the Yongmun Nursery Station. It is expected that this study will contribute to improving nursery soil fertilization management technology for healthy seedling production.

나트륨 농도가 2년생 인삼의 생육, 생리장해 및 상토의 화학적 특성에 미치는 영향 (Influence of Sodium Concentrations on Growth, Physiological Disorder Symptoms, and Bed Soil Chemical Properties of 2-Year-Old Ginseng)

  • 유진;서수정;장인배;장인복;문지원;권기범;이성우
    • 한국약용작물학회지
    • /
    • 제26권3호
    • /
    • pp.240-247
    • /
    • 2018
  • Background: Saline soil has negative effects on the growth of most crops. Sodium is the main element that causes salt accumulation in soil. Organic materials such as cow and poultry manure, are frequently used during the preparation stage, which causes an increase in the rate of salt accumulation in the soil. Methods and Results: To investigate the influences of sodium on ginseng, $NaH_2PO_4$, $Na_2SO_4$, and NaCl were used to adjust the sodium concentrations at 0, 12.5, 25, 50, 75 and 100 mM in nutrient solution. In a 2-year-old ginseng, toxic symptoms appeared when the sodium treatment exceeded 50 mM. The sodium concentration in the leaves was 3.33%, which is more than twice as high as that of the control treated at 50 mM. As the sodium concentration increased, the root weight significantly decreased. In the 100 mM treatment, the weight decreased by 28% when compared to that of the control. The Amount of ginsenoside significantly increased with an increase in sodium concentrations. Conclusions: These results suggest that the growth of 2-year-old ginseng is negatively affected when sodium exceeds 50 mM. This result can be used for a as basis in diagnosing the physiological disorders of ginseng.

코이어 더스트 혼합상토에 용과린의 시비수준에 의한 적축면 상추의 생장과 근권부 화학성 변화 (Growth of Red-leaf Lettuce and Changes in Soil Solution Chemical Properties of Coir-dust Containing Root Media Influenced by Application Rates of Pre-planting Fused-Superphosphate)

  • 김창현;최종명;이동훈
    • 원예과학기술지
    • /
    • 제33권5호
    • /
    • pp.658-667
    • /
    • 2015
  • 코이어 더스트(coir-dust, CD)와 팽연왕겨(expanded rice hull, ERH), 훈탄(carbonized rice hull, CRH), 및 분쇄수피(ground pine bark, GRPB)를 혼합하여 조제한 CD+ERH(8:2, v/v), CD+CRH(6:4) 및 CD+GRPB(6:4)의 세 종류 혼합상토에 기비로 혼합된 용과린의 시비수준이 적축면 상추의 생장과 근권부 화학성 변화에 미치는 영향을 구명하기 위하여 본 연구를 수행하였다. 용과린을 $0.0-6.0g{\cdot}L^{-1}$까지 $1.5g{\cdot}L^{-1}$씩 시비수준의 차이를 두어 상토에 혼합한 후 본엽 3매인 적축면 상추를 정식하고 5주간 태양광 병용형 식물공장에서 재배하였다. 매주 1회 중성비료를 $100mg{\cdot}L^{-1}$으로 농도를 조절하여 포트당 150mL씩 공급하였고, 시비 30분 후 포트 하단부에서 토양수를 추출하여 근권부 pH, EC 및 무기이온 농도 변화를 분석하였으며, 정식 5주 후에 지상부 생장을 조사하였다. 적축면 상추는 CD+CRH 보다 CD+ERH와 CD+GRPB에서 지상부 생장량이 많았고, 각 상토에서 용과린 시비수준이 높을수록 지상부 생장량이 많은 경향이었다. 정식 3주 이후 CRH를 포함한 상토의 근권부 pH는 4.0-4.8, $PO_4{^{3-}}$ 농도는 $20-100mg{\cdot}L^{-1}$ 범위로 분석되었는데 이는 ERH와 GRPB를 포함한 혼합상토 보다 pH는 낮고 $PO_4{^{3-}}$ 농도는 높은 결과이다. 용과린의 시비수준이 높을수록 세 종류 상토의 토양용액 $Ca^{2+}$, $Mg^{2+}$, $SO_4{^{2-}}$ 농도가 높았지는 경향이었으며, CD+CRH에서 다른 혼합상토보다 $K^+$ 농도가 높았다. 재배기간이 경과함에 따라 세 종류 상토의 $NO_3$-N 농도가 높아졌으며, $NO_3$-N 농도가 높을 때 토양용액 EC도 상승하는 경향을 나타냈다. 이상의 결과를 종합하면 식물공장에서 적축면 상추를 재배하기 위해 적합한 혼합상토는 CD+ERH와 CD+GRPB 였고, 기비로 혼합되는 용과린의 적정 시비 수준은 $4.5-6.0g{\cdot}L^{-1}$의 범위라고 판단하였다.

대전시 가로수 식재지 토양의 화학적 특성에 관한 연구 (A study on chemical properties of soil in roadside trees of Daejeon city)

  • 고소현;박관수;강길남;방병욱;김동일
    • 농업과학연구
    • /
    • 제32권1호
    • /
    • pp.1-8
    • /
    • 2005
  • 본 연구는 교통량이 가로수 식재지 토양의 화학적 특성에 미치는 영향을 파악하기 위하여 실시되었다. 이를 위해 대전시에 위치한 은행나무와 양버즘나무 가로수 주변 토양의 화학적 특성을 조사 분석하였다. 교통량이 많은 지역의 토양 pH는 7.0 내외로 높게 나타났으며, 이는 제설용으로 살포되고 있는 염화칼슘이나 콘크리트로부터 용해되어 흘러나오는 알칼리성분 및 염기성 분진 때문으로 사료된다. 토양 중 Fe, Cd, Cu, Zn, 그리고 Pb 농도는 충남대학교 지역에서 보다 교통량이 많은 대전역전과 대화공단지역에서 높게 나타났다. 이와 같은 결과는 자동차의 타이어 및 부품의 합금 등으로 이용된 물질들이 도로 주행 시 마찰 또는 마모되어 도로주변으로 배출되었기 때문으로 사료된다.

  • PDF

중국 길림성 백성지역 흑개토의 이화학성 및 인산 흡착 특성 (Physical-chemical Properties and Phosphorus Adsorption Characteristics of Soils in Baicheng, China)

  • 김성애;이상모;최우정;류순호
    • Applied Biological Chemistry
    • /
    • 제44권2호
    • /
    • pp.92-96
    • /
    • 2001
  • 농경지로의 개발 가능성이 높은 중국 길림성 백성지역의 주요한 토양인 흑개토의 이화학성 및 인산 흡착특성을 조사하였다. 토지 이용방식 또는 재배작물이 서로 다른 중국 길림성 백성지역 4곳과 중국 용정에 위치한 연변 대학교 농과대학 부속 시험장 1곳에서 1993년 8월에 토양을 채취하여 실험을 수행하였다, 중국 길림성 백성지역 토양의 $_PH$는 미경작지 10.2, 경작지는 $7.3{\sim}7.6$으로 비교적 높았다. 양이온 치환용량은 20 cmol(+) $kg^{-1}$ 이상이었으며, 치환성 양이온 중 Na는 특히 표토에 많이 존재하였으며, Ca의 함량이 매우 높아 Ca 포화율이 100% 이상을 나타내었다. 토양 포화 침출액의 주요 양이온은 Na이었으며, ECe와 SAR을 기준으로 백성 미경작지 토양은 염류-나트륨성 토양, 경작지 토양은 나트륨성 또는 일반 토양에 해당하였다. 백성지역 토양의 유효인산 함량은 10mg P $kg^{-1}$ 미만으로 아주 낮았으며, 최대 인산흡착량은 $ $ mg P $kg^{-1}$이었다. 길림성 백성지역 토양의 경우 유효인산 함량이 매우 낮아 토양 비옥도 중진을 위한 인산질 비료의 시용과 함께 토양 투수성의 개선 등과 같은 적절한 토양 관리가 필요하며, 용정지역 토양의 경우에는 인산흡착 특성을 고려하여 인의 과잉 축적을 방지하기 위한 인산질 비료의 적정 시용을 권장하여야 한다.

  • PDF

폐광산지역 경작지 토양의 중금속 존재형태와 토양오염평가 (Fraction and Soil Pollution Assesment Index of heavy metals in cultivated land soils near the abandoned mine)

  • 김휘중;양재의;이재영;최상일;전상호
    • 한국지하수토양환경학회지:지하수토양환경
    • /
    • 제8권4호
    • /
    • pp.53-63
    • /
    • 2003
  • 연구의 목적은 옥동천 유역 토양의 중금속의 존재형태와 존재형태에 따른 중금속의 오염지수를 산정하는데 있다. 토양채취는 경작지 토양을 대상으로 하였고 토양은 물리적 특성과 이화학적 특성을 분석하였다. 그 결과 경작지 토양의 pH는 5.2에서 7.6을, 총질소 함량과 loss on ignition은 각각 0.6∼2.5%, 1.9∼12.9%를 나타냈다. 경작지 토양의 중금속 농도는 폐광된 탄광지역의 논토양에서 높게 나타났으며, 총 중금속의 농도는 Zn > Pb > Ni > Cu > Cd 순으로 나타났다. 이러한 결과는 토양환경기준치와 비오염 경작지 토양의 중금속 농도 보다 높게 나타나는 경향을 보였으며, 총 중금속 중 일부분이 이동 가능성이 있는 부분으로 나타났다. 토양오염 평가지수(SPAI)는 조사지 토양에서 Non polluted와 Moderately polluted를 나타냈으며, 이러한 결과는 비 이동성 형태보다는 이동성 형태의 값이 났게 나타났다. 경작지 토양에서 중금속 존재형태와 SPAI 값은 중금속에 의한 오염과 식물체에 미치는 잠재적인 유해한 결과를 얻을수 있다. 따라서 결과에서 보여진 폐탄광지역의 토양을 복원하기 위해서 신속한 대책이 필요하다.

Geological Distribution and Background Level of Copper and Zinc in Non-drinking Groundwater, South Korea

  • Jeon, Sang-Ho;Park, Sunhwa;Kim, Hyun-Koo;Song, Da-Hee;Kim, Hye-Jin;Kim, Moon-su;Kim, Deok-hyun;Lee, Gyeong-Mi;Kim, Tae-seung
    • 한국토양비료학회지
    • /
    • 제49권2호
    • /
    • pp.200-207
    • /
    • 2016
  • To add new groundwater standard, 7 candidate materials (copper, zinc, selenium, manganese, iron, chromium, aluminum) were calculated by CROWN (Chemical Ranking Of groundwater pollutaNts). Copper and zinc were selected as groundwater candidates through the process and monitored total 430 samples for 2 years with 113 groundwater sampling sites. In this study, geological distribution characteristics (igneous rock, metamorphic rock, sedimentary rock) of copper and zinc were evaluated and the geological background levels obtained by a cumulative probability distribution and pre-selection methods were compared. In the results, the highest average concentrations of the copper and zinc were observed both in the igneous rock. The detection concentration ranges of copper and zinc in 430 groundwater samples were $0.002{\sim}0.931mg\;L^{-1}$, and $0.002{\sim}32.293mg\;L^{-1}$, respectively. In addition, detection concentration ranges of copper and zinc were $0.002{\sim}0.931mg\;L^{-1}$, $0.002{\sim}32.293mg\;L^{-1}$ in the igneous rock, $0.002{\sim}0.134mg\;L^{-1}$, $0.004{\sim}7.038mg\;L^{-1}$ in the metamorphic rock and $0.002{\sim}0.008mg\;L^{-1}$, $0.003{\sim}3.948mg\;L^{-1}$ in the sedimentary rock, respectively. As a result of the background concentrations with two methods, zinc concentrations with the pre-selected method are comparatively higher than that of the others with the cumulative distribution.