• Title/Summary/Keyword: Sodium iron pyrophosphate

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Pyro-synthesis of Na2FeP2O7 Nano-plates as Cathode for Sodium-ion Batteries with Long Cycle Stability

  • Song, Jinju;Yang, Juhyun;Alfaruqi, Muhammad Hilmy;Park, Wangeun;Park, Sohyun;Kim, Sungjin;Jo, Jeonggeun;Kim, Jaekook
    • Journal of the Korean Ceramic Society
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    • v.53 no.4
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    • pp.406-410
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    • 2016
  • Carbon-coated sodium iron pyrophosphate ($Na_2FeP_2O_7$) was prepared by a simple and low-cost pyro-synthesis route for further use as the cathode for Na-ion batteries. The X-ray diffraction (XRD) pattern of the sample annealed at $650^{\circ}C$ confirmed the pure triclinic phase of $Na_2FeP_2O_7$. Electron microscopy studies revealed a cross linked plate shape morphology of the $Na_2FeP_2O_7$ sample. When tested for application in Na-ion battery, the $Na_2FeP_2O_7$ cathode showed two redox pairs in the potential window of 2.0-4.0 V. The cathode registered initial discharge and charge capacities of 80.85 and 90 mAh/g, respectively, with good cycling performance.