• Journal of Korean Society of Environmental Engineers
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• v.37 no.1
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• pp.60-68
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• 2015

The study of waste activated sludge (WAS) solubilization has been increased for sludge volume reduction and enhancing the efficiency of anaerobic digestion. Microwave (MW)-assisted solubilization is an effective method for the solubilization of WAS because this method can lead to thermal, nonthermal effect and ionic conduction by dielectric heating. In this study, the solubilization of WAS by MW heating and conductive heating (CH) was compared and to enhance the MW-assisted solubilization of WAS at low MW output power, chemical agents were applied such as $H_2SO_4$ as the strong acid and $CaCl_2$, NaCl as the ionic materials. Compared to the COD solubilization of WAS by CH, that by MW heating was approximately 1.4, 6.2 times higher at $50^{\circ}C$, $100^{\circ}C$, respectively and the highest COD solubilization of WAS was 10.0% in this study of low MW output power condition. At the same MW output power and reaction time in chemically agents assisted experiments, the COD solubilization of WAS were increased up to 18.1% and 12.7% with the addition of $H_2SO_4$ and NaCl, however, that with the addition of $CaCl_2$ was 10.7%. This result might be due to the fact that the precipitation reaction occurred by calcium ion ($Ca^{2+}$) and phosphate ion (${PO_4}^{3-}$) produced in WAS after MW-assisted solubilization. In this study, $H_2SO_4$ turned out to be the optimal agent for the enhancement of MW efficiency, the addition of 0.2 M $H_2SO_4$ was the most effective condition for MW-assisted WAS solubilization.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.2
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• pp.113-119
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• 2011

The study purpose was to examine an effect of zero emission of excess sludge on biological reactor and treated water quality within the biological reactor in the process of biological treatment combined with excess sludge reduction system with ozone. Under an ozone injection rate 0.03 g $O_3/g$ SS, Sludge Disintegration Number (SDN) 3 and less than pH 4 as pre-treatment process, it was possible to maintain a stable biological treatment process without sludge disintegration. In the test of $OUR_{max}$, of sludge, its value was hardly under the condition of ozone injection rate 0.03 g $O_3/g$ SS. There were almost no changes of MLVSS/MLSS within biological reactor followed by a solubilization of excess sludge. Accumulation of microorganism within biological reactor was also not observed. After solubilization of excess sludge, an increase for organic matter and SS concentrations of an effluent was not observed and T-N concentration was reduced by increasing nitrification and denitrification rate within biological reactor. Most of T-P was not removed by zero emission of excess sludge and was leaked by being included in effluents.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.12 no.2
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• pp.979-984
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• 2011

Although sludge production has been increased due to the number of the wastewater treatment plants expanded, needs of the techniques for the sludge reduction and disposal has been issued importantly because the sludge dumping to ocean is prohibited from 2012 by the London Dumping Convention. Therefore, the sludge solubilization using electrolysis as an alternative techniques for the sludge disposal was carried out in this study. Iridium coated titanium based insoluble electrodes were used and 20 volt was applied to the electrolysis reactor using DC power supply. Supernatants of the treated sludge was monitored: The soluble COD, TN, TP of it was increased to 151%, 22% and 6% respectively. And the sludge floc size distribution was changed, that is, the flocs ranged from 0.1 to 1.0 ${\mu}m$ were increased. All of these results indicate that the cells were lysed and the internal matters bursted out of the cell after electrolysis. As well as the reduction of the sludge production, the soluble organic matters from the cells could be used as an external carbon sources in the advanced wastewater treatment plants.

• Journal of the Korea Organic Resources Recycling Association
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• v.27 no.2
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• pp.13-18
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• 2019

Sewage sludge treatment is increasing every year due to improvement of living and urbanization. However, interest in anaerobic digestion which is one of the recycling technology. There is anaerobic digestion of increasing due to limitations of ocean dumping and final disposal. But, the limit of anaerobic digestion efficiency due to the advanced treatment of sewage has been limited, and studies for solubilization technology have been actively conducted. Therefore, in this study, we aimed to investigate the variation of generation of scum and the solubilization efficiency in the application of pre-treatment of ozone reaction and the change of properties of digested sludge with wet milling. There are results of VS/TS increased by 4.4% and $SCOD_{cr}/TCOD_{cr}$ increased by 9.4% by wet milling alone. In addition, the increase of the specific surface area due to which the reduction of the particle size of the solid content of the sludge in the ozone reaction caused by wet milling decreased the generation rate of scum at 14.3% and increased VS/TS at 2.1%, compared with the ozone reaction alone. From these results, it is expected that the application of wet milling can be increased the contact efficiency with solids in the sludge during ozone reaction with suppress scum and increase the efficiency of the subsequent process in anaerobic digestion.

• Journal of Environmental Science International
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• v.23 no.5
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• pp.853-859
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• 2014

The purpose of this study was to improve low digestibility in anaerobic digestion facility of the sewage treatment plant. To perform this research, sludge digestion and digestion gas purification facilities in sewage treatment plant was applied. In the result of this study, it was very effective for sludge reduction from the improvement of digestive efficiency. In addition, it was confirmed that high purity $CH_4$ (methane) was produced. This results can be useful as basic data to improve the low digestibility in anaerobic digestion processes.

• Journal of Wetlands Research
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• v.15 no.2
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• pp.165-170
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• 2013

Pilot scale study was carried out to produce Volatile Fatty Acids with primary sludge from municipal wastewater treatment plant. An acid fermenter was operated at pH 9, $35^{\circ}C$, SRT of 3.5-4.25d, using a final effluent as elutriating water(Mode-I) and pH 9, SRT 5d, temperature of $35^{\circ}C$(Mode-II), $55^{\circ}C$(Mode-III), using a primarily treated water as elutriating water. Although solubilization rate was enhanced with the increase of temperature, the VFAs production rate was decreased. The VS reduction was shown approximately 56%, and the sludge volume reduction was 93%. The optimal conditions for solubilization was obtained at pH 9, $35^{\circ}C$ and SRT of 5d.

• Journal of the Korea Organic Resources Recycling Association
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• v.10 no.3
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• pp.68-73
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• 2002

Acidogenic fermentation of primary sludge was investigated for the solution to reduce the sewage sludge and develope external carbon source for BNR process. In a viewpoint to use existing anaerobic digestion tanks, we didn't change environmental factors such as reactor configuration, temperature, pH and investigate the variation of solubilization rates, acidification rates and environmental factors which affected by the variation of HRT. The average solubilization rates were 0.0309 and $0.0204mgSCOD_{prod.}/mgICOD_{inf.}$ at a HRT of 3 and 1.5 days, respectively. The average acidification rates were 0.0068mg HAc/mg $TCOD_{inf.}$ and 0.0652mg HAc/mg $VSS_{destroyed}$ at a HRT of 3day. At a HRT of 1.5 days the average acidification rates were 0.0060mg HAc/mg $TCOD_{inf.}$ and 0.0346mg HAc/mg $VSS_{destroyed}$. For the period of experiments alkalinity and pH were properly maintained without artificial adjusting.

• Journal of the Korea Organic Resources Recycling Association
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• v.24 no.3
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• pp.35-43
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• 2016

COD properties of waste activated sludge (WAS) were investigated for various solubilization rate of mechanical pretreatment method in anaerobic digestion process. Inert COD was 37.0% of total COD in untreated WAS. Particulate biodegradable COD was converted to soluble biodegradables and particulate unbiodegradables as solubilization was processed. Particulate unbiodegradable portion of COD in WAS can be increased as particulate biodegradable portion is decreased in case of relatively long SRT of biological treatment. Thus, COD properties of WAS should be investigated in case of relatively low particulate biodegradable COD, because of possible low effect of solubilization. COD removal rate in anaerobic digester was enhanced as much as 2.1% and 15.1% for solubilization rate 5% and 35% due to pretreatment, respectively. COD removal rate was increased from 25% to 40%, and methane gas generation was increased from $607m^3/d$ to $907m^3/d$ as particulate COD of WAS was solubilized to 35% in pretreatment facilities.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.188.1-188.1
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• 2011

0.5 ton/day 용량의 장비를 이용하여 초음파와 고전압 단독 처리에 의한 슬러지 용존화율을 조사하였다. 또한 초음파와 고전압을 병행한 방법에 의한 슬러지 용존화율을 조사하였다. 그 결과 초음파와 고전압을 개별적으로 적용하였을시 나타나는 슬러지 용존화율 보다 이 둘을 병행하여 함께 처리했을 시에 나타나는 슬러지 용존화율에 기대 이상의 상승효과가 있는 것을 알 수 있었다.

• New & Renewable Energy
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• v.1 no.2 s.2
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• pp.60-72
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• 2005

The effect of alkaline pre-treatment on the solubilization of waste activated sludge(WAS) was investigated, and the biodegradability of WAS, pretreated WAS, [PWAS], food waste and two types of mixture were estimated by biochemical methane potential [BMP] test at $35^{\circ}C$. The biodegradability of PWAS and mixture waste were significantly improved due to the effect of alkaline hydrolysis of WAS. An alkaline pre-treatment was identified to be one of the useful pre-treatment for improving biodegradability of WAS and mixture waste. In high-rate anaerobic co-digestion system coordinate with an alkaline pre-treatment in process, the digesters were operated at the HRT of 5, 7, 10 and 13 days with a mixture of FW $50\%\;and\;PWAS\;50\%,\;$In term of $CH_4$ content, VS removal and specific methane production [SMP] which are the parameters in the performance of digester, the optimum operating condition was found to be a HRT of 7 days and a OLR of 4.20g/L-day with the highest SMP of 0.340 L $CH_4/g$ VS.