• Title/Summary/Keyword: Soil Chemical Concentrations

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Individual and combined effect of Portland cement and chemical agents on unconfined compressive strength for high plasticity clayey soils

  • Yilmaz, Yuksel;Eun, Jongwan;Goren, Aysegul
    • Geomechanics and Engineering
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    • v.16 no.4
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    • pp.375-384
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    • 2018
  • Unconfined compressive strength (UCS) of high plasticity clayey soil mixed with 5 and 10 % of Portland cement and four chemical agents such as sodium hexametaphosphate, aluminum sulfate, sodium carbonate, and sodium silicate with 0, 5, 10, and 20% concentrations was comparatively evaluated. The individual and combined effects of the cement and chemical agents on the UCS of the soil mixture were investigated. The strength of the soil-cement mixture generally increases with increasing the cement content. However, if the chemical agent is added to the mixture, the strength of the cement-chemical agent-soil mixture tends to vary depending on the type and the amount of the chemical agent. At low concentrations of 5% of aluminum sulfate and 5% and 10% of sodium carbonate, the average UCS of the cement-chemical agent-soil mixture slightly increased compared to pure clay due to increasing the flocculation of the clay in the mixture. However, at high concentrations (20%) of all chemical agents, the UCS significantly decreased compared to the pure clay and clay-cement mixtures. In the case of high cement content, the rate of UCS reduction is the highest among all cement-chemical agent-soil mixtures, which is more than three times higher in comparison to the soil-chemical agent mixtures without cement. Therefore, in the mixture with high cement (> 10%), the reduction of the USC is very sensitive when the chemical agent is added.

Long-Term Investigation of Regional Topographic Effects on Soil Chemical Properties and Heavy Metal Concentrations in Paddy Fields

  • Ahn, Byung-Koo;Kang, Seong-Soo;Shin, Jae-Yeon;Lee, Jin-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.5
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    • pp.738-743
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    • 2012
  • Topographic conditions of agricultural fields work as a important factor to identify different soil properties. This study was conducted to investigate the selected soil chemical properties and the concentrations of heavy metals, Cd, Cr, Pb, Cu, Ni, and Zn, in the paddy fields of different topographic areas at four year intervals from 1999 to 2011. Three-hundred soil sampling sites in the paddy fields were selected from the different topographic areas that were local valley and fans, fluvio-marine deposits, alluvial plains, and diluvial terraces. The mean values of soil pH ranged 5.7~5.8 that were within optimal range for rice cultivation. The mean values of other properties such as soil organic matter (SOM) content, the concentrations of exchangeable cations, $K^+$, $Ca^{2+}$, and $Mg^{2+}$, and available silicate concentration were lower or close to the optimal values, but the mean concentrations of available phosphorus were exceeded the range of optimal value, $80{\sim}120mg\;kg^{-1}$, in many paddy fields. In particular, The concentrations of available phosphorus in the paddy fields of local valley and fans, alluvial plains, and fluvio-marine plains were mostly declined. However, in diluvial terrace areas, the phosphorus concentrations unexpectedly increased; furthermore, they were significantly higher than those in other topographic areas. The mean concentrations of 0.1 M HCl-extractable heavy metals, Cd, Cr, Pb, Cu, Ni, and Zn, in the paddy fields were slightly and gradually declined during the study years, but the Pb concentrations were not statistically changed. In addition, the concentrations of heavy metals were widely ranged depending on the different sampling sites. Nevertheless, the concentrations of heavy metals were significantly lower than the levels of Soil Contamination Warning Standard (SCWS) for agricultural lands (1-region) presented in Soil Environment Conservation Law (SECL).

Adverse Effects on Crops and Soils Following an Accidental Release of Hydrogen Fluoride and Hydrofluoric Acid

  • Kang, Dae-Won;Kim, Hyuck-Soo;Kunhikrishnan, Anitha;Kim, Da-In;Lee, Seul;Park, Sang-Won;Yoo, Ji-Hyock;Kim, Won-Il
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.6
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    • pp.651-654
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    • 2016
  • A number of accidents relating to highly toxic hydrogen fluoride (HF) or hydrofluoric acid (HA) release have occurred over fast few decades in Korea. Thus, this study was conducted to investigate the fluoride (F) concentrations in paddy soil and brown rice from 2 different areas where the soils were exposed to HF and HA. In the first case, the HF leakage accident that occurred in 2012 affected the surrounding soils and crops and consequently, crops (rice) affected by HF were unavailable for forage even though F did not accumulate in the soil. For example, at the time of accident, F concentrations in brown rice samples were $33.0-1,395mg\;kg^{-1}$, while F concentrations in soil samples were $155-295mg\;kg^{-1}$ which were less than the Korean standard guideline values of $400mg\;kg^{-1}$. However, after a year, F concentrations in brown rice were observed below the detection limit ($1mg\;kg^{-1}$), although F concentrations in soils were similar with those in 2012. Also, large amounts of wastewater discharges containing HA occurred in 2013 and some agricultural soils exceeded the Korean standard guideline values for F ($400mg\;kg^{-1}$), but soil-plant F transfer was not observed. In conclusion, it was observed that soil to plant transfer of F is unlikely although HF and HA as gas or liquid form can cause direct damage to plants.

Effects of Organic Matters Decomposed by Microbial Activity on Yield of Leaf Lettuce Under Protected Cultivation (미생물 유기질비료의 시용이 상추의 수량에 미치는 영향)

  • 김경제;김석균
    • Korean Journal of Organic Agriculture
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    • v.8 no.1
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    • pp.131-137
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    • 1999
  • This study was conducted to investigate the effects of microbial fertilizers on the yields of Leaf lettuce, chemical components of soil, and the microbial floras. Six micriobial fertilizers, MPK+Husk+Palma, Husk+Palma, MPK+Compost, Compost, Bio livestock cattle system(BLCS) cattle dropping, and Tomi, were used. All of the microbial fertilizers were tend to increase yields of Leaf lettuce, especially MPK+Husk+Palma treatment was most effective. In a chemical components of soil, concentrations of K, Mg were increased with Tomi treatment, however, the other concentrations of soil chemical components were not different. In a microbial floras of soil, Tomi, Husk+Palma, and MPK+Husk+Palma treated plots increased in numbers of total bacteria and bacillus. Tomi treated plot increased in numbers of actinomycetes and fungi, also. The other microbial floras of soil were not different, however. The microbial fertilizers may affect the useful microbial floras, therefore, it would be increase yield of Leaf lettuce treated with them.

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Effects of forest fire on physical and chemical properties of soil (산불이 토양의 물리ㆍ화학적 특성에 미치는 영향)

  • 박관수
    • Journal of Korea Soil Environment Society
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    • v.4 no.1
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    • pp.119-126
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    • 1999
  • This study was carried out to estimate the effect of forest fire on physical and chemical properties of soil The forest fire was in April 1995 at Kongju of Chungnam. Soil samples were collected at 0~5cm, 5~10cm, and 10~20cm soil depths in September 1998 from the burned and unburned sites. Soil organic matter concentrations at 0~5cm and 5~10cm soil depths were significantly greater in unburned site than in burned site. Soil concentrations were greater in unburned site than in burned site at all soil depths. Cation exchange capacity was significantly higher in unburned site than in burned site at 0~5cm soil depth. There were no differences in available soil P, exchangeable soil K, Ca, and Mg, and pH of soil between burned and unburned sites. Soil water content at 0~5cm soil depth was significantly greater in unburned site than in burned site. Bulk density at 0~5cm soil depth was significantly higher in burned site than in unburned site. Forest fire had an adverse effect on physical and chemical properties of soil in this study, Burning of vegetation and forest 리oor organic matter in burned site may reduce organic matter supply to soil and increase soil erosion. Consequently, forest fire may have adverse influence on long-term site productivity.

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The Effects of Organic Manure and Chemical Fertilizer Application Levels on the Growth and Nutrient Concentrations of Yellow Poplar (Liriodendron tulipifera Lin.) Seedlings (유기질 및 화학비료 처리수준이 어린 백합나무 생장 및 양분농도에 미치는 영향)

  • Han, Si Ho;An, Ji Young;Choi, Hyung-Soon;Cho, Min Seok;Park, Byung Bae
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.18 no.5
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    • pp.37-48
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    • 2015
  • Soil nutrient management is important to maintain the constant productivity of seedling production in the nursery for successful forest restoration. This study investigated the effects of organic manure and chemical fertilizer application levels on the growth, soil properties, and nutrient concentrations of yellow poplar seedlings. One-year-old yellow poplar seedlings were treated with the combination of 3 level organic manures(0, 5 Mg/ha, 10 Mg/ha; mixture of poultry manure, cattle manure, swine manure, and sawdust) and 3 level nitrogen-phosphorus-potassium(NPK) chemical fertilizers(0, 1x(urea, $30g/m^2$; fused superphosphate, $70g/m^2$; potassium chloride, $15g/m^2$), 2x). Organic manure significantly increased the soil pH and the concentrations of nitrogen, available phosphorous, exchangeable potassium, calcium, and magnesium. In contrast, the NPK chemical fertilizer decreased the soil pH and exchangeable calcium concentration, did not affect the soil concentrations of nitrogen and magnesium, and increased the concentrations of available phosphorous and exchangeable potassium. Both organic manure and NPK chemical fertilizer treatments increased the seedling height, root collar diameter, and dry weight by 39% and 25%, respectively. The treatment with manure 5 Mg/ha and NPK 2x chemical fertilizer mostly increased seedling dry weight by 2.6 times more than that of the control. Compared to the effects of the fertilization treatments on the soil properties, the effects on nutrient concentrations in the leaves were relatively small. These findings indicate that organic manure that was derived from livestock byproducts and sawdust can be utilized with chemical fertilizer to improve seedling production as well as conserving soil quality.

Prediction of Arsenic Uptake by Rice in the Paddy Fields Vulnerable to Arsenic Contamination

  • Lee, Seul;Kang, Dae-Won;Kim, Hyuck-Soo;Yoo, Ji-Hyock;Park, Sang-Won;Oh, Kyeong-Seok;Cho, Il Kyu;Moon, Byeong-Churl;Kim, Won-Il
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.2
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    • pp.115-126
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    • 2017
  • There is an increasing concern over arsenic (As) contamination in rice. This study was conducted to develope a prediction model for As uptake by rice based on the physico-chemical properties of soil. Soil and brown rice samples were collected from 46 sites in paddy fields near three different areas of closed mines and industrial complexes. Total As concentration, soil pH, Al oxide, available phosphorus (avail-P), organic matter (OM) content, and clay content in the soil samples were determined. Also, 1.0 N HCl, 1.0 M $NH_4NO_3$, 0.01 M $Ca(NO_3)_2$, and Mehlich 3 extractable-As in the soils were measured as phytoavailable As concentration in soil. Total As concentration in brown rice samples was also determined. Relationships among As concentrations in brown rice, total As concentrations in soils, and selected soil properties were as follows: As concentration in brown rice was negatively correlated with soil pH value, where as it was positively correlated with Al oxide concentration, avail-P concentration, and OM content in soil. In addition, the concentration of As in brown rice was statistically correlated only with 1.0 N HCl-extractable As in soil. Also, using multiple stepwise regression analysis, a modelling equation was created to predict As concentration in brown rice as affected by selected soil properties including soil As concentration. Prediction of As uptake by rice was delineated by the model [As in brown rice = 0.352 + $0.00109^*$ HCl extractable As in soil + $0.00002^*$ Al oxide + $0.0097^*$ OM + $0.00061^*$ avail-P - $0.0332^*$ soil pH] ($R=0.714^{***}$). The concentrations of As in brown rice estimated by the modelling equation were statistically acceptable because normalized mean error (NME) and normalized root mean square error (NRMSE) values were -0.055 and 0.2229, respectively, when compared with measured As concentration in the plant.

Relationship Between Chemical Properties of Forest soil Solutions and Element concentrations in Needles of Pinus thunbergii in Industral Complexes (공단 인접지역 해송 잎의 무기성분 함량과 산림 토양용액의 화학적 특성간의 관계)

  • Lee, Wi-Young;Yang, Jae E.;Park, Chang-Jin;Zhang, Yong-Seon;Ok, Yong-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.37 no.5
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    • pp.322-328
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    • 2004
  • Available nutrients in soil solution play key roles on the growth of plants, but the equilibria in soil solution can be disturbed by acid precipitation. In this study, we investigated the relationships between element concentrations in the needles of Pinus thunbergii and chemical properties of forest soil solutions in the industrial complexes as an effort to find the possible limiting factor(s) causing the forest decline. The Ca/Al molar ratios in needles of Pinus thunbergii collected from the control sites were 18. However, at Onsan and Ulsan industrial complexes, those were decreased to the ranges from 10 to 11 for the one-year old needles and from 9 to 10 for the two-year old needles. The Mg/Al molar ratios showed similar tendencies with the Ca/Al molar ratios of the needles of Pinus thunbergii. In the A horizon, there existed a significant correlation between Mg concentrations in the needles of Pinus thunbergii and Ca/Al molar ratio of forest soil solution. Calcium concentrations in the needles of Pinus thunbergii in the B horizon were also significantly correlated with Ca/Al molar ratios of forest soil solutions. The uptakes of Ca and Mg by Pinus thunbergii were mainly limited by Al in the soil solutions of the A horizon and by Mn and Al in the soil solutions of the B horizon.

Long-term Investigation of Soil Chemical Properties in Paddy Fields Located in Different Topographic Areas of Jeonbuk Province

  • Ahn, Byung-Koo;Ko, Do-Young;Lee, Chang-Kyu;Kim, Jin-Ho;Song, Young-Ju;Lee, Jin-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.3
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    • pp.275-281
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    • 2016
  • The aim of this study was to examine the selected soil chemical properties of paddy fields in different topographic areas to efficiently manage nutrient valances of the paddy fields in Jeonbuk Province. Three-hundred soil sampling sites in paddy fields were selected from the different topographic areas in Jeonbuk Province. The soil samples were collected every four years from 1999 to 2015. Soil pH and exchangeable K and Mg concentrations declined during the experimental periods. However, almost all the chemical properties were within the proper levels for paddy soil, except exchangeable Mg concentration. Distributed areas of the paddy fields with soil pH below 5.5 continuously increased, but the paddy fields with lower concentrations of soil organic matter and available $P_2O_5$ than the proper levels declined after 2007. In addition, the paddy fields with available $SiO_2$ below the proper concentration decreased from 83.3% of the total paddy fields studied in 1999 to 61.0% of the total fields investigated in 2015. The paddy fields with lower exchangeable K and Mg than the proper levels increased after 2003 whereas the fields with lower exchangeable Ca concentration decreased. Dominant landform of coastal and plain areas was fluvio-marine plains that was distributed in 53.7% and 40.9%, respectively. Local valley and fans was a dominant landform of mountainous and middle-mountainous areas, which was 51.8% and 67.6%, respectively. Dominant soil textures distributed in coastal and plain areas were silty loam and loam. Those in mountainous and middle-mountainous areas were sandy loam and loam, respectively. Soil pH was relatively higher in coastal area and the comparatively higher content of soil organic matter was found in costal area than other areas. The concentrations of available $P_2O_5$, exchangeable Ca, and exchangeable Mg were generally higher in mountainous, coastal, plain areas, respectively, but available $SiO_2$ and exchangeable K concentrations were not significantly different among the different topographic areas.

The Decomposition Rate of Litter and Soil Microorganisms on Slope Directions (方位에 따른 落葉의 分解率과 土壤 微生物에 관한 硏究)

  • Park, Bong Kyu;Mi Rim Kim
    • The Korean Journal of Ecology
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    • v.8 no.1
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    • pp.31-37
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    • 1985
  • The decomposition rate of litter and the number of soil microorganisms were measured on various slope directions in deciduous oak forest in Mt. Yongam. And the chemical constitutents of litter and soil were analyzed. The decomposition rate by slope directions followed the order east facing slope>south-east facing slope>north-west facing slope>north-east facing slope>north facing slope>south facing slope>south-west facing slope>west facing slope. Of the chemical constituents analyzed, original concentrations of Ca and carbohydrate were closely correlated with the decomposition rate. There was a close relation between the number of fungi and decomposition rate by slope directions. However, a little relationship existed between the number of bacteria and decomposition rate by slope directions. The number of fungi and concentrations of Ca and carbohydrate correlated to each other. And the number of bacteria is related to concentrations of phosphorus.

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