• Title/Summary/Keyword: Soil Chemical

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A Study on the Introduction of Pre-management System to Prevent Soil Contamination by Chemical Accident (화학사고시 토양오염 사전관리제도 도입을 위한 국내외 제도 분석 및 시사점)

  • Yoo, Keunje;Yang, Jihoon;Hwang, Sang-Il
    • Journal of Soil and Groundwater Environment
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    • v.21 no.4
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    • pp.20-29
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    • 2016
  • Although a number of chemical accidents have been occurred in South Korea, the effective prevention act for soil contamination has not been established so far. To effectively protect soil contamination from chemical accidents, decision support laws and regulations are absolutely essential. Regarding this situation, this study was aimed at diagnosing problems in current chemical safety management and prevention and response system against chemical accidents through analyzing the domestic and foreign causes of chemical accidents and the accident response procedures and finally suggesting policy measures for solving those problems. In order to clarify management of soil contamination by chemical accident, this study suggests the establishment of chemical accident preparedness, response, and making of local chemical management law and policy. This law needs to be supported by a clear management framework to guide government officials and all other stakeholders in the management of soil contamination by chemical accident.

Individual and combined effect of Portland cement and chemical agents on unconfined compressive strength for high plasticity clayey soils

  • Yilmaz, Yuksel;Eun, Jongwan;Goren, Aysegul
    • Geomechanics and Engineering
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    • v.16 no.4
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    • pp.375-384
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    • 2018
  • Unconfined compressive strength (UCS) of high plasticity clayey soil mixed with 5 and 10 % of Portland cement and four chemical agents such as sodium hexametaphosphate, aluminum sulfate, sodium carbonate, and sodium silicate with 0, 5, 10, and 20% concentrations was comparatively evaluated. The individual and combined effects of the cement and chemical agents on the UCS of the soil mixture were investigated. The strength of the soil-cement mixture generally increases with increasing the cement content. However, if the chemical agent is added to the mixture, the strength of the cement-chemical agent-soil mixture tends to vary depending on the type and the amount of the chemical agent. At low concentrations of 5% of aluminum sulfate and 5% and 10% of sodium carbonate, the average UCS of the cement-chemical agent-soil mixture slightly increased compared to pure clay due to increasing the flocculation of the clay in the mixture. However, at high concentrations (20%) of all chemical agents, the UCS significantly decreased compared to the pure clay and clay-cement mixtures. In the case of high cement content, the rate of UCS reduction is the highest among all cement-chemical agent-soil mixtures, which is more than three times higher in comparison to the soil-chemical agent mixtures without cement. Therefore, in the mixture with high cement (> 10%), the reduction of the USC is very sensitive when the chemical agent is added.

Relationship between Soil Management Methods and Soil Chemical Properties in Protected Cultivation

  • Kang, Yun-Im;Lee, In-Bog;Par), Jin-Myeon;Kang, Yong-Gu;Kim, Seung-Heui;Ko, Hyeon-Seok;Kwon, Joon-Kook
    • Korean Journal of Environmental Agriculture
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    • v.28 no.4
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    • pp.333-339
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    • 2009
  • Various cultural practices have been promoted as management options for enhancing soil quality and health. The use of soil management methods can cause changes in fertility by affecting soil chemical properties. This study aimed to evaluate interactions between soil chemical properties and soil management methods in protected cultivation, and to classify soil management methods that similarly affect soil chemical properties. Water-logging and irrigation reduced soil pH and available $P_2O_5$ content. Application of animal manures has a positive effect on levels of organic matter, Av.$P_2O_5$, K, Zn, and Cu. The electrical conductivites tened to be low in the application of organic amendments, including rice and wood residues. Deeper plowing caused a reduction in Ca content. Practicing soil nutrient-considering fertilization and fertigation did not exert an influence on nutrient element contents. In a cluster analysis of the soil management methods according to major nutrients, low similarities were found with deeper plowing and crop rotation with rice in comparison with other practices. In a cluster analysis by minor nutrient characteristics, crop rotation and application of animal manures and rice residues were linked at a high Ward's distance, while other practices were found to be relatively low distinct. Each soil management method has a similar or different effect on soil chemical properties. These results suggest the necessity of establishing limits and standards according to the effects of soil management methods on soil chemical properties for economic soil practices.

Calculating Soil Quality Index for Biomass Production Based on Soil Chemical Properties

  • Kim, Sung-Chul;Hong, Young Kyu;Lee, Sang Phil;Oh, Seung Min;Lim, Kyung Jae;Yang, Jae E.
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.1
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    • pp.56-64
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    • 2017
  • Soil quality has been regarded as an important factor for maintaining sustainability of ecosystem. Main purpose of this research was i) to select minimum factor for predicting biomass, and ii) to calculate soil quality index for biomass according to soil chemical properties. Result showed that soil pH, electrical conductivity (EC), soil organic matter (SOM), cation exchange capacity (CEC), and available phosphorus are minimum data set for calculating biomass production in soil. Selected representative soil chemical properties were evaluated for soil quality index and rated from 1 to 5 (1 is the best for biomass production). Percentage of each grade in terms of biomass production in national wide was 14.52, 35.23, 33.03, 6.47, 10.75% respectively. Although, only soil chemical properties were evaluated for calculating optimum soil quality, result of this research can be useful to understand basic protocol of soil quality assessment in national wide.

Monitoring physical and chemical properties of soil in Chungcheongbuk-do

  • Yun-Gu Kang;Jae-Han Lee;Taek-Keun Oh
    • Korean Journal of Agricultural Science
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    • v.49 no.4
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    • pp.719-727
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    • 2022
  • The soil physical and chemical properties are the main factors that influence plant productivity and soil fertility. Since 1999, South Korea has been conducting a survey on changes in the agricultural environment survey every four years. The purpose of the present study is to monitor the physical and chemical properties of soil in Chungcheongbuk-do. Soil samples were collected from the exact sites of the aforementioned environment survey, and land use and cultivated crops were also investigated. From a Pearson correlation analysis, it was found that the total carbon contents were most negatively affected by the soil depth. The bulk density of soil increased up to a depth of 40 cm but decreased to a depth of 60 cm. The porosity and moisture of soil generally decreased, but the porosity increased at a depth of 50 - 60 cm. Chemical properties of soil gradually decreased with an increase of the soil depth from 0 to 70 cm, but little change was observed in soil pH with soil depth. In addition, the organic matter contents of the soil at a depth of 30 cm or more were below the optimal range. The soil of Chungcheongbuk-do thus requires organic matter application as a whole, and correction of items that are partially out of the optimal range is necessary.

Effect of Long Term Fertilization on Microbial Biomass, Enzyme Activities, and Community Structure in Rice Paddy Soil

  • Lee, Chang Hoon;Kang, Seong Soo;Jung, Ki Youl;Kim, Pil Joo
    • Korean Journal of Soil Science and Fertilizer
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    • v.46 no.6
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    • pp.487-493
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    • 2013
  • The effects of long-term fertilization on soil biological properties and microbial community structure in the plough layer in a rice paddy soil in southern Korea were investigated in relation to the continuous application of chemical fertilizers (NPK), straw based compost (Compost), combination these two (NPK + Compost) for last 40 years. No fertilization plot (Control) was installed for comparison. Though fertilization significantly improved rice productivity over control, the long-term fertilization of NPK and compost combination was more effective on increasing rice productivity and soil nutrient status than single application of compost or chemical fertilizer. All fertilization treatments had shown significant improvement in soil microbial properties, however, continuous compost fertilization markedly increased soil enzyme and microbial activities as compared to sole chemical fertilization. Results of microbial community structure, evaluated by EL-FAME (ester-linked fatty acid methyl esters) method, revealed big difference among Control, NPK, and Compost. However, both Compost and Compost+NPK treatments belonged to the same cluster after statistical analysis. The combined application of chemical fertilizer and organic amendments could be more rational strategy to improve soil nutrient status and promote soil microbial communities than the single chemical fertilizer or compost application.

Model Development for Estimating Total Arsenic Contents with Chemical Properties and Extractable Heavy Metal Contents in Paddy Soils (논토양의 이화학적 특성 및 침출성 중금속 함량을 이용한 비소의 전함량 예측)

  • Lee, Jeong-Mi;Go, Woo-Ri;Kunhikrishnan, Anitha;Yoo, Ji-Hyock;Kim, Ji-Young;Kim, Doo-Ho;Kim, Won-Il
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.6
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    • pp.920-924
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    • 2012
  • This study was performed to estimate total contents of arsenic (As) by stepwise multiple-regression analysis using chemical properties and extractable contents of metal in paddy soil adjacent to abandoned mines. The soil was collected from paddies near abandoned mines. Soil pH, electrical conductively (EC), organic mater (OM), available phosphorus ($P_2O_5$), and exchangeable cations (Ca, K, Mg, Na) were measured. Total contents of As and extractable contents of metals were analyzed by ICP-OES. From stepwise analysis, it was showed that the contents of extractable As, available phosphorus, extractable Cu, exchangeable K, exchangeable Na, and organic mater significantly influenced the total contents of As in soil (p<0.001). The multiple linear regression models have been established as Log (Total-As) = 0.741 + 0.716 Log (extractable-As) - 0.734 Log (avail-$P_2O_5$) + 0.334 Log (extractable-Cu) + 0.186 Log (exchangeable-K) - 0.593 Log (exchangeable-Na) + 0.558 Log (OM). The estimated value in total contents of As was significantly correlated with the measured value in soil ($R^2$=0.84196, p<0.0001). This predictive model for estimating total As contents in paddy soil will be properly applied to the numerous datasets which were surveyed with extractable heavy metal contents based on Soil Environmental Conservation Act before 2010.

Effects of Grain Size Distribution in Soil on the Strength Characteristics of Lime-Soil Mixtures (흙의 粒度分捕가 石灰混合土의 强度特性에 미치는 影響)

  • Cho, Seong-Jeong;Kang, Yea-Mook
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.27 no.2
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    • pp.57-71
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    • 1985
  • The characteristics of compaction and unconfined compressive strength were investigated by mixing with lime to all soils adjusted by given percentages of two kinds of clays to sand to obtain the most effective distribution of grain size and the optimum lime content for soil stabilization. In addition, unconfined compressive strength and durability tested by adding of sodium metasilicate, sodium sulfate, sodium carbonate, sodium gydroxide and magnesium oxide to lime-soil mixture mixed with 8 percent lime to adjusted soil having the mixing percentage of 60 percent of cohesive black clay and 40 percent of sand by weight to get the effect and the optimum content of chemicals. The results obtained were as follows; 1.With the addition of more lime, the optimum moisture content was increased, and the maximum dry density was decreased, whereas the more the amount of clay and the less was the maximum drt density. 2. In the soil having more fine grain size the unconfined compressive strength was larger in the earlier stage of curing period, in accordance with the longer period, the mixing percentages of sand to clay showing the maximum unconfined compressive strength, on the basis of 28-day strength, were 60% : 40% (black clay) and 40% : 60% (brown clay) respectively. 3. The reason why the soil adjusted with black clay was remarkably bigger in the unconfined compressive strength than ones adjusted with brown clay for all specimen of lime-soil mixture was the difference in the kind of clay, the amount of chemical compositions the value of pH. Black clay was mainly composed of halloysite that reacted with lime satisfactorily, whereas the main composition of brown clay was kaolinite that was less effect in the enhance of unconfined compressive strength. Also the difference of unconfined compressive strength was because black clay was larger in the amount of composition of calcium oxide and magnesium oxide in the value of pH affecting directly on the unconfined compressive strength of lime-soil mixture than brown clay. 4. In the lime-soil mixture mixed with 8 percent of lime to soil that mixing percentage of sand to black clay was 60% : 40%, on the standard of 7-day strength, the effect of chemical was arranged in the order of magnesium oxide, sodium carbonate, sodium sulfate, sodium hydroxide and sodium metasilicate. 5. The optimum amount of chemical being applicable to the maximum unconfined compressive strength of lime-chemical-soil mixture was 1 percent by weight for air dry soil in the case of adding sodium carbonated and 0.75 percent on sodium hydroxide, the unconfined compressive strength was increased continuously with increase of the amount of chemical up to 2 percent of chemical content is the lime-chemical-soil mixture added sodium metasilicate, sodium sulfate and magnesium oxide. 6. It was considered that the chemical played and accelerant role of early revelation of strength because the rate of increase of unconfined compressive strength of all of lime-chemical-soil mixtures was largest on the 7-day cured specimen. 7. The effect of test on freezing and thawing after adding suitable amount of chemical on the lime-soil mixture mixed with 8 percent of lime to soil that mixing percentage of sand to black clay was 60% : 40% was arranged in the order of magnesium oxide, sodium carbonate, sodium sulfate, sodium metasilicate and sodium hydroxide.

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Effect of Chemical Amendments on Soil Biological Quality in Heavy Metal Contaminated Agricultural Field

  • Kim, Yoo Chul;Hong, Young Kyu;Oh, Se Jin;Oh, Seung Min;Ji, Won Hyun;Yang, Jae E.;Kim, Sung Chul
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.2
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    • pp.146-152
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    • 2015
  • Heavy metal pollution has been a critical problem in agricultural field near at the abandoned metal mines and chemical amendments are applied for remediation purpose. However, biological activity can be changed depending on chemical amendments affecting crop productivity. Main purpose of this research was to evaluate biological parameters after applying chemical amendments in heavy metal polluted agricultural field. Result showed that soil respiration (SR) and microbial biomass carbon (MBC) were changed after chemical amendments were applied. Among three different amendments, lime stone (LS), steel slag (SS), and acid mine drainage sludge(AMDS), AMDS had an effect to increase SR in paddy soil. Comparing to control ($93.98-170.33mg\;kg^{-1}day^{-1}$), average of 30% increased SR was observed. In terms of MBC, SS had an increased effect in paddy soil. However, no significant difference of SR and MBC was observed in upland soil after chemical amendment application. Overall, SR can be used as an indicator of heavy metal remediation in paddy soil.

Study on the of the Correlation between Soil Chemical Properties and Bioactive Compounds of Acer tegmentosum Maxim.

  • Lee, Dong Hwan;Park, Youngki;Hong, Seong Su;Park, Gwang Hun;Kim, Hyun-Jun
    • Korean Journal of Plant Resources
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    • v.34 no.6
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    • pp.566-574
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    • 2021
  • This research was carried out to investigate the correlation between soil chemical properties and bioactive compounds of Acer tegmentosum Maxim. The methods of determining bioactive compounds were determined by high performance liquid chromatography, that contained (-)-gallocatechin (0.04±0.01 ~ 0.43±0.28%), salidroside (0.90±0.06 ~ 3.86±0.59%), tyrosol (0.03±0.00 ~ 0.43±0.00%), (-)-catechin (0.05±0.01 ~ 0.37±0.14%), 6'-O-galloylsalidroside (0.02± 0.01 ~ 0.31±0.06%), (-)-epicatechin-gallate (0.01±0.00 ~ 0.04±0.01%). The soil chemical properties analysis such as soil pH, electric conductivity (EC), organic matter (OM), total nitrogen (TN), available phosphate (Avail. P2O5), exchangeable cation and cation exchange capacity (CEC) were performed following the standard manual. The correlation analysis between soil chemical properties and bioactive compounds of A. tegmentosum, soil pH, available phosphate and exchangeable cation (Ca2+ and Mg2+) were negatively correlated with content of salidroside. On the other hand, soil exchangeable cation (Na+) showed positive correlation with content of salidroside. The results of this study was able to investigate the correlation between soil chemical properties and bioactive compounds of A. tegmentosum.