• Title/Summary/Keyword: Soda lignin

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EVALUATIN OF NALITA WOOD(Trema orientalis) AS SOURCE OF FIBER FOR PARERMAKING

  • Jahan, M. Sarwar;Mun, Sung-Phil
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2003.11a
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    • pp.17-26
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    • 2003
  • Nalita wood(Trema orientalis) is one of the fastest growing woods in the world. It may be a viable species for pulpwood. The physical, chemical and morphological properties of Nalita were studied. The total lignin, pentosan and holocellulose content in Nalita wood were 24.7%, 22% and 81.2%, respectively. Its fiber length was about 0.92 mm, which are comparable to Acacia mangium. Nitrobenzene oxidation of Nalita wood meal indicated that the guaciayl and syringyl unit were the major constituent of Nalita lignin. Nalita produced 50% pulp yield at Kappa number 21 in soda-anthraquinone process. The strength properties of Nalita pulp were comparable to other tropical hardwood pulp. At $40_{\circ}$ SR, the breaking length, burst index, tear index and total energy absorption were 6000 m, $3.5kPa{\cdot}m^2/g\;and\;7.0mN{\cdot}m^2/g\;and\;75J/m^2$, respectively.

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Study on the Mass Transfer Behavior of AQ and Its Effectiveness during AQ-Kraft Pulping Process

  • Huang, Xiannan;Song, Hainong;Qin, Chengrong;Yoon, Sung-Hoon;Chai, Xin-Sheng
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.291-294
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    • 2006
  • Studies of the effectiveness of anthraquinone (AQ) in kraft-AQ pulping in terms of its mechanism of mass transfer have been conducted. Experiments performed have demonstrated an 'apparent solubility' of AQ in caustic solutions of wood lignin. The adsorption behavior of AQ species was also analyzed. Anthraquinone-2-sulfonic acid (AQ-S), a water-soluble derivative of AQ, showed selective adsorption on wood. A mechanism for the transport of AQ into wood chips during kraft pulping are proposed, and some explanations for previously unexplained observations are addressed.

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The Kinetics of Delignification in Oxygen·Alkali pulping (효소(酵素)·알칼리 증해(蒸解)의 탈(脱)리그닌에 관(関)한 동역학적(動力學的) 분석(分析))

  • Jo, Byoung Muk;Shin, Dong So
    • Journal of Korean Society of Forest Science
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    • v.56 no.1
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    • pp.26-50
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    • 1982
  • In order to obtain more detailed information concerning the degradation of lignin in the oxygen alkali pulping single stage isothermal delignification of pine wood meal (Pinus koraiensis S. et Z.) was studied in the oxygen alkali system at five temperature level ($110^{\circ}C$, $120^{\circ}C$, $130^{\circ}C$, $140^{\circ}C$, $150^{\circ}C$) for 60 min.. The rate constant, activation energy, oxygen and alkali consumption during the oxygen alkali delignification were determined by the kinetic method. The 2/5 of total lignin was eliminated at the start of the reaction. The delignification rate constant was about 3 times that of caustic soda pulping. The activation energy was about 1/3 lower than in caustic soda pulping. Like oxygen consumption, alkali consumption was also rapid early at the reaction and almost ceased after about 10 min.. The degradation reaction of lignin was strongly dependent upon the pH decrease of the cooking liquor by organic acid generated in pulping. The lignin in the oxygen alkali pulping degraded into lover molecular weight and had more hydrophillic properties. The methoxyl group decreased considerably at the first of oxygen alkali delignification, while the carbonyl, carboxyl and phenolic hydroxyl group increased rapidly.

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On Possible Application of Microorganism for Chemical Pulping (화학(化學)펄프 제조(製造)에 미생물(微生物)의 응용(應用) 가능성(可能性))

  • Lee, Seon-Ho;Yoon, Byong-Ho;Lee, Won-Yong
    • Journal of Forest and Environmental Science
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    • v.13 no.1
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    • pp.143-152
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    • 1997
  • The decayed wood by Fomes pini (Thore) Lloyd required a smaller H factor than the sound wood for pulping to permanganate number 20. The H factors for the decayed wood pulping by the kraft and soda processes were reduced by 15% and 17%, respectively, in the presence of 1% anthraquinone. The wood components degraded by fungi are normally more readily solubilized in alkali than the corresponding components in sound wood. The nonphenolic ${\beta}$-O-4 type lignin model compound, veratrylglycerol-${\beta}$-guaiacyl ether(I), and phenolic model compound, syringylglycerol-${\beta}$-syringyl ether(III), were degraded by the white-rot fungi to yield ${\alpha}$-guaiacoxy-${\beta}$-hydroxypropioveratrone(II) from the former and ${\alpha}$-syringyloxy-${\beta}$-hydroxypropiosyringone(IV) from the latter. Structures of the degradation products indicated that C ${\alpha}$-oxidation could occur with white-rot fungi. It has been shown that the alkaline cleavage of ${\beta}$-aryl ether bonds in the lignin units is accelerated by the presence of ${\alpha}$-carbonyl groups.

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Effect of Urea Addition on Soda Pulping of Oak Wood

  • Cho, Nam-Seok;Matsumoto, Yuji
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.285-290
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    • 2006
  • As an alternative method to solve air pollution problem and difficulty of pulp bleaching of kraft pulping process, NaOH-Urea pulping was applied. The properties of NaOH-Urea pulp were compared to those of NaOH and kraft pulps. Addition of urea in low alkali charges retarded delignification rate compared to NaOH pulping. But, in high alkali application, delignification was significantly enhanced not from the addition of urea but from the high alkalinity. It was disclosed that urea did not participate on delignification reaction by the experiment using lignin model compound. Compared to paper strengths at the same level of sheet density, NaOH-Urea pulp gave as almost same breaking length and tensile index as those of kraft pulp. Especially tensile energy absorption and burst index were higher than those of kraft pulp.

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Evaluation of Defiberation by Organosolv Ethanolamine Pulping for Integral Utilization of Oil Palm EFB (오일팜 바이오매스 EFB 고도 활용을 위한 Organosolv 에탄올아민 펄핑에 따른 섬유화 특성평가)

  • Kim, Chul-Hwan;Kim, Dong-Seop;Sung, Yong Joo;Hong, Hae-Eun;Kim, Se-Bin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.1
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    • pp.67-74
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    • 2013
  • Organosolv ethanolamine pulping for oil palm empty fruit bunches(EFB) were evaluated in this study. The screen yield by the ethanolamine pulping were higher than that by the soda pulping at the same operation conditions. The higher concentration of ethanolamine solvent resulted in the higher yield and the lower contents of residual lignin. The EFB pulp fibers were the narrower in fiber width but the higher in coarseness than those of the hardwood pulp fiber, while the fiber length of the EFB pulp fiber were similar to that of the hardwood fiber. The intrinsic zero span tensile testing showed the EFB pulp fiber by the 80% ethanolamine pulping were the stronger than the fiber by the soda pulping. The results of this study supported that the ethanolamine pulping could be used as an alternative pulping method for the EFB.

Studies on the Pulping Characteristics of Larchwood (Larix leptolepis Gordon) by Alkaline Process with Additives (첨가제(添加劑) 알칼리 법(法)에 의한 일본 잎갈 나무의 펄프화(化) 특성(特性)에 관(關)한 연구(硏究))

  • Lim, Kie-Pyo;Shin, Dong-Sho
    • Journal of the Korean Wood Science and Technology
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    • v.7 no.2
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    • pp.3-30
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    • 1979
  • Larch ($\underline{Larix}$ $\underline{leptolepis}$ GORDON), one of the major afforestation species in Korea in view of its growing stock and rate of growth, is not favored as a raw material for pulp due to its low yield of pulp and difficulties with bleaching arising from the high content of extractives in wood, and the high heartwood ratio and the active phenolics, respectively. The purpose of this study is to investigate the characteristics of firstly pulping with various additives of cellulose protector for the yield of pulp, and secondly bleaching with oxygen for chlotination-alkali extraction of five stage-sequence to reduce chlorine compounds in bleaching effluents. The kraft cooking liquor for five age groups of larchwood was 18 percent active alkali with 25 percent sulfidity and 5 : 1 liquor-to-wood ratio, and each soda liquor for sap-and heart-wood of the 15-year-old larchwood was 18 percent alkali having one of the following cellulose protectors as the additive; magnesium sulfate ($MgSO_4$, 2.5%), zinc sulfate ($ZnSO_4$, 2.5%), aluminium sulfate ($Al_2(SO_4)_3$, 2.5%), potasium iodide (KI, 2.5%), hydroquinone (HQ, 2.5%), anthraquinone (AQ, 0.1%) and ethylene diamine (EDA, 2.5%). Then each anthraquinone-soda liquor for the determination of suitable cooking condition was the active alkali level of 15, 17 and 19 percent with 1.0, 0.5 and 0.1 percent anthraquinone, respectively. The cooking procedure for the pulps was scheduled to heat to 170$^{\circ}C$ in 90 minutes and to cook 90 minutes at the maximum temperature. The anthraquinone-soda pulps from both heartwood and sapwood of 15-year-old larchwood prepared with 0.5 percent anthraquinone and 18 percent active alkali were bleached in a four-stage sequency of OCED. (O: oxygen bleaching, D: chlorine dioxide bleaching and E: alkali extraction). In the first stage oxygen in atmospheric pressure was applied to a 30 percent consistency of pulp with 0.1 percent magnesium oxide (MgO) and 3, 6, and 9 percent sodium hydroxide on oven dry base, and the bleached results were compared pulps bleached under the conventional CEDED (C: chlorination). The results in the study were summarized as follows: 1. The screened yield of larch kraft pulp did not differ from particular ages to age group, but heartwood ratio, basic density, fiber length and water-extractives contents of wood and the tear factor of the pulp increased with increasing the tree age. The total yield of the pulp decreased. 2. The yield of soda pulp with various chemicals for cellulose protection of the 15-year-old larchwood increased slightly more than that of pure soda pulp and was slightly lower than that of kraft pulp. The influence of cellulose protectors was similar to the yield of pulps from both sapwood and heartwood. The effective protectors among seven additives were KI, $MgSO_4$ and AQ, for which the yields of screened pulp was as high as that of kraft pulp. Considering the additive level of protector, the AQ was the most effective in improving the yield and the quality of pulp. 3. When the amount of AQ increased in soda cooking, the yield and the quality of the pulp increased but rejects in total yield increased with decreasing the amount of active alkali from 19 to 15 percent. The best proportion of the AQ seemed to be 0.5 percent at 17 percent active alkali in anthraquinone-soda pulping. 4. On the bleaching of the AQ-soda pulp at 30 percent consistency with oxygen of atomospheric pressure in the first stage of the ODED sequence, the more caustic soda added, the brighter bleached pulp was obtained, but more lignin-selective bleaching reagent in proportion to the oxygen was necessary to maintain the increased yield with the addition of anthraquinone. 5. In conclusion, the suitable pulping condition for larchwood to improve the yield and quality of the chemical pulp to the level for kraft pulp from conventional process seemed to be. A) the selection of young larchwood to prevent decreasing in yield and quality due to the accumulation extractives in old wood, B) the application of 0.5 percent anthraquinone to the conventional soda cooking of 18 percent active alkali, and followed, C) the bleaching of oxygen in atmospheric pressure on high consistency (30%) with 0.1 percent magnesium oxide in the first stage of the ODED sequence to reduce the content of chlorine compounds in effluent.

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Effect of Boiling Methods on the Physicochemical Properties of Su Ri Chwi(Synurus palmatopinnonatifidus var. indivisus KITAM.) (삶는 방법에 따른 수리취(Synurus palmatopinnonatifidus var. indivisus KITAM.)의 이화학적 특성)

  • Kim, Myung-Hee;Park, Yong-Kon;Jang, Myung-Sook
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.21 no.6
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    • pp.701-705
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    • 1992
  • The effect of different boiling methods(with distilled water, 1% salt added water and 1% sodium bicarbonate added water) on the physicochemical properties of Su Ri Chwi (Synurus palmatopinnonatifidus var. indivisus KITAM.) were investigated. The addition of 1% sodium bicarbonate (baking soda) to the boiling water resulted in an increase in the pH of effluent. The green value of cooked Su Ri Chwi was simillar to the raw material. Su Ri Chwi cooked in 1% sodium bicarbonate added for 10minutes retained higher chlorophyll and vitamin C contents than those of Su Ri Chwi treated in distilled water and 1% salt water for 30minutes. 70% of the water-soluble proteins in raw Su Ri Chwi was albumin. However, albumin was decreased by the method used. The contents of glutelin, globulin, and prolamin were increased by the cooking, vice versa. The contents of NDF, ADF, cellulose, and lignin were decreased regardless of the method used, on the other hand, the content of hemicellulose was increased.

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Preparation of Microcrystalline Cellulose by using Sawdust of Tropical Hardwood Nyatoh (열대활엽수 니아토 제재 부산물을 활용한 미세결정 셀룰로오스의 제조)

  • Sung, Yong-Joo;Lee, Ji-Young;Lee, Han-Ba-Loh;Kim, Sung-Jun;Lee, Joon-Woo;Kim, Se-Bin;Park, Gwan-Soo
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.3
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    • pp.59-65
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    • 2011
  • The saw dust of tropical hardwood, Nyatoh(Palaquium Spp.), was used as a raw material for the preparation of the high valued microcrystalline cellulose(MCC). Three pulping methods, soda pulping, Kraft pulping, and acid-sulfite pulping were applied to obtain cellulose from the saw dust. The residual impurities were removed with the additional bleaching processes: (A) $ClO_2{\rightarrow}H_2O_2$; (B) $ClO_2{\rightarrow}O_3$; (C) $O_3$. For the acid treatment for MCC preparation, the $H_2SO_4$, with three concentration, 20%, 40%, 60% were applied and the effects of $H_2SO_4$ concentration on the properties of MCC were evaluated. The results indicated that the MCC obtained by acid-sulfite pulping followed with $O_3$ treatment and 40% $H_2SO_4$ treatment showed less residual lignin, higher brightness and crystallinity than that of Avicel MCC.

Studies on the Asplund Pulping of Wood for Paper Pulp(II) -Effect of some cellulose stabilizers added to the alkaline chip-treatment and the peroxide bleaching on the quality of larchwood asplund pulps- (제지용(製紙用) 아스플룬드펄프 제조(製造)에 관한 연구(II) -일본 잎갈나무��의 알카리 전처리(前處理)와 아스플룬드 펄프의 과산화물(過酸化物) 표백(漂白)에서 셀룰로오스 안정제(安定劑)의 영향(影響)에 관하여-)

  • Lim, Kie-Pyo
    • Journal of the Korean Wood Science and Technology
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    • v.9 no.3
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    • pp.7-15
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    • 1981
  • A Japanese larch has been reforested very much in Korea, but it is not used as a wood resources for paper pulp by now. So this study is carried out to utilize the larchwood for paper pulp manufacture through the Asplund pulping process. The experiment on increasing in the brightness of the pulp is made through the addition of $MgSO_4$, $ZnSO_4$, $Al_2(SO_4)_3$, and KI as a cellulose stabilizer in chip treatment with caustic soda which is followed by high-temperature defibration and conventional peroxide bleaching (5% NaOH plus 2% additive salt per wood in cold pretreatment), or in high-consistency (30%) pulp bleaching of hydrogen peroxide and peracetic acid (100% acitve oxygen per lignin) for conventional one. The results obtained are as follows: 1. The solution of 0.5% additive salts had different pH by the sort of bases that was pH 5.7 in $MgSO_4$, liquor, pH 4.9 for $ZnSO_4$, and pH 2.9 for $Al_2(SO_4)_3$, and in the precepitation of bases which ranged to pH 6-13 for $MgSO_4$, pH 5-12 for $ZnSO_4$, and pH 3-10 for $Al_2(SO_4)_3$. 2. The cellulose stabilizer affective in high-consistency peroxide bleaching was KI, $MgSO_4$, and $ZnSO_4$, but has made a little improvement in de lignification and brightness of pulp in comparison with no addition. 3. The higher alkalinity in the chip treatment has made the higher strength and brightness of larchwood Aspiund pulp instead of downing the pulp yield. And the effective compound for cellulose stabilizer in caustic soda pretreatment of chip was $ZnSO_4$, $Al_2(SO_4)_3$ and KI in order for the conventional peroxide bleaching after Asplund pulping. 4. Therefore, the more effective additives for cellulose stabilization in high-temperature defibration of larchwood suppose to be $ZnSO_4$, $Al_2(SO_4)_3$, and KI, while KI and $MgSO_4$ for peroxide bleaching.

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