• Title/Summary/Keyword: Soft ray

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Effects of Phosphorous-doping on Electrochemical Performance and Surface Chemistry of Soft Carbon Electrodes

  • Kim, Min-Jeong;Yeon, Jin-Tak;Hong, Kijoo;Lee, Sang-Ick;Choi, Nam-Soon;Kim, Sung-Soo
    • Bulletin of the Korean Chemical Society
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    • v.34 no.7
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    • pp.2029-2035
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    • 2013
  • The impact of phosphorous (P)-doping on the electrochemical performance and surface chemistry of soft carbon is investigated by means of galvanostatic cycling and ex situ X-ray photoelectron spectroscopy (XPS). P-doping plays an important role in storing more Li ions and discernibly improves reversible capacity. However, the discharge capacity retention of P-doped soft carbon electrodes deteriorated at $60^{\circ}C$ compared to non-doped soft carbon. This poor capacity retention could be improved by vinylene carbonate (VC) participating in forming a protective interfacial chemistry on soft carbon. In addition, the effect of P-doping on exothermic thermal reactions of lithiated soft carbon with electrolyte solution is discussed on the basis of differential scanning calorimetry (DSC) results.

Electronic structure studies of Co-substituted FINEMET alloys by x-ray absorption spectroscopy

  • Chae, K.H.;Gautam, S.;Song, J.H.;Kane, S.N.;Varga, L.K.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.377-377
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    • 2010
  • FINEMET type nanocrystalline materials synthesized by controlled crystallization of amorphous ribbons[1] exhibit excellent soft magnetic properties making them attractive for technological applications. Present work reports the electronic structure studies of Co-substituted FINEMET to get information on the effect of successive Co substitution on local environment around Fe and Co atom by using near edge x-ray absorption fine structure (NEXAFS) and x-ray magnetic circular dichroism (XMCD) measurements. NEXAFS spectroscopy and XMCD measurements have been carried out at Fe $L_{3,2}$ and Co $L_{3,2}$-edges to investigate the chemical states and electronic structure of FINEMET [$(Fe_{100-x}Co_x)_{78}Si_9Nb_3Cu_1Ba$](0$L_{3,2}$-edge reveal that Fe is in 2+ state and in tetrahedral symmetry with other elements. The magnetic properties exhibiting soft magnetic behavior[2] are discussed on the basis of the electronic structure studied through XMCD.

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Exploring the Extra Component in the Gamma-ray Emission of the New Redback Candidate 3FGL J2039.6-5618

  • Ng, Cho-Wing;Cheng, Kwong-Sang;Takata, Jumpei
    • Journal of Astronomy and Space Sciences
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    • v.33 no.2
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    • pp.93-99
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    • 2016
  • A redback system is a binary system composed of a pulsar and a main sequence star. The inverse Compton (IC) scattering between the stellar soft photons and the relativistic pulsar wind will generate orbital-modulating GeV photons. We look for these IC emissions from redback systems. A multi-wavelength observation of an unassociated gamma-ray source, 3FGL J2039.6-5618, by Salvetti et al. (2015) detected an orbital modulation with a period of 0.2 days in both X-ray and optical cases. They suggested 3FGL J2039.6-5618 to be a new redback candidate. We analyzed the gamma-ray emission of 3FGL J2039.6-5618 using the data from the Fermi large area telescope (Fermi-LAT) and obtained the spectrum in different orbital phases. We propose that the spectrum has orbital dependency and estimate the characteristic energy of the IC emission from the stellar-pulsar wind interaction.

Introduction to Qunatification of Damage Parameters for Concrete Using X-ray Computed Tomography (X-ray Computed Tomography를 이용한 콘크리트의 손상파라미터 정량화)

  • 박대효;박재민;안태송
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.501-504
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    • 2003
  • The purpose of this work is to introduce some fundamental stereological concepts to quantify damage parameters using X-ray CT(Computed Tomography) in the scope of CDM(Continuum Damage Mechanics). X-ray CT is a completely nondestructive technique for visualizing features in the interior of opaque solid objects, and for obtaining digital information on their 3D geometries and properties. Many researchers have introduced lots of damage parameters to model the mechanical behavior of deteriorated materials. Those damage parameters can be represented in many forms such as specific void or crack surfaces, the spacing between cracks, the specific damaged surface area, the specific damaged surface area tensor, the mean solid path among the damaged surfaces and the mean solid path tensor. Despite of many accomplishments in CDM since there is no the systematic experiment, it have limitations in application. In this situation, X-ray computed tomography is highlited by many researchers and applied in a wide range of materials including rock, bone, ceramic, metal, soft tissue and concrete.

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Thickness-dependent magnetic domain structures of Co ultra-thin film investigated by scanning transmission X-ray microscopy

  • Yoon, Ji-Soo;Kim, Namdong;Moon, Kyoung-Woong;Lee, Joo In;Kim, Jae-Sung;Shin, Hyun-Joon;Kim, Wondong
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1185-1189
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    • 2018
  • Thickness-dependent magnetic domain structure of ultrathin Co wedge films (0.3 nm-1.0 nm) sandwiched by Pt layers was investigated by scanning transmission x-ray microscopy (STXM) employing X-ray magnetic circular dichroism (XMCD), utilizing elliptically polarized soft x-rays and electromagnetic fields, with a spatial resolution of 50 nm. The magnetic domain images measured at the Co $L_3$ edge showed the evolution of the magnetic domain structures from maze-like form to the bubble-like form as the perpendicular magnetic field was applied. The asymmetric domain expansion of a 500 nm-scale bubble domain was also measured when the in-plane and perpendicular external magnetic field were applied simultaneously.