• 청정기술
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• 제16권1호
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• pp.46-50
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• 2010

본 연구에서는 새집증후군의 대표적 원인물질인 수중 부유 톨루엔을 효율적으로 분해하기 위해 Sn원소를 티타니아 골격에 삽입하여 고온 고압에서 용매열(solvothermal)법으로 Sn-$TiO_2$ 나노 광촉매를 제조하였다. 제조한 Sn-$TiO_2$의 물리적 특성은 X-ray 회절분석법, 투과전자현미경, 주사전자현미경, 자외선-가시선 분광 광도계를 통하여 분석하였다. Sn-$TiO_2$의 광촉매 활성은 수중 부유 톨루엔 광분해반응을 통해 확인하였고, 반응 전후의 수중 부유 톨루엔 농도는 자외선-가시선 분광광도계를 이용하여 측정하였다. 수중 부유 톨루엔 광분해반응 결과 0.01 mol% Sn-$TiO_2$촉매가 순수 $TiO_2$ (anatase) 광촉매보다 활성이 향상되었으며. 500ppm 수중 부유 톨루엔은 300분 이내에 완전히 분해되었다.

• Journal of Welding and Joining
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• 제19권4호
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• pp.406-412
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• 2001

This study is focussed on the numerical prediction of the thermal fatigue life of a ${\mu}BGA$(Micro Ball Grid Array) solder joint. Numerical method is used to perform three-dimensional finite element analysis for Sn-37mass%Pb. Sn-3.5mass%Ag solder alloys during the given thermal cycling. Strain values, along with the result of mechanical fatigue tests for solder alloys were then used to predict the solder joint fatigue life using the Coffin-Manson equation. In this study, a practical correlation for the prediction of the thermal fatigue life is suggested by using the dimensionless variable $\gamma$. As a result. it could be found that Sn-3.5mass%Ag has longer fatigue life than Sn-37mass%Pb in low cycle fatigue. In addition. the result with ${\gamm}ashow$a good agreement with the FEA results.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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• pp.175.1-175.1
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• 2015

CuSn thin films were deposited by rf magnetron co-sputtering method with pure Cu and Sn metal targets with a variety of rf powers. CuSn thin films were studied with a surface profiler (alpha step), X-ray photoelectron spectroscopy (XPS), X-ray induced Auger electron spectroscopy (XAES), X-ray diffraction (XRD), and contact angle measurement. The thickness of CuSn thin films was fixed at $200{\pm}10nm$ and deposition rate was calculated by the measured with a surface profiler. From the survey XPS spectra, the characteristic peaks of Cu and Sn were observed. Therefore, CuSn thin films were successfully synthesized on the Si (100) substrate. The oxidation state and chemical environment of Cu and Sn were investigated with the binding energy regions of Cu 2p XPS spectra, Sn 3d XPS spectra, and Cu LMM Auger spectra. Change of the crystallinity of the films was observed with XRD spectra. Using contact angle measurement, surface free energy (SFE) and wettability of the CuSn thin films were studied with distilled water (DW) and ethylene glycol (EG).

• 한국분말재료학회지
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• 제13권1호
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• pp.46-51
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• 2006

Through the volume change of Sn in a low-temperature phase transformation, the Sn nanopowder with high, purity, was fabricated by an economic and eco-friendly process. The fine cracks were spontaneously generated. in, Sn ingot, which was reduced to powders in the repetition of phase transformation. The Sn nanopowder with 50 run in size was obtained by the 24th repetitions of phase transformation by low-temperature and ultrasonic treatments. Also, the $SnO_2$ powder was fabricated by the oxidation of the produced Sn powder to the ingot and milled by the ultrasonic milling method. The $SnO_2$ nanopowder of 20 nm in size was fabricated after the milling for 180 h.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2001년도 추계학술발표대회 개요집
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• pp.147-148
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• 2001

• 센서학회지
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• 제18권6호
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• pp.417-422
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• 2009

The problems associated with the synthesis, characterization and application of $SnO_2$-Au nanocomposites for the optimization of conductometric gas sensors have been discussed in this report. Nanocomposites have been synthesized on the surface of $SnO_2$ films using successive ionic layer deposition(SILD) method. It has been shown that the proposed approach to surface modification of metal oxide films is an excellent method for the optimization of the operating characteristics of $SnO_2$-based gas sensors, being developed for the detection of reducing gases as well as ozone.

• Bulletin of the Korean Chemical Society
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• 제35권8호
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• pp.2331-2334
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• 2014

$Cu_2SnSe_3$ (CTSe) and $Cu_2ZnSnSe_4$ (CZTSe) nanoparticles were synthesized by sonochemical reactions under multibubble sonoluminescence (MBSL) conditions. First, $Cu_2SnSe_3$ nanoparticles were synthesized by the sonochemical method with an 85% yield, using CuCl, $SnCl_2$, and Se. Second, ZnSe was coated on the CTSe nanoparticles by the same method. Then, they were transformed into CZTSe nanoparticles of 5-7 nm diameters by heating them at $500^{\circ}C$ for 1 h. The ratios between Zn and Sn could be controlled from 1 to 3.75 by adjusting the relative concentrations of CTSe and ZnSe. With relatively lower Zn:Sn ratios (0.75-1.26), there are mostly CZTSe nanoparticles but they are believed to include very small amount of CTS and ZnSe particles. The prepared nanoparticles show different band gaps from 1.36 to 1.47 eV depending on the Zn/Sn ratios. In this sonochemical method without using any toxic or high temperature solvents, the specific stoichiometric element Zn/Sn ratios in CZTSe were controllable on demand and their experimental results were always reproducible in separate syntheses. The CZTSe nanoparticles were investigated by using X-ray diffractometer, a UV-Vis spectrophotometer, scanning electron microscope, Raman spectroscopy, and a high resolution-transmission electron microscope.

• Bulletin of the Korean Chemical Society
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• 제33권10호
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• pp.3383-3386
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• 2012

SnS thin films were deposited on glasses through metal organic chemical vapor deposition (MOCVD) method at relatively mild conditions, using bis(3-mercapto-1-propanethiolato) tin(II) precursor without toxic $H_2S$ gas. The MOCVD process was carried out in the temperature range of $300-400^{\circ}C$ and the average grain size in fabricated SnS films was about 500 nm. The optical band gap of the SnS film was about 1.3 eV which is in optimal range for harvesting solar radiation energy. The precursor and SnS films were characterized through infrared spectroscopy, nuclear magnetic resonance spectroscopy, DIP-EI mass spectroscopy, elemental analyses, thermal analysis, X-ray diffraction, and field emission scanning electron microscopic analyses.

• 한국수소및신에너지학회논문집
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• 제22권4호
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• pp.504-511
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• 2011

Nano-sized Sn powder was prepared by pulsed wire evaporation method. The Sn powder and carbon black were charged in jar and ball milled. The milling time was varied with 10 min., 1h, 2h, and 4h, respectively. The milled powders were dried and the shape and size were observed by FE-SEM. Nano-sized Sn powders were plastic-deformed and agglomerated by impact force of balls and heat generated during the SPEX milling. The agglomerated Sn powder also consisted of many nano-sized particles. Initial discharge capacities of milled Sn electrode powders with carbon powder were milled for 10 min., 1h, 2h, and 4h were 787, 829, 827, and 816 mAh/g, respectively. After 5 cycle, discharge capacities of Sn electrode powders with carbon powder milled for 10 min., 1h, 2h, and 4h decreased as 271, 331, 351, and 287 mAh/g, respectively. Because Sn electrode powders milled for 2h constist of uniform and fine size, the cyclability of coin cell made of this powders is better than others.

• 한국통신학회논문지
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• 제24권7B호
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• pp.1322-1330
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• 1999

B-ISDN과 같은 초고속 네트워크에서 전송오류의 주요원인은 과잉밀집 상태에 있어서의 버퍼 오버플로우이며 이로 인해 셀 손실을 야기한다. 기존의 통신 프로토콜은 손실된 패킷이나 전송에러들을 다루기 위해 ARQ와 같이 오류회복을 위해 재전송 기법을 사용하고 있으나 이러한 ARQ 방법들은 재전송으로 인한 전송 지연시간이 매우 크기 때문에 초고속 네트워크에서는 적합하지 않다. 따라서 본 논문은 이러한 문제를 줄이기 위하여 B-ISDN에서 FEC를 이용한 셀손실 회복기법을 제안하였다. 제안된 기법은 새로운 순서번호(SN)인 SN*를 이용하여 연속적인 셀손실을 식별한다. SN*는 SN이외에 다른 두 개의 필드(ST, LI)를 조합하여 생성한 순서번호로 그 특성에 따라 가산적(additive) SN*와 승산적(multiplicative) SN*로 구분된다.이러한 연구결과로 FEC는 네트워크 노드상에 버퍼 오버플로우로 인한 셀손실이 발생한 경우에 유용하며 B-ISDN과 같은 초고속 통신망에서의 셀손실 회복에 효과적으로 사용할 수 있는 오류에 기법임을 보여주고 있다. 본 논문에서 제안된 효율적인 셀손실 회복기법은 향후 ATM 네트워크에서의 우선순위 제어, 과잉밀집 제어 등의 연\ulcorner에 효율적으로 사용될 수 있다.