• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2018.06a
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• pp.43.1-43.1
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• 2018

Spatial distribution of binding state in depth direction is investigated in a hard skin layer on soft polydimethylsiloxane (PDMS) fabricated by Ar ion beam irradiations. The hard skin layer known as a silica-like homogenous layer was composed of two layers. Impinging Ar ions transfer energy to PDMS as a function of collisional energy transfer rate, which is the maximum at surface and decreases gradually as an ion penetrates. This formed the heterogeneous hard skin layer that consists of a top-most layer and an intermediate layer. XPS depth profiling showed the existence of the top-most layer and intermediate layer. In the top-most layer, scission and cross-linking were occurred simultaneously and Si-O bond showed dissociated status, SiOx (x = 1.25 - 1.5). Under the top-most layer, there was the intermediate layer in which cross-linking is mainly occurred and Si-O bond showed silica-like binding status, SiOx (x = 1.75 - 2). And theoretical analysis which calculates the collisional energy transfer and a displacement per atom explained the thickness variation of top-most layer according to Ar ion energy from 360 eV to 840 eV.

• Textile Coloration and Finishing
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• v.24 no.4
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• pp.296-304
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• 2012

For development of dyeability, the cotton fabric was dyed repeatedly with persimmon juice by padding mangle. We evaluated the mechanical properties and hand value by Kawabata Evaluation System, and observed the change of surface morphology. The results obtained from this study were as follows. With the increase of repeating padding times of dyeing, the linearity of load-extension curve and tensile energy per unit length of the cotton fabric were increased, but the tensile resilience of fabric was decreased. The value of shear stiffness and shear hysteresis were increased. Also compression resilience and linearity of compression thickness curve were increased. The cotton fabric dyed with persimmon juice had shown the thickness and weight increase as the number of padding increase. As repeating times of dyeing with persimmon juice were increased, among the 6 hand values, the item of stiffness, anti-drape stiffness, fullness and softness were increased, while flexibility with soft feeling and crispness were greatly decreased. The amount of coated persimmon juice on the surface of the fabric was gradually increased as the padding times of dyeing. And cotton fabrics were dyed evenly with persimmon juice by padding mangle.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.11a
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• pp.528-528
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• 2007

Cu CMP widely has been using for the formation of multilevel metal interconnects by the Cu damascene process. And lower dielectric constant materials are required for the below 45nm technology node. As the dielectric constant of dielectric materials are smaller, the strength of dielectric materials become weaker. Therefore these materials are easily damaged by high down pressure during conventional CMP. Also, technical problems such as surface scratches, delamination, dishing and erosion are also occurred. In order to overcome these problems in CMP, the ECMP (electro-chemical mechanical planarization) has been introduced. In this process, abrasive free electrolyte, soft pad and low down force were used. The electrolyte is one of important factor to solve these problems. Also, additives are required to improve the removal rate, uniformity, surface roughness, defects, and so on. In this study, KOH and $NaNO_3$ based electrolytes were used for Cu ECMP and the electrochemical behavior was evaluated by the potentiostat. Also, the Cu surface was observed by SEM as a function of applied voltage and chemical concentration.

• Journal of Magnetics
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• v.17 no.3
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• pp.185-189
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• 2012

The coercivity of near single domain size $Nd_2Fe_{14}B$-type particles prepared by ball milling of HDDR-treated $Nd_{12.5}Fe_{80.6}B_{6.4}Ga_{0.3}Nb_{0.2}$ alloy was investigated. The feasibility of a surface nitrogenation for improving the coercivity stability of the fine $Nd_2Fe_{14}B$-type particles was also studied. The near single domain size $Nd_2Fe_{14}B$-type particles had a high coercivity of over 9 kOe. However, the coercivity radically deteriorated as the temperature increased in air (< 2 kOe at $200^{\circ}C$). This coercivity reduction was attributed to the soft magnetic phases, ${\alpha}$-Fe and $Fe_3B$, which formed on the surface of the fine particle due to oxidation. Surface nitrogenation of the fine particles significantly improved the stability of their coercivity. The improvement in coercivity stability was attributed to the formation of a thin nitrogenated layer on the surface of the fine $Nd_2Fe_{14}B$-type particles, which enhanced the anisotropy field and gave improved resistance to oxidation (dissociation).

• The Journal of Korean Academy of Prosthodontics
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• v.36 no.4
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• pp.549-565
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• 1998

Porcelain is considered to be one of the materials of choice for restoration where esthetics is of concern. But porcelain surface without final glazing treatment may induce undesirable results such as inflammatory response on adjacent soft tissues due to plaque accumulation and increased wear of opposing teeth. Therefore, rough porcelain surface must be smoothened by final glazing treatment or chairside polishing procedure. The purpose of this study was to compare the surface roughness among self-glazed, overglazed and polished porcelain with various polishing kit, and to detect which phase of polishing is optimal in clinic. Specimens were fabricated with Vita VMK porcelain. The surface treatment of each group was performed as follows. Group 1 : overglazing treatment Group 2 : self-glazing treatment Group 3 : polishing with the Truluster Polishing System for Porcelain(Brasseler, U.S.A.) Group 4 : polishing with the Exa Cerapol Adjustment kit (Edenta dental products, Switzerland) followed by finishing with diamond-filled polishing paste Group 5 : polishing with the Shofu Porcelain Adjustment kit (Shofu inc., Japan) followed by finishing with diamond-filled polishing paste. At each polishing steps, the measurement of Ra and Rq values were performed, and the surface was examined by scanning electron microscope. The results were as follows : 1. Overglazing treatment brought smoother surface than self-glazing treatment. 2. Polishing systems without porcelain polishing paste did not make better result than self-glazing treatment. 3. Polishing system with porcelain polishing paste made similar result to overglazing treatment. 4. Applying diamond-filled polishing paste after using polishing system which has no porcelain polishing paste produced surface as smooth as overglazing treatment does.

• Journal of Periodontal and Implant Science
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• v.46 no.6
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• pp.362-371
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• 2016

Purpose: The increasing demand for esthetically pleasing results has contributed to the use of ceramics for dental implant abutments. The aim of this study was to compare the biological response of epithelial tissue cultivated on lithium disilicate ($LS_2$) and zirconium oxide ($ZrO_2$) ceramics. Understanding the relevant physicochemical and mechanical properties of these ceramics will help identify the optimal material for facilitating gingival wound closure. Methods: Both biomaterials were prepared with 2 different surface treatments: raw and polished. Their physicochemical characteristics were analyzed by contact angle measurements, scanning white-light interferometry, and scanning electron microscopy. An organotypic culture was then performed using a chicken epithelium model to simulate peri-implant soft tissue. We measured the contact angle, hydrophobicity, and roughness of the materials as well as the tissue behavior at their surfaces (cell migration and cell adhesion). Results: The best cell migration was observed on $ZrO_2$ ceramic. Cell adhesion was also drastically lower on the polished $ZrO_2$ ceramic than on both the raw and polished $LS_2$. Evaluating various surface topographies of $LS_2$ showed that increasing surface roughness improved cell adhesion, leading to an increase of up to 13%. Conclusions: Our results demonstrate that a biomaterial, here $LS_2$, can be modified using simple surface changes in order to finely modulate soft tissue adhesion. Strong adhesion at the abutment associated with weak migration assists in gingival wound healing. On the same material, polishing can reduce cell adhesion without drastically modifying cell migration. A comparison of $LS_2$ and $ZrO_2$ ceramic showed that $LS_2$ was more conducive to creating varying tissue reactions. Our results can help dental surgeons to choose, especially for esthetic implant abutments, the most appropriate biomaterial as well as the most appropriate surface treatment to use in accordance with specific clinical dental applications.

• Geophysics and Geophysical Exploration
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• v.15 no.1
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• pp.1-7
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• 2012

To evaluate methods of determining near-surface shear-wave velocities (${\nu}_s$), we derived dispersion curves of Rayleigh waves generated by both passive and active sources in Chuncheon, Korea. Microtremors were recorded for 5 minutes in each of four triangular arrays with radii of 5 ~ 40 m. Those data were analyzed using the Spatial Autocorrelation method. Rayleigh waves were also generated by a hammer source and recorded in the same area for 2 s using 24 4.5-Hz geophones. Multichannel Analysis of Surface Waves was applied to those data. Velocity spectra were derived with relatively high signal-to-noise ratios in the frequency ranges of 7 ~ 19 and 11 ~ 50 Hz for the microtremors and synthetically generated Rayleigh waves, respectively. The resultant dispersion curves were combined as one and then input to inversion to derive shear wave velocities that were compared with a lithology log from a nearby well. Shearwave velocities in the top soil and soft-rock layers are almost constant with values of 221 and 846 m/s, respectively; while the inverse-modeled ${\nu}_s$ increases linearly in the gravelly sand, cobbles, and weathered-rock layers. If rock type is classified based on shear-wave velocity, the inversion-derived boundary between weathered-rock and soft rock may be about 5 m deeper than in the well log.

• Proceedings of the Korea Association of Crystal Growth Conference
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• 2000.06a
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• pp.165-177
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• 2000

Ceramic on ceramic total hip prostheses are developed to apply to young patients because lifetime of polyethylene joint prostheses is limited by loosening due to biological response. As mating faces of all-ceramic joint must be highly conformed to reduce stress concentration, wear properties of flat surfaces are investigated in this study. Through wear tests at 2 MPa of contact pressure and 36 mm/s of sliding velocity, alumina and silicon carbide keep low wear rate, high hardness and smooth surface. Soft surface film was detected after the test in bovine serum. This suggests that boundary lubrication is effective to reduce wear in all-ceramic joint.

• Proceedings of the Korea Association of Crystal Growth Conference
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• 2000.06a
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• pp.151-163
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• 2000

A polymerized organic-inorganic complexation route is introduced for the synthesis of oxide ceramic powders. Polyvinyl alcohol was used as the organic carrier for precursor ceramic gel. Porous and soft powders, which have a high specific surface area, were obtained after calcinating the aerated precursors. The PVA content and its degree of polymerization had a significant influence on the homogeneity of the final powder. In particular, attrition milling process with the porous powder resulted in ultra-fine particles. In the case of the preparation of cordierite powder, nano-size powder, which has a high specific surface area of 181 ㎡/g, was obtained by the milling process. The complexation route was also applied to the synthesis of unstable phase in room temperature like beta-cristobalite, high temperature form of silica.

• Proceedings of the Korean Geotechical Society Conference
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• 1999.03a
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• pp.177-184
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• 1999

In soft ground tunneling, shield method is very good for safety of neighboring structures. Although shield tunnel method has the merits to minimize the deformation of ground around tunnel, ground deformations occurred until the material grouted in tail void hardens are inevitable. In this study, the effects of micropile used as one method to restrain the settlement of neighboring structures by the tail void are studied by laboratory model tests. As a basic test result, the effective direction of micropile and the restraint rate of settlement by micropile reinforcement are known.