• Journal of Korean Society on Water Environment
• /
• v.23 no.1
• /
• pp.138-143
• /
• 2007

This study goes in for the observation of the characteristics of nitrogen removal from swine wastewater by struvite crystallization. In addition, the struvite formation potential in supernatants after struvite crystallization was investigated. In the study for nitrogen removal by struvite crystallization, the effects of pH and molar ratio of magnesium (Mg) injected using bittern as Mg source were investigated. Also, the potential of struvite formation in the supernatant with amount of Mg added was carefully observed. As the results, the optimum pH in the removal of nitrogen was 8.8 and sludge volume was increased as pH was raised from 7 to 12 under the condition that the molar ratio of $Mg^{2+}$ to ${NH_4}^+$-N to ${PO_4}^{3-}$-P was 1:1:1. An optimum removal efficiency of ammonia-N was observed at 1 molar ratio of Mg to ${NH_4}^+$-N, showing no further increase at over 1 molar ratio and dramatical deterioration at under 1 molar ratio. However, the sludge volume was increased by increasing the molar ratio of Mg. In the experiments for the potential of struvite formation in the supernatants, initial -log([$Mg^{2+}$][${NH_4}^+$][${PO_4}^{3-}$]) value was much lower than $pK_{sp}$ and gradually reached $pK_{sp}$ at 2 days, as the molar ratio of Mg increased over 1.2. At 31 days, -log([$Mg^{2+}$][${NH_4}^+$][${PO_4}^{3-}$]) value was returned to the initial value. In addition, the supernatants had a potential precipitation of hydroxylapatite due to calcium contained in bittern, $K_2Mg(SO_4)_3$ and $K_3Na(SO_4)_2$ resulting from the decrease of sodium and potassium in supernatants formed after struvite crystallization as times go by. Based on the results, it appears that some retention time and proper dosage of Mg may be needed for the prevention of scale in pipe line.

• Economic and Environmental Geology
• /
• v.37 no.1
• /
• pp.107-111
• /
• 2004

This study was undertaken to summarize of the efficiencies of the passive treatment system and suggest future studies for the solution of mine drainage problem. Flow rates of mine drainage from the abandoned coal mines are about 80,000 ton/day. Contaminated mine drainages over about 50 ton/day of flow rate were treated by passive treatment facilities such as Successive Alkalinity Producing Systems(SAPS), oxidation pond and oxic wetland. Chemical analysis for 13 passive coal mine treatment facilities showed that SAPS was the core of treatment facilities because the variation of Fe removal rates was relatively smaller than any other processes and re-leaching of Fe was not measured. The performance and life of SAPS depended on decrease in permeability and retention time due to accumulation of sludge. It is inferred that upgrade of design of the passive treatment system and in-situ treatment using underground void will be necessary for the amelioration of the mine drainage with high metal loading rates.

• Journal of Korean Society of Water and Wastewater
• /
• v.21 no.3
• /
• pp.331-339
• /
• 2007

The purpose of this study was to investigate the biodegradability and performance of organic removal and methane production rate when treating piggery wastewater using a pilot scale two-phase anaerobic system operated up to a volumetric rate of $10m^3/day$. The pilot scale two-phase anaerobic process is consisted of a continuous-flow stirred-tank reactor (CFSTR) for the acidification phase and an Upflow Anaerobic Sludge Blanket reactor (UASB) for the methanogenesis. The acidogenic reactor played key roles in reducing the periodically applied shock-loading and in the acidification of the influent organics. The acidogenic CFSTR was operated at organic loading rates (OLR) between 1.8 and $14.4kgCOD/m^3{\cdot}day$, and the UASB reactor was operated between 0.5 and $5.6kgCOD/m^3{\cdot}day$. A stable maximum biogas production rate was $81m^3/day$ and the methane conversion rate of the organic matter varied from 0.30 to $0.42L\;CH_4/g\;COD_{removed}$(0.40) at hydraulic retention time (HRT) above 3.5days. The methane contents ranged from 73 to 82% during the experimental period. It is known that most of the removed organic matter was converted to methane gas, and the produced biogas might be high quality for its subsequent use.

• Journal of Korean Society of Environmental Engineers
• /
• v.22 no.12
• /
• pp.2239-2245
• /
• 2000

For the treatment of wastewater being discharged in large quantities as in these modern times, qualitative and quantitative concepts should be introduced in consideration of the recycling. In view of a qualitative concept, high rate aeration process is known as the most effective process up to now. However, Lee suggested UHR process showing the superiority over high rate process in treatment rate and quantity. Therefore, this study was performed to investigate the basic sphere of design and treatment quality, such as applicable $BOD_5$-loading and influent wastewater concentration of UHR process, based on Lee's suggestions1). Consequently, this process showed applicable $BOD_5$-loading of $2.2{\sim}7.0kg-BOD_5/kg-MLSS{\cdot}day$, exceeding three times or more of high rate process with maximum applicable loading of $2.25kg-BOD_5/kg-MLSS{\cdot}day$. Meanwhile, with the range of influent wastewater concentration from 200 to 450 mg/L. it showed the treatment rate from 94.7 to 97.3%, it indicated very good condition. In view of quantitative concept of treatment, UHR process is considered an epoch-making treatment process being superior to existing ones.

• Journal of Korean Society on Water Environment
• /
• v.23 no.5
• /
• pp.689-696
• /
• 2007

Kinetic analysis was important to develope the biological nutrient removal process effectively. In this research, anoxic-anaerobic-aerobic system was operated to investigate kinetic behavior on the nutrient removal reaction. Nitrification and denitrification were important microbiological reactions of nitrogen. The kinetics of organic removal and nitrification reaction have been investigated based on a Monod-type expression involving two growth limiting substrates : TKN for nitrification and COD for organic removal reaction. The kinetic constans and yield coefficients were evaluated for both these reactions. Experiments were conducted to determine the biological kinetic coefficients and the removal efficiencies of COD and TKN at five different MLSS concentrations of 5000, 4200, 3300, 2600, and 1900 mg/L for synthetic wastewater. Mathematical equations were presented to permit complete evaluation of the this system. Kinetic behaviors for the organic removal and nitrification reaction were examined by the determined kinetic coefficient and the assumed operation condition and the predicted model formulae using kinetic approach. The conclusions derived from this experimental research were as follows : 1. Biological kinetic coefficients were Y=0.563, $k_d=0.054(day^{-1})$, $K_S=49.16(mg/L)$, $k=2.045(day^{-1})$ for the removal of COD and $Y_N=0.024$, $k_{dN}=0.0063(day^{-1})$, $K_{SN}=3.21(mg/L)$, $k_N=31.4(day^{-1})$ for the removal of TKN respectively. 2. The predicted kinetic model formulae could determine the predicted concentration of the activated sludge and nitrifier, investigate the distribution rate of input carbon and nitrogen in relation to the solid retention time (SRT).

• Journal of Korean Society on Water Environment
• /
• v.26 no.1
• /
• pp.160-167
• /
• 2010

In this research, the performance evaluation between an alternating type process and a recirculating type process was investigated by using mathematical models. The Advanced Phase Isolation Ditch (APID) process and the $A^2/O$ process were selected the target processes of the alternating type and recirculating type, respectively. For more quantitative evaluation, 5 performance indexes which included economy and energy efficiency as well as effluent quality were used, and various disturbance conditions of influent were given to the process models. As simulation results, the APID process which had the specific operation modes to use the organic matter in influent effectively showed higher efficiency of denitrification than the $A^2/O$ process. In the case of effluent TSS, the $A^2/O$ process that the retention time in reactors could be maintained stably was more effective than the APID process. In the cases of various disturbance condition, although it was identified that both two processes had similar effluent quality, the sludge production of the $A^2/O$ process showed lower than that of the APID process while the APID process showed higher energy efficiency.

• Journal of Wetlands Research
• /
• v.16 no.3
• /
• pp.363-370
• /
• 2014

Sewage distribution rate in rural area is only 50% level than urban area. Normally, rural area sewage is focused on the reason of water source pollution owing to rural areas were located in near water source. The Korea government is effort to manage the rural community sewage for protect the water source. In this study conducted analysis on rural community sewage treatment plant(RCSTP) nutrient treatment efficiency using operation results on winter season. Research areas are newly constructed in Bong-hwa, Yeong-yang and An-dong areas which are located in near An-dong Im-ha Dam. Based on operation result, sludge retention time(SRT) and mixed liquer suspended solid(MLSS) were effected on RCSTP nutrient treatment efficiency. Thus, it is necessary to manage of operation condition for nutrient treatment efficiency in RCSTP during the winter season.

• 한국신재생에너지학회:학술대회논문집
• /
• 2006.06a
• /
• pp.465-469
• /
• 2006

Two mesophilic trickling bed bioreactors filled with two different types of media, hydrophilic- and hydrophobic-cubes, were designed and tested for hydrogen production via anaerobic fermentation of sucrose. Each reactor consisted of a column packed with polymeric cubes and inoculated with heat-treated sludge obtained from anaerobic digestion tank. A defined medium containing sucrose was fed with changing flow rate into the capped reactor, hydraulic retention time and recycle rate. Hydrogen concentrations in gas-phase were constant, averaging 40% for all conditions tested. Hydrogen production rates increased up to $10.5 L{\cdot};h^{-1}{\cdot}L^{-1}$ of reactor when influent sucrose concentrations and recycle rates were varied. Hydrophobic media provided higher value of hydrogen production rate than hydrophilic media at the same operation conditions. No methane was detected when the reactor was under a normal operation. The major fermentation by-products in the liquid effluent of the both trickling biofilters were acetate and butyrate. The reactor filled with hydrophilic media became clogged with biomass and bio gas, requiring manual cleaning of the system, while no clogging occurred in the reactor with hydrophobic media. In order to make long-term operation of the reactor filled with hydrophilic media feasible, biofilm accumulation inside the media in the reactor with hydrophilic media and biogas produced from the reactor will need to be controlled through some process such as periodical backwashing or gas-purging. These tests using trickling bed biofilter with hydrophobic media demonstrate the feasibility of the process to produce hydrogen gas in a trickle-bed type of reactor. A likely application of this reactor technology could be hydrogen gas recovery from pre-treatment of high carbohydrate-containing wastewaters.

• Korean Journal of Ecology and Environment
• /
• v.42 no.2
• /
• pp.153-160
• /
• 2009

A phytoplankton cultivation system was installed and operated for removal of nutrients from stream water polluted by nonpoint source pollution. The system was a continuous-flow culture comprising a phytoplankton tank that received inflow from a storage reservoir. When the system was operated as a batch culture for the purpose of determining hydraulic retention time (HRT), the proper HRT value was three days, and the removal rate of TP and TN averaged 70% and 44%, respectively. When the system was operated with the continuous flow from a stream for 45 days, 53.9% of TP and 53.1% of TN were removed as sludge. Due to active growth of phytoplankton, pH and dissolved oxygen in the phytoplankton tank were extremely high, reaching 10.8 and 16mg $L^{-1}$, respectively. It was concluded that nutrients can be effectively removed from polluted stream waters by cultivating phytoplankton.

• Transactions of the Korean hydrogen and new energy society
• /
• v.17 no.4
• /
• pp.379-388
• /
• 2006

Two mesophilic trickling bed bioreactors filled with two different types of media, hydrophilic- and hydrophobic-cubes, were designed and conducted for hydrogen production under the anaerobic fermentation of sucrose. Each bioreactor consisted of the column packed with polymeric cubes and inoculated with heat-treated sludge obtained from anaerobic digestion tank. A defined medium containing sucrose was fed by the different hydraulic retention time(HRT), and recycle rate. Hydrogen concentrations in gas-phase were constant, averaging 40% of biogas throughout the operation. Hydrogen production rate was increased till $10.5\;L{\cdot}h^{-1}{\cdot}L^{-1}$ of bioreactor when influent sucrose concentrations and recycle rates were varied. At the same time, the hydrogen production rate with hydrophobic media application was higher than its hydrophilic media application. No methane was detected when the reactor was under a normal operation. The major fermentation by-products in the liquid effluent of the both trickling biofilters were acetate, butyrate and lactate. In order to run in the long term operation of both reactor filled with hydrophilic and hydrophobic media, biofilm accumulation on hydrophilic media and biogas produced should be controlled through some process such as periodical backwashing or gas-purging. Four sample were collected from each reactor on the opposite hydrogen production rate, and their bacterial communities were compared by terminal restriction fragment length polymorphism (T-RFLP) analysis of PCR products generated using bacterial 16s rRNA gene primers (8f and 926r). It was expressed a marked difference in bacterial communities of both reactors. The trickling bed bioreactor with hydrophobic media demonstrates the feasibility of the process to produce hydrogen gas. A likely application of this reactor technology can be hydrogen gas recovery from pre-treatment of high carbohydrate-containing wastewaters.