• Geomechanics and Engineering
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• v.11 no.1
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• pp.77-94
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• 2016

A forked tunnel, as a special complicated underground structure, is composed of big-arch tunnel, multi-arch tunnel, neighborhood tunnels and separate tunnels according to the different distances between two separate tunnels. Due to the complicated process of design and construction, surrounding jointed rock mass stability of the big-arch tunnel which belongs to the forked tunnel during excavation is a hot issue that needs special attentions. In this paper, an elasto-plastic damage constitutive model for jointed rock mass is proposed based on the coupling method considering elasto-plastic and damage theories, and the irreversible thermodynamics theory. Based on this elasto-plastic damage constitutive model, a three dimensional elasto-plastic damage finite element code (D-FEM) is implemented using Visual Fortran language, which can numerically simulate the whole excavation process of underground project and perform the structural stability of the surrounding rock mass. Comparing with a popular commercial computer code, three dimensional fast Lagrangian analysis of continua (FLAC3D), this D-FEM has advantages in terms of rapid computing process, element grouping function and providing more material models. After that, FLAC3D and D-FEM are simultaneously used to perform the structural stability analysis of the surrounding rock mass in the forked tunnel considering three different computing schemes. The final numerical results behave almost consistent using both FLAC3D and D-FEM. But from the point of numerically obtained damage softening areas, the numerical results obtained by D-FEM more closely approach the practical behaviors of in-situ surrounding rock mass.

• Geomechanics and Engineering
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• v.36 no.1
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• pp.39-50
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• 2024

Bitumen and high-quality subangular aggregates, the two principal materials used for asphalt concrete construction, are finite and expensive materials. The general availability of crumb rubber and naturally occurring aggregates of different shapes, especially flat and elongated shapes, indicates that they are feasible alternative materials for expanding the volume of bitumen and utilizing a wider range of aggregate shapes for the development of asphalt concrete, with an associated environmental benefit. The study investigated the effect of adding up to 15% crumb rubber and aggregates sorted into different groups, i.e., rounded, elongated, flat, and their combinations, on the rheological and mechanical properties and durability of 50/70 of hot-mix asphalt pavement. The addition of crumb rubber decreased ductility and penetration but increased the softening point. For a 5.5% bitumen content, asphalt concrete briquettes consisting of 7% crumb rubber and three types of aggregate shapes, i.e., 100% rounded, a mix of 75% rounded and 25% elongated, and a mix of 75% rounded, 15% elongated and 10% flat, were associated with high Marshall stability and indirect tensile strength as well as low lateral deformation due to their high solidity and moderate angularity ratio. Also, the addition of 7% crumb rubber resulted in a significant improvement in the tensile strength ratio and rebound strain of briquettes consisting of 75% rounded and 25% elongated aggregates and those with 75% rounded, 15% elongated and 10% flat aggregates. In relation to the parameters investigated, the three groups of briquettes met some of the local (South Africa) requirements for the surface course and base course of low traffic volume roads.

• Journal of the Korean Chemical Society
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• v.12 no.2
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• pp.65-80
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• 1968

The physico-chemical properties of nine selected thallium borosilicate glasses and other 21 supplementary compositions were investigated. Their composition-property curves are found to be in many respects analogous to those of other borosilicate glasses containing lithia, soda, and lead oxide. It is indicated that certain minima found in the composition-property curves of thallium borosilicate glasses might be caused by a change in boron coordination as has been observed to occur in the $Na_2O-B_2O_3-SiO_2$ glasses. Typical effects of thallium ions on the borosilicate glass are summarized as follows: 1) Addition of thallium ions increased density, refractive index, water solubility, linear coefficient of thermal expansion, and dielectric constant. 2) Increased concentration of thallium decreased the softening point of the glasses, caused fluorescence under ultraviolet radiation and smeared out the absorption edges up to $15{\mu}$ in the infrared region. An extensive liquid immiscibility was found by replication electron microscope technique in the $Tl_2O-B_2O_3-SiO_2$ system. The immiscibility covers a composition range roughly from 55 wt. % Tl2O to the binary system $B_2O_3-SiO_2.$ By acid treatment, it was found that the immiscible glass consists of separate silica-rich and boron-rich phases.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.23 no.5
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• pp.246-254
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• 2013

Translucent opal glass was fabricated in order to substitute polycarbonate diffuser of LED lighting for the purpose of improving the durability problem. Calcium phosphate was used for the opacifier of opal glass and melted at $1550^{\circ}C$ for 2 hrs in electric furnace. Because opal glass was made by phase separation and growth of opacifier grains during cooling procedure after forming of melted glass, we identified the effect of opaque properties by the change of forming and cooling temperature, as R.T. (room temperature), $850^{\circ}C$, $1100^{\circ}C$ and $1200^{\circ}C$. As the results, it had excellent optical properties for the diffuser of LED lighting in the fabricated sample of forming and cooling at $1200^{\circ}C$, with no dazzling from direct light by high haze value over 82 % and low parallel transmittance value under 10 %. For the thermal properties, it had expressed thermal expansion coefficient of $6.352{\times}10^{-6}/^{\circ}C$ and softening point of $839^{\circ}C$.

• Journal of the Korean Geotechnical Society
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• v.19 no.4
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• pp.191-200
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• 2003

This paper presents the rheological properties of bitumen for reducing negative skin friction. The bitumen has been widely used due to both the cost and construction effectiveness. Also, it is well known that the use of bitumen for reducing negative skin friction renders the best results among other available methods. Three different modified bitumens were used for the testing programs. The physical tests include the penetration, the softening point and penetration index. The rheological tests include phase angle, complex modulus, creep tests and flow tests. The tests were conducted at four different temperatures(15, 30, 45 and 6$0^{\circ}C$) in order to simulate the field condition. The test results were analyzed using the phase angle, G$^*$/sin $\delta$, creep compliance and shear viscosity. The result of tests showed that the phase angle increased and G$^*$/sin $\delta$ decreased with the increase of temperature. The creep compliance increased as the loading time increased. The difference of the creep compliance is detected as the time and temperature are varied, however, the difference of the shear viscosity is not significant among the samples tested in this study. The rheological properties of the bitumen also showed that the physical testing method and the temperature dependant testing method are somewhat limited to showing and expressing the full rheological properties of the modified bitumen. The introduction of the time and the temperature dependent testing method is necessary to find out the full rheological properties of the modified bitumen.

• International Journal of Highway Engineering
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• v.3 no.2 s.8
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• pp.113-121
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• 2001

Among the currently available binder specifications, Superpave Performance Grade asphalt specification is regarded as a superior specification on its theoretical background as well as pavement performance relationship. Many difficulties are expected; however, for Superpave implementation in Korea because of heavy burden of equipment cost as well as lack of trained personnel in asphalt industry, which may too much barrier to overcome in Korean situation. As an effort to improve qualify of asphalt binder, recently, people discuss about a possibility of constituting a performance-based asphalt specification using rather easy-to-measure asphalt properties. The objective of this paper is to determine the possibility of constituting a performance-based asphalt specification using an empirical asphalt properties, such as penetration ring and ball softening point rather than using fundamental properties of asphalt. Nine straight asphalts, that covers entire straight asphalt from all Korean refineries, and eighteen modified asphalts that were modified from two modifiers were included in the study. An analysis was made through a comparison between empirical properties and Superpave PG criteria. This study concluded that it may possible to constitute a pseudo-Superpave-like specification using an empirical asphalt properties as a specification criteria. Therefore, more systematic research is needed to constitute the asphalt specification.

• International Journal of Highway Engineering
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• v.4 no.1 s.11
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• pp.149-159
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• 2002

This study was performed to estimate the high-speed direct tensile strength(DTS1), low-speed direct tensile strength(DTS2) , indirect tensile strength(ITS) resilient modulus(MR) and stiffness index(SI) of sand asphalt mixture based on the absolute viscosity, kinematic viscosity, penetration, softening point and PG grade of binder. DTS2 showed higher correlation with the physical properties than other properties of mixture, and the next was DTS1, ITS, SI and MR in order. Among binder properties, PG grade showed the highest relation with DTS2. Therefore. it was found that the high DTS mixture could be made when the binder with a high PG grade was used. However, since the individual physical property showed a relatively low correlation, various properties were used together in regression analysis. The estimation models of DTS and ITS were over 0.99, respectively. R2 of MR and SI estimation models were over 0.91 and 0.93, respectively. It was concluded that mechanical properties could be estimated with a high coefficient of determination from those physical properties.

• Applied Chemistry for Engineering
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• v.27 no.5
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• pp.537-542
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• 2016

In this study, we have prepared mesophase pitch from pyrolysis fuel oil (PFO) by heterogeneous reforming process. This process was conducted by direct fluorination at various temperature and followed by the heat treatment at $390^{\circ}C$. The reformed pitch was then investigated by softening point analysis, elemental analysis, fourier-transform infrared spectroscopy, high resolution X-ray diffraction and polarization microscope analysis. Carbon contents of reformed pitch increased according to increasing the reaction temperature of fluorination, while oxygen, nitrogen and sulfur contents were completely eliminated. As the fluorination temperature increased, the creation, growth, coalescence and alignment process of mesophase spheres were observed. Also the interlayer spacing of carbon hexagonal planar structure decreased, while its crystalline size increased. In addition, aromatic ring compound contents increased by the condensation polymerization of aliphatic compound. These results can be attributed to the radical reactivity of the fluorine increased as the reaction temperature increased. It was considered that the fluorination reaction could help PFO to generate aromatic compounds, via promoting polymerization by radical reaction.

• Journal of Adhesion and Interface
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• v.16 no.1
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• pp.29-34
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• 2015

Hydrocarbon resins, which are defined as low molecular weight, amorphous, and thermoplastic polymers, are widely used as tackifier for various types of adhesives, as processing aids in rubber compounds, and as modifiers for plastics polymers such as isotactic polypropylene. Typically, hydrocarbon resins are non-polar, and thus highly compatible with non-polar rubbers and polymer. However, they are poorly compatible with polar system, such as acrylic copolymer, polyurethanes, and polyamides. Moreover, recently the raw materials of hydrocarbon resin from naphtha cracking had been decreased because of light feed cracking such as gas cracking. To overcome this problem, in this study, novel hydrocarbon resins were designed to have a highly polar chemical structure which material is sustainable. And, it was successfully synthesized by Diels-Alder reaction of dicyclopentadiene monomer and sorbic acid from blueberry as renewable resources. Acrylic resins were formulated with various tackifiers solution including sorbic acid grafted hydrogenated dicyclopentadiene hydrocarbon resins in acrylic adhesive and rolling ball tack, loop tack, $180^{\circ}$ peel adhesion strength, and shear adhesion strength were measured. The properties depend on the softening point and polar content of tackifiers.

• Korean Journal of Medicinal Crop Science
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• v.28 no.2
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• pp.152-166
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• 2020

Background: Ginsenosides, which have various physiological activities, are known to be abundant in the leaves and roots of ginseng. Ginseng sprouts can be used as a fresh vegetable and roots, stems, and leaves of ginseng can be consumed. This study aimed to investigate the effect of carbon dioxide treatment and the modified atmosphere (MA) packaging method in suppressing quality deterioration during the distribution of ginseng sprouts. Methods and Results: Ginseng sprouts were packed using Styrofoam, barrier film + non gas treatment, barrier film + gas treatment, 15 ㎛ polyamide (PA) double film + non gas treatment, 15 ㎛ PA double film + gas treatment, 25 ㎛ PA film + non gas treatment, or 25 ㎛ PA film + gas treatment. Quality parameters including gas composition, relative humidity, chlorophyll SPAD (Soil Plant Analysis Development) value, firmness, and rate of quality loss in ginseng sprouts were monitored at the following temperatures: 20℃, and 10℃. Ginseng sprouts packaged with 25 ㎛ PA film showed loss in quality because of wilting owing to low relative humidity within the film. Chlorophyll and firmness did not differ between film and gas treatments. The time point at which the combined loss from softening and decay owing to fungal, and bacterial infection and wilt reached 20% was considered the limit of distribution. At 20℃, the packaging not included in the 20% distribution loss rate limit or up to 7 days was 15 ㎛ PA double film + gas treatment. At 10℃, the packaging not included in the 20% distribution loss rate limit for up to 18 days were barrier film + gas treatment and 15 ㎛ PA double film + gas treatment. Conclusions: The film packaging suitable for the distribution of ginseng sprouts was found to be the barrier film and PA film with low gas permeability and maintaining hygroscopicity at 95% relative humidity. To prevent the loss in quality of ginseng sprouts, gas treatment (8% of O₂ and 18% of CO₂) in the film was found to be more suitable than no gas treatment for inhibition of decay.