• Title/Summary/Keyword: Softening Point

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Fracture process of rubberized concrete by fictitious crack model and AE monitoring

  • Wang, Chao;Zhang, Yamei;Zhao, Zhe
    • Computers and Concrete
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    • v.9 no.1
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    • pp.51-61
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    • 2012
  • According to the results of three-point bending tests of rubberized concrete and plain concrete, the parameters such as total fracture energy ($G_F$), initial fracture energy ($G_f$), and tensile strength ($f_t$) are obtained for concrete material. Using ABAQUS software and a bilinear softening fictitious crack model, the crack propagation process was simulated and compared to the experimental results. It is found that the increase of AE hit count has a similar trend with the increase of energy dissipation in FEM simulation. For two types of concretes, both experimental results and numerical simulation indicate that the rubberized concrete has a better fracture resistance.

Crystallization Mechanism in ZnO-P2O5 System Glass (ZnO-P$_2$O$_5$ 계 유리의 결정화 기구에 관한 연구)

  • 박용완;연석주
    • Journal of the Korean Ceramic Society
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    • v.28 no.9
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    • pp.683-688
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    • 1991
  • ZnO-P2O5 system glass containing 45 to 60 mol% ZnO has been melted at 120$0^{\circ}C$ and crystallized through heat treatment. Each condition of crystallization was determined by measurement of dilatometric softening point and DTA. The principal crystalline phase was identified as zinc metaphosphate [Zn(PO3)2] in the glasses containing 45~55 mol% ZnO and zinc pyrophosphate (Zn2P2O7) in the sample of 60 mol% ZnO with X-ray diffraction patterns. The crystalline mechanism was investigated by XRD and SEM. As the results, the specimens containing 50~60% ZnO showed the existence of oriented structure due to one-dimensional crystal growth.

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Preparation of Carbon Fiber from Heavy Oil Residue through Bromination

  • Park, Young-Ok;Yang, Kap-Seung
    • Fibers and Polymers
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    • v.2 no.4
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    • pp.178-183
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    • 2001
  • A pitch precursor for a general purpose carbon fiber was prepared by condensation of pyrolized fuel oil (petroleum residual oil) with bromine under nitrogen blowing. such a condensation raised the softening point of the pitch from 4$0^{\circ}C$ to $265^{\circ}$ with a yield of 43%. The pitch precurosr showed an enhanced aromaticity and enlarged molecular size, which led to a reduction in molecular mobility and optical isotropy. The precursor was spun into fibers of $20\mu\textrm{m}$ diameter at a take-up speed of 700m/min. The fiber was stepwise stabilized in air and carbonized in Ar gas to obtain an isotropic carbon fiber. The carbon fiber exhibited tensile strengths of 500-800 ㎫though the fiber was formed via a crude method. The electric conductivity of the carbon fiber was relatively high, 2.2$\times$$10^2$S/cm, sufficient to be used as electrode materials.

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Temporal Variations of Reinforced Roadbed Stiffness Using In-situ Seismic Tests (현장탄성파시험을 이용한 강화노반의 시간적 강성 변화)

  • Mok, Young-Jin;Park, Chul-Soo;Lim, Jeong-Yeul;Choi, Choong-Lak
    • Proceedings of the KSR Conference
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    • 2007.05a
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    • pp.404-411
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    • 2007
  • Reinforced roadbeds are valued from the point of view of maintenance as well as enhanced mechanical capacity. They support more train load and less transmit to the sub-layers than general roadbeds. Also, the lateral sloping surface of the reinforced roadbed and its low permeability, achieved by the controlled compaction, increase drainage capability and prevent the softening of sub-layers. In the study, a series of cross-hole tests was performed to observe the temporal changes in the stiffness of reinforced roadbeds, if any, due to the cyclic loading of trains and alternating rainy and frozen seasons at Pyeong-taek experimental site. The three types of reinforced roadbed materials are slag, crushed stones, and soils, and the thickness of all the reinforced roadbeds is 0.8m. The stiffness of the slag and soil reinforced roadbeds was not changed or slightly decreased. The stiffness of the crushed stone was somewhat increased and is inferred to being densified close to surface.

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A Study on Fracture Characteristics of Chemically Prestressed Mortar (화학적 프리스트레스가 도입된 모르타르의 파괴특성에 관한 연구)

  • 안중길;심별;송하원;변근주
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.828-833
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    • 2003
  • In this paper, a study on fracture characteristics of chemically prestressed mortar with addition of expansive additives was carried out. Uni-axial tension tests with reinforced mortar specimen restrained by embedded reinforcing bar and three point bending tests with notched steel fiber reinforced beams were carried out to verify the characteristics of the cracking behavior, the tension stiffening effect due to bond between rebar and mortar, and fracture characteristic. Tension stiffening curve for the chemically prestressed mortar was obtained from uni-axial tension test. And increased fracture energy due to the chemical prestress was also obtained from bending test and tension softening curve for chemically prestressed mortar was also obtained.

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Preparation of Partial Mesophase Pitch-based Carbon Fiber from FCC-DO

  • Park, Sang-Hee;Yang, Kap-Seung;Soh, Soon-Young
    • Carbon letters
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    • v.2 no.2
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    • pp.99-104
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    • 2001
  • Partial mesophase (PM) pitch precursor was prepared from fluidized catalytic cracking-decant oils (FCC-DO) by chemical reaction in the presence of $Br_2$. The PM pitch heated-treatment at $420^{\circ}C$ for 9 h exhibited the softening point of $297^{\circ}C$ with 23% yield, and 55% anisotropic content. The PM pitch precursor was melt-spun through circular nozzle by pressurized $N_2$, stabilized at $310^{\circ}C$, carbonized at $700^{\circ}C$, $1000^{\circ}C$, and $1200^{\circ}C$. The enough stabilization introduced 16.4% of the oxygen approximately. The stacking height ($L_{c002}$) and interlayer spacing ($d_{002}$) of the as-spun fibers were 4.58 nm and $3.45{\AA}$ and the value became minimum and maximum at $700^{\circ}C$ respectively in the carbonization procedure. The tensile strength increased with an increase in the heat treatment temperature exhibiting highest value of 750 MPa at $1200^{\circ}C$ carbonization.

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A comparative study on thermal, mechanical and dielectric characteristics of low density polyethylene crosslinked by radiation and chemical methodes (화학적방법과 방사선으로 가교된 저밀도 폴리에티렌의 열적 기계적 및 유전적 특성의 비교연구)

  • 김봉흡;강도열;김정수
    • 전기의세계
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    • v.25 no.2
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    • pp.100-106
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    • 1976
  • A comparative study on thermal, static mechanical and dielectric characteristics were made over a temperature range of ca.20.deg.C to 320.deg.C and a frequency range of KHZ to MHZ band on low density polyethylene specimens crosslinked, respectively, by radiation and chemical method. The thermal property of both specimens shows that softening point appears to unchange by crosslinking, however, melting and liquidizing temperatures attain rapid increase at the imitiation of crosslinking. Mechanical properties show little difference to both specimens crosslinked by different method, further the behaviors were discussed in connection with the relaxation of molecular segments in amorphous phase. Dose dependent dielectric characteristics observed at ambient temperature under several fixed frequencies exhibit extremities at ca. 20 Mrad and the behaviors also were interpreted qualitatively by taking into consideration of dipole concentration change in amorphous phase together with the role of specimen geometry to the depth of oxidative layer. Observing frequency dependent dielectric characteristics, it was also proved that ionic conduction loss is appreciably greater in the specimen prepared by chemical method than that by radiation.

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Characterization of Pitch Derived from Petroleum Residue and Coal-tar (석유계 잔사유 및 coal-tar의 핏치 개질 특성)

  • KIM, JIHONG;KIM, HYEONGGI
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.5
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    • pp.612-619
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    • 2016
  • Pitch synthesis reaction was studied based on the effect for chemical composition of feedstock. Feedstock was selected as pyrolyzed fuel oil (PFO) and coal-tar (CT), which are by-products in petroleum and steel industry. Pitch was prepared at $420^{\circ}C$ for 180 minutes on atmospheric pressure by thermal treatment. Thermal stability and softening point (SP) of the prepared pitches were investigated and their molecular weight distribution was analyzed by MALDI-TOF. PFO has various aliphatic compounds and coal-tar has high aromaticity with 3 wt% of primary quinoline insolubles. The thermal property of PFO was enhanced with polymerization reaction during the thermal treatment with increased molecular weight range. But CT was inferior to PFO because of side reaction by hetero elements. CTP was appeared molecular weight by 0~200 m/z.

Layered model of aging concrete. General concept and one-dimensional applications

  • Truty, Andrzej;Szarlinski, Jan;Podles, Krzysztof
    • Computers and Concrete
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    • v.17 no.6
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    • pp.703-721
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    • 2016
  • A novel approach to modeling concrete behavior at the stage of its maturing is presented in this paper. This approach assumes that at any point in the structure, concrete is composed of a set of layers that are activated in time layer by layer, based on amount of released heat that is produced during process of the concrete's maturing. This allows one to assume that each newly created layer has nominal stiffness moduli and tensile/compressive strengths. Hence introduction of explicit stiffness moduli and tensile/compressive strength dependencies on time, or equivalent time state parameter, is not needed. Analysis of plain concrete (PC) and reinforced concrete (RC) structures, especially massive ones, subjected to any kind of straining in their early stage of existence, mostly due to external loads but especially by thermal loading and shrinkage, is the goal of the approach. In this article a simple elasto-plastic softening model with creep is used for each layer and a general layered model behavior is illustrated on one-dimensional (1D) examples.

Study on $Carisolv^{TM}$ from View Point of Free Radical.

  • Tsujimoto, Y.;Gomi, H.;Tsukada, N.;Hirayama, S.;Ikemi, T.;Yamazaki, M.
    • Proceedings of the KACD Conference
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    • 2001.11a
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    • pp.568.2-568
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    • 2001
  • $Carisolv^{TM}$ system was developed for removal of carious dentin with chemo-mechanical method by Swedish researcher. $Carisolv^{TM}$ is composed of 0.5% NaClO and three kinds of amino acid, i.e. glutamic acid, leucine and lysin. After these agents are mixed together, the gel mixed is applied to carious dentin and the carious dentin is removed with hand instrument without using burs. The mechanism of softening the dentin is postulated that the degenerated collagen by caries is chlorinated and the decomposed. But the details of the mechanism are not clarified yet.(omitted)

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